The present invention relates to admixtures, especially a dispersant for solid particles, in particular a dispersant for mineral binder compositions, comprising: a) a superplasticizer and b) a copolymer having a polymer backbone and side chains bonded thereto, comprising at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2, wherein the copolymer has a nonrandom distribution of the monomer units M1 and/or the monomer units M2 in a direction along the polymer backbone,
and wherein the superplasticizer and the copolymer differ from a chemical and/or structural point of view.

The present invention provides efficient methods to form a high solids content polymeric polyacid or a comb polymer useful as a superplasticizer or dispersant which comprise heating to from 80 to 100 C for a first time period, and then, sequentially, heating to a second temperature of from 150 to 250 C. for a second time period a wet reaction mixture having a solids content of from 80 to 99 wt. % and comprising from 15 to 60 wt. % of one or more ethylenically unsaturated acid or a salt thereof, from 37 to 76.99 wt. % of one or more polyether polyols, alkyl polyether polyols, polyether amines or alkyl polyether amines in the presence of (i) from 0.01 to 1 wt. %, of one or more water soluble radical initiators or redox pairs and (ii) from 2 to 22 wt. % of one or more phosphorus oxide containing compounds, all weights based on the total weight of the wet reaction mixture.

A process for preparing a polymer mixture containing at least two different comb polymers, wherein the comb polymers each have a polymer backbone having side chains attached via ester and/or amide groups, which process includes the steps of: a) providing and/or preparing a reaction mixture containing at least a first base polymer bearing acid groups and a second base polymer bearing acid groups, wherein the two base polymers differ chemically; b) conjointly esterifying and/or amidating the two base polymers with at least one unilaterally hydroxyl-terminated side chain compound and/or with at least one unilaterally amino-terminated side chain compound to obtain at least two different comb polymers.

The present invention provides a method and admixture composition for making hydratable cementitious compositions, ones believed to have much less stickiness in comparison to prior methods. Decreased stickiness in concrete mixes means that they are easier to pour or to cast into place, as well as easier to finish. Dispersant carboxylate polymers of the invention having this ability are characterized by possessing two different, relatively short chain lengths of polyalkyleneoxide units and low weight-average molecular weights.

The invention relates to a pulverulent composition which can be produced by bringing a powder which comprises at least one inorganic binder into contact with from 0.01 to 10% by weight, based on the total mass of the composition, of a liquid component comprising at least one copolymer which can be obtained by polymerization of a mixture of monomers comprising (I) at least one ethylenically unsaturated monomer which comprises at least one radical selected from the group consisting of carboxylic acid, carboxylic acid salt, carboxylic esters, carboxamide, carboxylic anhydride and carboximide and (II) at least one ethylenically unsaturated monomer having a polyalkylene oxide radical, where the liquid component contains at least 1% by weight of the at least one copolymer and at least 30% by weight of an organic solvent. Furthermore, a process for producing the liquid component, the use thereof and also specific copolymers are disclosed.

A method for inerting a swellable clay and/or for reducing or inhibiting adverse effects of swellable clays on the effectiveness of dispersants in mineral binder compositions, includes adding a comb polymer to a mineral binder composition. The comb polymer includes: at least one poly(alkylene oxide) side chain-bearing monomer unit without ionic groups, optionally at least one cationic monomer unit, optionally at least one anionic monomer unit, and optionally, at least one non-ionic monomer unit.

A method for inerting a swellable clay and/or for reducing or inhibiting adverse effects of swellable clays on the effectiveness of dispersants in mineral binder compositions, includes adding a comb polymer to a mineral binder composition. The comb polymer includes: at least one poly(alkylene oxide) side chain-bearing monomer unit without ionic groups, optionally at least one cationic monomer unit, optionally at least one anionic monomer unit, and optionally, at least one non-ionic monomer unit.

The present invention relates to the use of a cationic copolymer as a rheology modifier in a geopolymer foam formulation, a geopolymer foam formulation comprising a cationic copolymer, a process for preparing a geopolymer foam, a geopolymer foam comprising a cationic copolymer and composition for preparing a geopolymer foam formulation.

The present invention relates to the use of a cationic copolymer as a rheology modifier in a geopolymer foam formulation, a geopolymer foam formulation comprising a cationic copolymer, a process for preparing a geopolymer foam, a geopolymer foam comprising a cationic copolymer and composition for preparing a geopolymer foam formulation.

The present invention relates to cationic copolymers, a process for the production of these cationic copolymers and the use of these cationic copolymers as dispersants for geopolymer binder systems. These cationic copolymers where the cationic charge is due to the presence of certain cyclic and/or polycationic groups are stable towards Hoffmann elimination that would otherwise occur at very high pH values. Moreover, the dispersing effect of cationic polymers can be further enhanced through the addition of polyvalent anions.