This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.

An additive manufacturing method may involve: Providing a first material in powder form and a second material as a consumable electrode; forming the first material into a first layer on a base; placing an end of the second material in close proximity to a portion of the first layer; operating a power supply connected to the base and the second material to provide electrical energy sufficient to initiate a chemical reaction between the first and second materials and form a reaction product; feeding additional amounts of the second material while moving the end of the second material along a desired pattern adjacent the first layer, additional reaction products forming additional portions of the article; providing additional quantities of the first material over the first layer to form a subsequent layer; and operating the power supply form additional portions of the article in the subsequent layer.

The present invention is a method for obtaining a ceramic slurry for the production of filaments for 3D FDM printing, comprising adding a polysaccharide, a glycol or an ethanolamine as a gelling agent to a suspension of ceramic material in order to produce said ceramic slurry. The invention also comprises the green body obtained from said slurry and the ceramic filament extruded from the green body.

A method for producing an annular combustion chamber of a turbojet using CMC. For this, a shaping tool with movable slides is used and said chamber is produced around the tool, thereby producing a fibrous preform of which the shape is consolidated by drape moulding on the tool and pyrolysis, which is then densified by CVI. Several slides have back drafts, at least one other of such slides having a draft or neither a draft nor a back draft. Then, the slides are removed in a predetermined order imposed by the back drafts and the relative positions of the slides.

A process of forming a Si-containing ceramic comprises forming a Si-based polymeric composition. The process includes neutralizing a charge of said Si-based polymeric composition. The process includes adding thermal energy under a controlled atmosphere to the Si-based polymeric composition. A turbine engine component comprises an airfoil and the airfoil comprises a Ceramic Matrix Composite (CMC) material.

High-entropy ultra-high temperature ceramics (HE-UHTC) coatings deposited on substrates, as well methods for depositing the HE-UHTC coatings on the substrates, are provided. An HE-UHTC electrode can be fabricated via spark plasma sintering (SPS) and then a thin coating of the HE-UHTC can be deposited in a precision-controlled manner on a substrate via an electro-spark deposition process.

The present disclosure provides a method of making a non-oxide ceramic part. The method includes obtaining a photopolymerizable slurry; selectively curing the photopolymerizable slurry to obtain a gelled article; drying the gelled article to form an aerogel article or a xerogel article; heat treating the aerogel article or the xerogel article to form a porous ceramic article; and sintering the porous ceramic article to obtain a sintered ceramic article. The photopolymerizable slurry includes non-oxide ceramic particles; at least one radiation curable monomer; a solvent; a photoinitiator; an inhibitor; and at least one sintering aid. Further, aerogels, xerogels, porous ceramic articles, and non-oxide ceramic articles are provided. In addition, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

An additive manufacturing method may involve: Providing a first and a second material, the second material capable of reacting with the first material to form a reaction product; forming at least the first material into a first layer; subjecting at least a portion of the first layer to energy in the presence of the second material, the energy being sufficient to initiate a reaction between at least the first and second materials to form a portion of the article, the portion of the article comprising the reaction product; forming a second layer of at least the first material on the first layer; and subjecting at least a portion of the second layer to energy in the presence of the second material, the energy being sufficient to initiate a reaction between the first and second materials to form an additional portion of the article.

An osmotic energy conversion system includes a housing having a first inlet and a second inlet, an MXene lamellar membrane located inside the housing and configured to divide the housing into a first chamber and a second chamber, and first and second electrodes placed in the first and second chambers, respectively, and configured to collect electrical energy generated by a salinity-gradient formed by first and second liquids across the MXene lamellar membrane. The first chamber is configured to receive the first liquid at the first inlet and the second chamber is configured to receive the second liquid at the second inlet. The first liquid has a salinity lower than the second liquid, and the MXene lamellar membrane includes plural nanosheets of MXene stacked on top of each other.

An osmotic energy conversion system includes a housing having a first inlet and a second inlet, an MXene lamellar membrane located inside the housing and configured to divide the housing into a first chamber and a second chamber, and first and second electrodes placed in the first and second chambers, respectively, and configured to collect electrical energy generated by a salinity-gradient formed by first and second liquids across the MXene lamellar membrane. The first chamber is configured to receive the first liquid at the first inlet and the second chamber is configured to receive the second liquid at the second inlet. The first liquid has a salinity lower than the second liquid, and the MXene lamellar membrane includes plural nanosheets of MXene stacked on top of each other.