C04B24/165

POLYMER HAVING DISPERSING FUNCTION, OIL WELL CEMENT DISPERSANT, AND PREPARATION METHOD THEREFOR AND USE THEREOF

A polymer having a dispersing function, a preparation method therefor, and a use thereof as a cement dispersant are provided. The polymer has a structural unit a, a structural unit b, a structural unit c and a structural unit d. The structural unit a is provided by an unsaturated polyether and/or polyester, the structural unit b is provided by an unsaturated carboxylic acid or an anhydride or salt thereof, the structural unit c is provided by a silane and/or siloxane containing a polymerizable group, and the structural unit d is provided by an unsaturated sulfonic acid or a salt thereof. The molar ratio of the structural unit a to the structural unit d is 1:(5-15) and the polymer has a weight average molecular weight of 20,000 to 120,000. The polymer can be used as an oil well cement dispersant.

POLYMER HAVING DISPERSING FUNCTION, OIL WELL CEMENT DISPERSANT, AND PREPARATION METHOD THEREFOR AND USE THEREOF

A polymer having a dispersing function, a preparation method therefor, and a use thereof as a cement dispersant are provided. The polymer has a structural unit a, a structural unit b, a structural unit c and a structural unit d. The structural unit a is provided by an unsaturated polyether and/or polyester, the structural unit b is provided by an unsaturated carboxylic acid or an anhydride or salt thereof, the structural unit c is provided by a silane and/or siloxane containing a polymerizable group, and the structural unit d is provided by an unsaturated sulfonic acid or a salt thereof. The molar ratio of the structural unit a to the structural unit d is 1:(5-15) and the polymer has a weight average molecular weight of 20,000 to 120,000. The polymer can be used as an oil well cement dispersant.

MULTIFUNCTIONAL SUPERPLASTICIZER FOR ULTRA-HIGH PERFORMANCE CONCRETE AND PREPARATION METHOD THEREFOR

Providing a multi-functional group superplasticizer for an ultra-high performance concrete and a method for preparing the same. Its backbone is an alkyl chain, and its side chain are some side chains with carboxylic acid or carboxylate at terminals, some polyether side chains, and some polyol amine side chains substituted with phosphoric acid or phosphite at terminals, the polyol amine side chains substituted with phosphoric acid or phosphite at terminals is connected to the backbone through a phenyl or an alkyl group of 1-9 carbons, and a ratio of a number of the side chains with carboxylic acid or carboxylate at terminals to a total number of side chains is ≥0 and ≤0.8; and a ratio of a number of the polyether side chains to the total number of side chains is ≥0.1 and ≤0.9.

Water-soluble or water-swellable polymers as water loss reducers in cement slurries

This invention relates to water-soluble or water-swellable polymers, containing a) 25-35 mol. % of one or more recurrent structural units of formula (1), where R.sup.1 and R.sup.2 represent hydrogen, methyl or ethyl, A represents a linear or branched C.sub.1-C.sub.12-alkylene, and Q.sup.+ stands for NH.sub.4.sup.+, Li.sup.+, Na.sup.+, K.sup.+, ½ Ca.sup.++, ½ Mg.sup.++, ½ Zn.sup.++, ⅓ Al.sup.+++, or organic ammonium ions of the formula [HNR.sup.5R.sup.6R.sup.7].sup.+, b) 3 to 8 mol. % of one or more recurrent structural units of formula (2), where R.sup.1 represents hydrogen, methyl, or ethyl, X.sup.+ stands for H.sup.+, NH.sub.4.sup.+, Li.sup.+, Na.sup.+, K.sup.+, ½ Ca.sup.++, ½ Mg.sup.++, ½ Zn.sup.++, ⅓ Al.sup.+++, or organic ammonium ions of the formula [HNR.sup.5R.sup.6R.sup.7].sup.+, B is a linear or branched alkylene group with 1 to 6 carbon atoms, and n is a whole number between 0 and 5, and c) 57 to 72 mol. % of a (meth)acrylamide.

Water-soluble or water-swellable polymers as water loss reducers in cement slurries

This invention relates to water-soluble or water-swellable polymers, containing a) 25-35 mol. % of one or more recurrent structural units of formula (1), where R.sup.1 and R.sup.2 represent hydrogen, methyl or ethyl, A represents a linear or branched C.sub.1-C.sub.12-alkylene, and Q.sup.+ stands for NH.sub.4.sup.+, Li.sup.+, Na.sup.+, K.sup.+, ½ Ca.sup.++, ½ Mg.sup.++, ½ Zn.sup.++, ⅓ Al.sup.+++, or organic ammonium ions of the formula [HNR.sup.5R.sup.6R.sup.7].sup.+, b) 3 to 8 mol. % of one or more recurrent structural units of formula (2), where R.sup.1 represents hydrogen, methyl, or ethyl, X.sup.+ stands for H.sup.+, NH.sub.4.sup.+, Li.sup.+, Na.sup.+, K.sup.+, ½ Ca.sup.++, ½ Mg.sup.++, ½ Zn.sup.++, ⅓ Al.sup.+++, or organic ammonium ions of the formula [HNR.sup.5R.sup.6R.sup.7].sup.+, B is a linear or branched alkylene group with 1 to 6 carbon atoms, and n is a whole number between 0 and 5, and c) 57 to 72 mol. % of a (meth)acrylamide.

Functionalized Polyacrylate Polymer Compositions
20210292552 · 2021-09-23 ·

Functionalized polyacrylate polymer compositions for treating clay or clay bearing aggregates compositions are disclosed. Also disclosed are methods for preparing the functionalized polyacrylate polymer compositions, admixtures containing such polymers and methods for the mitigation of clays in cementitious and aggregate compositions using these polymers.

Copolymers having a gradient structure
11066330 · 2021-07-20 · ·

The present invention relates to a copolymer, especially for use as a dispersant for solid particles, in particular for use as dispersant for mineral binder compositions, having a polymer backbone and side chains bonded thereto, comprising at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2, wherein the copolymer has a gradient structure in at least one section A in a direction along the polymer backbone with regard to the ionizable monomer unit M1 and/or with regard to the side chain-bearing monomer unit M2.

MULTITYPE-ADSORPTIVE-GROUP POLYCARBOXYLIC ACID WATER-REDUCING AGENT, METHOD FOR PREPARING THE SAME AND USE THEREOF

The present invention discloses a multitype-adsorptive-group polycarboxylic acid water-reducing agent, consisting of 30-60 wt % of a macromolecule with multitype-adsorptive groups and water, the macromolecule with multitype-adsorptive groups has a polyethylene glycol side chain, and adsorption groups of the polymer backbone include a carboxylic acid group, a sulfonic acid group and a phosphoric acid group, the phosphoric acid group being linked to the backbone of the macromolecule with multitype-adsorptive groups by nucleophilic addition. The water-reducing agent of the present invention has significantly improved adaptability to different cements and aggregates while maintaining a high water reduction efficiency, compared with the conventional polycarboxylic acid water-reducing agent. It has a good water reducing efficiency in many different grades of cement, as well as a better resistance to aggregates containing more impurities such as machine-made sand.

Phosphorylated amino polycarboxylic acid cement retarder

A variety of systems, methods and compositions are disclosed, including, in one method, a method of cementing may comprise: providing a cement composition comprising: a hydraulic cement comprising Portland cement in an amount of about 50% by weight of hydraulic cement or less, water, and a phosphorylated amino polycarboxylic acid cement retarder; placing the cement composition in a wellbore; and allowing the cement composition to set. A cement composition, the composition comprising: a hydraulic cement comprising Portland cement in an amount of about 50% by weight of hydraulic cement or less; water; and a phosphorylated amino polycarboxylic acid cement retarder.

Phosphorylated amino polycarboxylic acid cement retarder

A variety of systems, methods and compositions are disclosed, including, in one method, a method of cementing may comprise: providing a cement composition comprising: a hydraulic cement comprising Portland cement in an amount of about 50% by weight of hydraulic cement or less, water, and a phosphorylated amino polycarboxylic acid cement retarder; placing the cement composition in a wellbore; and allowing the cement composition to set. A cement composition, the composition comprising: a hydraulic cement comprising Portland cement in an amount of about 50% by weight of hydraulic cement or less; water; and a phosphorylated amino polycarboxylic acid cement retarder.