The present invention provides a self-healing ceramic material with reduced porosity and a method for preparing the same. The self-healing ceramic material comprises the following components by volume: 60-85 parts by volume of Al.sub.2O.sub.3, 10-20 parts by volume of TiN, 10-20 parts by volume of TiSi.sub.2, 0.1-1 parts by volume of MgO, and 0.1-1 parts by volume of Y.sub.2O.sub.3. Wherein, Al.sub.2O.sub.3 serves as a matrix, TiN and TiSi.sub.2 act as repair agents, and MgO and Y.sub.2O.sub.3 function as sintering aids. The repair function is realized by adding TiN and TiSi.sub.2, which have repair capabilities, to the ceramic matrix, enabling the ceramic material to heal cracks. TiN plays the main role of repair function, and TiSi.sub.2 assists in the repair and helps reduce the formation of surface pores.

The present disclosure relates to an electrolytic cell for the production of aluminium by reducing alumina. The cell may comprise a sidewall including at least one side block. The side block may comprise an aluminous material having an apparent porosity of less than about 10% and a composition, as a weight percentage on the basis of the aluminous material and for a total of about 100%, such that: Al2O3>about 50%, beta-alumina being less than about 20% of the weight of the aluminous material, oxides that are less reducible than alumina at 1000 C.<about 50%, Na2O<about 3.9%, and other components<about 5%.

A powder is disclosed having a coarse fraction representing more than 60% and less than 85% of the powder, as a weight percentage on the basis of the oxides, and that is constituted of particles having a size greater than or equal to 50 m, referred to as coarse particles, the powder comprising at least 5% of coated grains having a size greater than or equal to 50 m, as a weight percentage on the basis of the oxides of the powder, and a fine fraction, forming the balance to 100% as a weight percentage on the basis of the oxides, constituted of particles having a size of less than 50 m, referred to as matrix particles. The powder can be applied in combustion chambers in which the temperature may reach 1400 C.

A refractory object can include at least approximately 10 wt % Al.sub.2O.sub.3 and at least approximately 1 wt % SiO.sub.2. In an embodiment, the refractory object can include an additive. In a particular embodiment, the additive can include TiO.sub.2, Y.sub.2O.sub.3, SrO, BaO, CaO, Ta.sub.2O.sub.5, Fe.sub.2O.sub.3, ZnO, or MgO. The refractory object can include at least approximately 3 wt % of the additive. In an additional embodiment, the refractory object can include no greater than approximately 8 wt % of the additive. In a further embodiment, the creep rate of the refractory object can be at least approximately 110.sup.6 h.sup.1. In another embodiment, the creep rate of the refractory object can be no greater than approximately 510.sup.5 h.sup.1. In an illustrative embodiment, the refractory object can include a glass overflow trough or a forming block.

Disclosed are ceramic bodies comprised of composite cordierite-mullite-aluminum magnesium titanate (CMAT) ceramic compositions having high cordierite-to-mullite ratio and methods for the manufacture of same.

A refractory object can include at least 10 wt % Al.sub.2O.sub.3. In an embodiment, the refractory object can further include a dopant including an oxide of a rare earth element, Ta, Nb, Hf, or any combination thereof. In another embodiment, the refractory object may have a property such that the averaged grain size does not increase more than 500% during sintering, an aspect ratio less than approximately 4.0, a creep rate less than approximately 1.010.sup.5 m/(mhr), or any combination thereof. In a particular embodiment, the refractory object can be in the form of a refractory block or a glass overflow forming block. The glass overflow forming block can be useful in forming an AlSiMg glass sheet. In a particular embodiment, a layer including MgAl oxide can initially form along exposed surfaces of the glass overflow forming block when forming the AlSiMg glass sheet.

The invention relates to a fire-resistant ceramic product.

Titanium dioxide is used as an emissivity enhancer in high emissivity coating compositions. The titanium dioxide increases the emissivity of the high emissivity coating compositions. In certain embodiments, titanium dioxide is recovered from industrial waste sources such as catalyst containing waste streams from olefin polymerization processes or re-based sources. Titanium dioxide emissivity enhancers recovered from industrial waste sources contribute favorably to the cost of manufacturing high emissivity coating compositions containing such enhancers.

In order to address the technical problem of allowing an unshaped refractory material using a spinel-containing alumina cement to provide further improved corrosion resistance and slag infiltration resistance while reducing the occurrence of crack/peeling, an unshaped refractory material is provided which comprises a refractory raw material mixture having a particle size of 8 mm or less, with the refractory raw material mixture having an alumina cement at least a part of which is a spinel-containing alumina cement, and, with respect to 100 mass % of the refractory raw material mixture, the alumina cement contains CaO in an amount of 0.5 to 2.5 mass %, and the spinel-containing alumina cement contains spinel in an amount of 3.5 to 10.5 mass %.

Titanium dioxide is used as an emissivity enhancer in high emissivity coating compositions. The titanium dioxide increases the emissivity of the high emissivity coating compositions. In certain embodiments, titanium dioxide is recovered from industrial waste sources such as catalyst containing waste streams from olefin polymerization processes or re-based sources. Titanium dioxide emissivity enhancers recovered from industrial waste solution sources contribute favorably to the cost of manufacturing high emissivity coating compositions containing such enhancers.