C04B35/6225

Metal and ceramic nanofibers

Provided herein are nanofibers and processes of preparing nanofibers. In some instances, the nanofibers are metal and/or ceramic nanofibers. In some embodiments, the nanofibers are high quality, high performance nanofibers, highly coherent nanofibers, highly continuous nanofibers, or the like. In some embodiments, the nanofibers have increased coherence, increased length, few voids and/or defects, and/or other advantageous characteristics. In some instances, the nanofibers are produced by electrospinning a fluid stock having a high loading of nanofiber precursor in the fluid stock. In some instances, the fluid stock comprises well mixed and/or uniformly distributed precursor in the fluid stock. In some instances, the fluid stock is converted into a nanofiber comprising few voids, few defects, long or tunable length, and the like.

PREPARATION METHOD OF OXIDE HIGH-ENTROPY CERAMIC FIBER

The present invention relates to a method of preparing an oxide high entropy ceramic fiber; the oxide high entropy ceramic fiber of the present invention comprises five elements among Zr, Hf, Ti, Ce, Y, La, Gd, Er, Sm; the salt or precursor corresponding to the selected element is used as a metal source, anhydrous ethanol or anhydrous methanol is used as a solvent, polyvinylpyrrolidone or polyethylene oxide is used as a spinning aid to configure a spinning solution, the precursor fibers are prepared by electrostatic spinning, and the precursor fibers are heat-treated in air to obtain the oxide high-entropy ceramic fibers; the oxide high entropy ceramic fiber prepared by the present invention has a uniform diameter and good flexibility.

METHODS OF MANUFACTURING GREEN BODIES AND SUBSTRATES

A method of manufacturing a green body, the method comprising: providing: a third composition comprising a second substrate material, a third polymer, a fusing agent, and a third solvent; forming the third composition into a structure wherein the third composition forms a third layer; and contacting the third layer with a fourth solvent in which the third polymer is insoluble to precipitate said polymer, thereby forming a green body.

A substrate is further manufactured by: arranging a plurality of green bodies to form an assembly of green bodies;
fusing the green bodies in the assembly together, thereby forming a precursor substrate; and sintering the precursor substrate, thereby forming a substrate.

FILAMENTS BASED ON A COATED CORE MATERIAL

The invention relates to a filament comprising a core material (CM) comprising an inorganic powder (IP) and the core material (CM) is coated with a layer of shell material (SM) comprising a thermoplastic polymer. Further, the invention relates to a process for the preparation of said filament, as well as to three-dimensional objects and a process for the preparation thereof.

MULTI-COMPOSITION FIBER WITH REFRACTORY ADDITIVE(S) AND METHOD OF MAKING

Multi-composition fibers with one or more refractory additives, and methods of making the fibers, are provided. The method(s) includes providing a precursor-laden environment, and promoting fiber growth using laser heating. The precursor-laden environment includes a primary precursor material and a refractory precursor material. The multi-composition fiber may include a primary fiber material, and a refractory material substantially homogeneously intermixed with the primary fiber material.

Method for producing oxygen sensor

A production method for producing an oxygen sensor, includes spinning a precursor consisting of a salt of at least one metal chosen from Sc, Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ho, Yb, Sr, Ba, Mn, Co, Mg, and Ga, a solvent, and a macromolecular polymer to produce nanofibers of the precursor containing the salt of the metal. The method further includes calcining the nanofibers of the precursor at a temperature ranging from 550 C. to 650 C. for 2 to 4 hours, and making a solid electrolyte material composed of the nanofibers obtained from the calcining. The resulting solid electrolyte material constitutes a part of the oxygen sensor.

METHOD FOR PRODUCING OXYGEN SENSOR

A production method for producing an oxygen sensor, includes spinning a precursor consisting of a salt of at least one metal chosen from Sc, Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ho, Yb, Sr, Ba, Mn, Co, Mg, and Ga, a solvent, and a macromolecular polymer to produce nanofibers of the precursor containing the salt of the metal. The method further includes calcining the nanofibers of the precursor at a temperature ranging from 550 C. to 650 C. for 2 to 4 hours, and making a solid electrolyte material composed of the nanofibers obtained from the calcining. The resulting solid electrolyte material constitutes a part of the oxygen sensor.

Method for producing fuel cell including nanofibers of metal oxide

A production method for producing a fuel cell, includes spinning a precursor consisting of a salt of at least one metal chosen from Sc, Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ho, Yb, Sr, Ba, Mn, Co, Mg, and Ga, a solvent, and a macromolecular polymer to produce nanofibers of the precursor containing the salt of the metal. The method further includes calcining the nanofibers of the precursor at a temperature ranging from 550 C. to 650 C. for 2 to 4 hours, and making a solid electrolyte material composed of the nanofibers obtained from the calcining. The resulting solid electrolyte material constitutes a part of a fuel cell.

Organic-inorganic hybrid nanofibres having a mesoporous inorganic phase, preparation thereof by electrospinning, membrane, electrode, and fuel cell

Organic-inorganic hybrid nanofibres comprising two phases: a first mineral phase comprising a structured mesoporous network with open porosity; and a second organic phase comprising an organic polymer, wherein said organic phase is basically not present inside the pores of the structured mesoporous network. A membrane and an electrode comprising said nanofibres. A fuel cell comprising said membrane and/or said electrode. A method of preparing said nanofibres by electrically assisted extrusion (electrospinning).