Method of producing a high strength (with improved tensile strength and elongation at break properties), high quality, cost effective, nanoparticle enhanced polyurea, polyurethane, and epoxy composites with chemical bonding into polymer backbone. The mechanical properties of tensile strength and elongation at break improves concurrently and significantly with tensile strength increasing well over 300%. The polymer/nanoparticle composite can be produced cost effectively as a high quality coating system or in nanoparticle concentrate forms.

Provided are: a coated sand having improved fluidity and being capable of improving a filling rate of a casting mold to be obtained; and a coated sand for advantageously manufacturing a casting mold having excellent strength, which coated sand provides a casting mold with good mold-releasability and collapsibility, gives cast products a favorable casting surface, and effectively improves sand adhesion on cast products. The coated sand is formed as a dry granular material having fluidity at room temperature, in which the surface of a refractory aggregate is coated with a solid layer of a water-soluble inorganic binder, and spherical particles of silicone resin having binder-repellency exist on the surface of the binder layer, or form a layer on the surface of the binder layer, a part of the spherical particles being not covered with the water-soluble inorganic binder and being exposed.

Embodiments provide a method of encapsulating a solid cement additive. The method includes the step of applying a base film-forming monomer to the solid cement additive. The method includes the step of forming a coating layer surrounding the solid cement additive. The coating layer includes the base film-forming monomer. The method includes the step of applying an overlay film-forming monomer to the coating layer surrounding the solid cement additive. The method includes the step of reacting the base film-forming monomer and the overlay film-forming monomer to produce a polymer shell. The solid cement additive includes solid particles useful in cementing applications. The polymer shell includes a crosslinked polymer. The polymer shell surrounds the solid cement additive. The polymer shell has a permeability to water allowing controlled release of the solid cement additive.

Embodiments provide a method of encapsulating a solid cement additive. The method includes the step of applying a base film-forming monomer to the solid cement additive. The method includes the step of forming a coating layer surrounding the solid cement additive. The coating layer includes the base film-forming monomer. The method includes the step of applying an overlay film-forming monomer to the coating layer surrounding the solid cement additive. The method includes the step of reacting the base film-forming monomer and the overlay film-forming monomer to produce a polymer shell. The solid cement additive includes solid particles useful in cementing applications. The polymer shell includes a crosslinked polymer. The polymer shell surrounds the solid cement additive. The polymer shell has a permeability to water allowing controlled release of the solid cement additive.

A composition of matter has cement particles and resin structures having: a first functional group bonded directly to a surface of each cement particle; and a second functional group that bonds to calcium silicate hydrate upon hydration, wherein the second functional group is bondable with second functional groups of others of the cement particles to form a polymer network; and a backbone that connects the first functional group with the second functional group. A method of forming cement particles includes mixing cement particles with reactive molecules, the reactive molecules having a first functional group bonded directly to a surface of each cement particle, a second functional group that is bondable to calcium silicate hydrate upon hydration, wherein the second functional group is bondable with second function groups of others of the cement particles to form a polymer network, and a backbone that connects the first functional group with the second functional group. A composition of matter has cement particles, and a cured resin structure resulting from a reaction between two or more reactive molecules having functional groups that react with each other onto the surfaces of the cement particle, wherein one of the reactive molecules is used in less than a stoichiometric amount, leaving unreacted functional groups, and wherein the unreacted functional groups are bondable to calcium silicate hydrate upon hydration.

A composition of matter has cement particles and resin structures having: a first functional group bonded directly to a surface of each cement particle; and a second functional group that bonds to calcium silicate hydrate upon hydration, wherein the second functional group is bondable with second functional groups of others of the cement particles to form a polymer network; and a backbone that connects the first functional group with the second functional group. A method of forming cement particles includes mixing cement particles with reactive molecules, the reactive molecules having a first functional group bonded directly to a surface of each cement particle, a second functional group that is bondable to calcium silicate hydrate upon hydration, wherein the second functional group is bondable with second function groups of others of the cement particles to form a polymer network, and a backbone that connects the first functional group with the second functional group. A composition of matter has cement particles, and a cured resin structure resulting from a reaction between two or more reactive molecules having functional groups that react with each other onto the surfaces of the cement particle, wherein one of the reactive molecules is used in less than a stoichiometric amount, leaving unreacted functional groups, and wherein the unreacted functional groups are bondable to calcium silicate hydrate upon hydration.

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and a means for molecular scale healing is disclosed; the composition has the ability to resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer serves to bring surfaces of a structural defect into approximation, whereafter use of the means for molecular scale healing allowed for movement of the healing means into the defect and thus obtain molecular scale healing. The means for molecular scale healing can be a thermoplastic such as fibers, particles or spheres which are used by heating to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. Compositions of the invention have the ability to not only close macroscopic defects, but also to do so repeatedly even if another wound/damage occurs in a previously healed/repaired area.

A method of using a gas control additive to provide gas migration control in a wellbore includes the steps of mixing the gas control additive with a cement to form a cement slurry, where the gas control additive includes a semi-permeable membrane and a scrubbing agent, such that the semi-permeable membrane forms a shell around a core such that the scrubbing agent is in the core, introducing the cement slurry to the wellbore, and reacting the scrubbing agent with an antagonistic gas to produce a helper byproduct, where the antagonistic gas migrates from a hydrocarbon-bearing formation into the wellbore and permeates through the semi-permeable membrane to the core of the gas control additive.

A method of using a gas control additive to provide gas migration control in a wellbore includes the steps of mixing the gas control additive with a cement to form a cement slurry, where the gas control additive includes a semi-permeable membrane and a scrubbing agent, such that the semi-permeable membrane forms a shell around a core such that the scrubbing agent is in the core, introducing the cement slurry to the wellbore, and reacting the scrubbing agent with an antagonistic gas to produce a helper byproduct, where the antagonistic gas migrates from a hydrocarbon-bearing formation into the wellbore and permeates through the semi-permeable membrane to the core of the gas control additive.

A method of using a gas control additive to provide gas migration control in a wellbore includes the steps of mixing the gas control additive with a cement to form a cement slurry, where the gas control additive includes a semi-permeable membrane and a scrubbing agent, such that the semi-permeable membrane forms a shell around a core such that the scrubbing agent is in the core, introducing the cement slurry to the wellbore, and reacting the scrubbing agent with an antagonistic gas to produce a helper byproduct, where the antagonistic gas migrates from a hydrocarbon-bearing formation into the wellbore and permeates through the semi-permeable membrane to the core of the gas control additive.