Organosilicon chemistry, polymer derived ceramic materials, and methods. Such materials and methods for making polysilocarb (SiOC) and Silicon Carbide (SiC) materials having 3-nines, 4-nines, 6-nines and greater purity. Processes and articles utilizing such high purity SiOC and SiC.

Organosilicon chemistry, polymer derived ceramic materials, and methods. Such materials and methods for making polysilocarb (SiOC) and Silicon Carbide (SiC) materials having 3-nines, 4-nines, 6-nines and greater purity. Processes and articles utilizing such high purity SiOC and SiC.

A fabrication apparatus for fabricating ceramic structures of controlled size and composition is provided. The fabrication apparatus includes an additive manufacturing machine configured to dispense preceramic materials in a printed pattern, the printed pattern corresponding to the ceramic structures of the controlled size and composition, a radiation emitter configured to emit curing radiation toward the printed pattern to cure the preceramic materials and a lamp element configured to shine light on the preceramic materials to convert the preceramic materials to ceramics.

Cement, concrete, stucco, and plaster that have black ceramic polymer derived pigments, and in embodiments have a uniform blackness throughout the structure. In embodiments the black pigment is a ceramic SiOC, that has a size of about 0.8 μm.

Cement, concrete, stucco, and plaster that have black ceramic polymer derived pigments, and in embodiments have a uniform blackness throughout the structure. In embodiments the black pigment is a ceramic SiOC, that has a size of about 0.8 μm.

A method for producing a silicon-carbide-based composite. In the production of a silicon-carbide-based composite comprising a carbon-fiber-reinforced/silicon carbide composite (a C/SiC composite) or a silicon-carbide-fiber-reinforced/silicon carbide composite (a SiC/SiC composite), a film boiling method is carried out, using an organosilicon polymer having a chlorine-free polysilane skeleton and/or a chlorine-free polycarbosilane skeleton. The organosilicon polymer is in a liquid form at room temperature. The molar ratio of Si and C in the matrix of the C/SiC composite or the SiC/SiC composite is Si:C=1:1.08 to 1:1.43.

A method for producing a silicon-carbide-based composite. In the production of a silicon-carbide-based composite comprising a carbon-fiber-reinforced/silicon carbide composite (a C/SiC composite) or a silicon-carbide-fiber-reinforced/silicon carbide composite (a SiC/SiC composite), a film boiling method is carried out, using an organosilicon polymer having a chlorine-free polysilane skeleton and/or a chlorine-free polycarbosilane skeleton. The organosilicon polymer is in a liquid form at room temperature. The molar ratio of Si and C in the matrix of the C/SiC composite or the SiC/SiC composite is Si:C=1:1.08 to 1:1.43.

Methods, processes, systems, devices and apparatus are provided for additive manufacture resulting in the 3D printing of ceramic materials and components with a thickness greater than three millimeters (3 mm). A sulfur-free 3D printable formulation comprises a liquid inorganic polymer resin using Stereolithograpy (SLA) printers and Digital Light Processing (DLP) curing of the polymer resin via the chemical bonding of the materials rather than sintering. Thus, the process has shorter manufacturing intervals, significantly lower energy use and produces larger scale ceramic components having less linear shrinkage, less mass loss and high ceramic yield with no corrosive sulfur compounds present in the ceramic component.

A bonding tape for joining carbide ceramic structures, wherein the bonding tape comprises: a mixture comprising carbide ceramic particles, preceramic polymer liquid, fine carbon particles and metal nanoparticles that form a eutectic liquid at temperatures below 1400° C.

A bonding tape for joining carbide ceramic structures, wherein the bonding tape comprises: a mixture comprising carbide ceramic particles, preceramic polymer liquid, fine carbon particles and metal nanoparticles that form a eutectic liquid at temperatures below 1400° C.