A method of producing a graphite-containing refractory within which carbon fiber bundles are placed, the graphite constituting 1% to 80% by mass, the method including a bundling step of bundling carbon fibers to form the carbon fiber bundles; a mixing step of mixing a refractory raw material with graphite to prepare a graphite-containing refractory raw material; a pressing step of pressing the graphite-containing refractory raw material in which the carbon fiber bundles are placed to prepare a formed product; and a drying step of drying the pressed product, wherein the bundling step includes bundling 1000 to 300000 of the carbon fibers with a fiber diameter of 1 to 45 μm/fiber to form carbon fiber bundles 100 mm or more in length.

The invention relates to a pre-impregnated fibre-reinforced composite material in laminar form, obtained impregnating a fibrous mass with a polymeric binder composition and intended to be subjected to successive forming and pyrolysis operations to produce a fibre-reinforced composite ceramic material. The polymeric binder composition is based on one or more resins chosen from the group consisting of siloxane resins and silsesquioxane resins, and can optionally comprise one or more organic resins. The polymeric binder composition is a liquid with viscosity between 55000 and 10000 mPas at temperatures between 50° C. and 70° C. The polymeric binder composition forms a polymeric binding matrix, not cross-linked or only partially cross-linked that fills the interstices of the fibrous mass. The invention also relates to a method for making said pre-impregnated fibre-reinforced composite material in laminar form. The invention further relates to a fibre-reinforced composite ceramic material, obtained by forming and subsequent pyrolysis of a pre-impregnated fibre-reinforced composite material, as well as a method for making said material.

The present invention relates to a manufacturing process for a watch component (50) in composite material with a ceramic matrix comprising the following steps: depositing in a mould a succession of layers (10, 20, 30, 40) each comprising a ceramic powder (12), at least one layer (10; 10, 30; 10, 20, 30, 40) further including fibres (14) mixed with the ceramic powder (12), the fibres (14) being arranged randomly; performing a FAST/SPS sintering operation; demoulding the sintered watch component comprising the succession of layers (10, 20, 30, 40), and optionally machining the sintered component to the final dimensions of the watch component (50). The fibres (14) are visible on the surface of the watch component (50).

A method for making a carbon carbon, carbon ceramic matrix, or carbon silica composite, comprising melt processing a resin comprising a polyaryletherketone (PAEK) and at least one reinforcing additive to make a precursor part, pyrolyzing the precursor part to make a pyrolyzed part, infusing a liquid second resin into the pyrolyzed part to make an infused part, and pyrolyzing the infused part. Other methods comprise processing aligned reinforcing additives and a resin comprising a PAEK to make an aligned reinforcing additives PAEK, aligned 1-2 dimensional flake material, or aligned 1-2 dimensional platelet material, to create a fabric, prepreg or tape comprising the aligned reinforcing additives and impregnated PAEK. Other methods comprise impregnating continuous fiber tape or fabric with a resin comprising PAEK and at least one reinforcing additive or co-weaving a continuous fiber or fabric with a PAEK fiber comprising PAEK and at least one reinforcing additive.

A composite material fabrication method includes stacking a plurality of fiber layers and a first binder and curing the first binder to form a three-dimensional structure with a plurality of mesh openings, and filling the plurality of mesh openings with a plurality of fiber filaments of a fiber array and a second binder and curing the second binder. A plurality of first mesh openings of the plurality of mesh openings are connected in a first direction.

A method for forming a ceramic matrix composite (CMC) component with an internal cooling channel includes partially densifying a first fiber preform to form a portion of a final ceramic matrix volume, machining a first channel into a surface of the partially densified first fiber preform, covering the first channel with a fibrous member to form a near net shape fiber preform with an internal passage formed by the first channel and the fibrous member, and densifying the near net shape fiber preform.

A method of forming a structure comprising a continuous fiber material comprises continuously feeding, through a continuous fiber nozzle assembly of an additive manufacturing tool, a feed material comprising a continuous fiber material and a thermoset resin material, heating or cooling the feed material to maintain a temperature of the feed material to a temperature sufficient to tackify the feed material and at least partially cure the feed material and initiate adhesion of the feed material on a build platform or a previously formed portion of a structure, and moving the continuous fiber nozzle assembly in three dimensions while depositing the feed material on the build platform or the previously formed portion of the structure to form the structure comprising the continuous fiber material extending in three dimensions. Related methods of forming a composite structure, and related tools for additively manufacturing a structure are disclosed.

A method of fabricating a laminar composite article, includes steps of spreading a plurality of continuous fiber tows from a spool to form a first ply layer having a substantially consistent layer thickness, applying a binder to the spread plurality of continuous fiber tows, curing the plurality of continuous fiber tows and applied binder at a cure temperature less than a thermal decomposition temperature of the binder, and processing the cured plurality of continuous fiber tows at a post-cure temperature greater than the cure temperature.

The present invention relates to a method of printing a composite material (1), for example polymeric, carbonaceous, siliconic or metallic comprising steps of: i) providing a plurality of bundles (2) of reinforcement fibres (4), wherein the reinforcement fibres (4) have a length in the range 3-50 mm and are in the number of about 1,000-100,000 in each bundle (2); ii) aligning the bundles (2) along a predetermined path (X, X′); iii) incorporating at least part of the bundles (2) into a matrix (6, 8), for example polymeric, carbonaceous, siliconic or metallic, preserving the alignment along said path (X, X′); iv) laying and solidifying at least one layer (8) of the matrix (6, 8) of step iii) to make the composite material (1).

The present invention relates to a metal-halide composite, articles comprising a metal-halide composite and method of making and using same. The metal-halide matrix materials used in such composite have the desired properties of high thermal conductivity, resistance to thermal induced microstructural changes, and ease of use. As a result, they permit the fabrication of higher performance cryogenic magnets, motors, generators, and cables. Additionally, they permit the fabrication of plate reinforced composites that are useful in lightweight armor and other articles. Additionally, an optoelectronic composite could be built depending on the choice of metal-halide matrix and reinforcement.