This invention relates to three-dimensional printing. This invention in particular relates to a method of generating mold and printing a three-dimensional object. The mold thickness is controlled and holes are generated in the mold surface for releasing moisture easily. The mold surface having holes is designed initially digitally and then combined with the three-dimensional model before printing the three-dimensional object. In case the thickness of the mold surface is more then it reduces the overall quality of the three-dimensional object. When the model is enclosed inside the mold, there will be some residue moisture in the model even if the drying apparatus can improve this by drying layer by layer. This affects the final quality of the part. A solution of these problems is provided in the present invention. The thickness of the mold layer is between 0.5 to 1 mm and holes having 0.1 to 0.4 mm diameter. The holes are evenly distributed on the mold. The mold having the holes is prepared from which moisture can easily escape. A method of digitally generated a mold having thin layer and holes is used for fabricating three dimensional objects with high precision and quality.

This invention relates to three-dimensional printing. This invention particularly relates to a system with a dynamic variable size nozzle orifice for three-dimensional printing of objects based on crafting and molding techniques, and a method thereof. The present invention provides a dynamic variable nozzle orifice, where one embodiment uses a nozzle made of a soft flexible material. The soft flexible material, such as rubber, latex or silicone, is such that when the extrusion pressure is high the orifice will enlarge and allow wider extrusion volume for filling large or wide voids. In another scenario, when the extrusion pressure is lower the orifice will be narrower and give precise narrow extrusion to fill smaller voids. Another embodiment uses a method of controlling the orifice size which is by a mechanical means independent of the pressure in the nozzle. Such a method can utilize an iris device for controlling the size of the orifice. By utilizing the function of a dynamic orifice size of the nozzle when depositing a crafting material inside a mold structure as described herein, the printing time can be reduced without a reduction in detailing abilities. Subsequently, the systems and methods of the present invention are useful for fabricating high-quality three-dimensional objects using a crafting paste and molding techniques.

Disclosed is a method of making high temperature fiber including chemically bonding high temperature material to a fiber template at a first temperature to form a precursor fiber and processing the precursor fiber at a second temperature to form the high temperature fiber. The first temperature does not equal the second temperature. Also disclosed are high temperature fibers made by the method.

Disclosed is a method of making high temperature fiber including incorporating an inorganic atom into a polymer precursor fiber to form a modified polymer precursor fiber and converting the modified polymer precursor fiber to a high temperature fiber having a bonded inorganic atom.

A non-woven fabric is provided which includes a three-dimensional array of fibers. The three-dimensional array of fibers includes an array of standing fibers extending perpendicular to a plane of the non-woven fabric and attached to a base substrate, where the base substrate is one or more of an expendable film substrate, a metal base substrate, or a mandrel substrate. Further, the three-dimensional array of fibers includes multiple layers of non-woven parallel fibers running parallel to the plane of the non-woven fiber in between the array of standing fibers in a defined pattern of fiber layer orientations. In implementation, the array of standing fibers are grown to extend from the base substrate using laser-assisted chemical vapor deposition (LCVD).

The present invention relates to aqueous suspensions containing 30 to 95 wt.-% metal carbide particles and a dispersant, and to a process for coating substrates using said aqueous suspensions. The invention also relates to the coated substrates that can be produced by the process according to the invention and to the uses thereof.

Disclosed is a thermoelectric composite material includes a thermoelectric material including crystal grains; and a MXene inserted at boundaries of the crystal grains consisting of the thermoelectric material. Accordingly, the thermoelectric composite material may have a reduced thermal conductivity and an increased electrical conductivity. Furthermore, mechanical properties of the thermoelectric composite material may be improved. Thus, the thermoelectric composite material may improve the thermoelectric ability of a thermoelectric module including the same. A method of manufacturing the thermoelectric composite material includes coating MXene on a surface of a thermoelectric material powder including crystal grains; and sintering the thermoelectric material powder coated with the MXene to form a sintered body including the MXene inserted at boundaries of the crystal grains consisting of the thermoelectric material.

A method of fabricating a friction part out of composite material, the method including densifying a carbon yarn fiber preform with a matrix including at least pyrolytic carbon and a ZrO.sub.xC.sub.y phase, where 1x2 and 0y1, the matrix being formed by film-boiling or by chemical vapor infiltration from a first precursor for pyrolytic carbon and a second precursor that includes zirconium, the second precursor being a zirconium complex including an alcoxy or carboxylate ligand bonded to zirconium.

Method for manufacturing a CMC, i.e. ceramic matrix composite material, part provided with at least one cutout, as well as to such a CMC part provided with at least one cutout, the method comprising the following steps: providing (E1) a fibrous reinforcement (10), forming (E2) a cavity in a portion of the fibrous reinforcement (10), injecting (E3) a slip comprising at least a ceramic powder and a solvent, the slip being injected so as to impregnate the fibrous reinforcement (10) and to fill the cavity of the fibrous reinforcement (10), drying (E4) the obtained assembly, carrying out a densification (E6) by infiltration of a liquid densification material and solidification of said densification material, machining (E7) at least one cutout in the obtained blank (30) within the volume corresponding to the cavity of the fibrous reinforcement (10).

This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.