Systems and methods for forming an oxidation protection system on a composite structure are provided. In various embodiments, the oxidation protection system comprises a boron-glass layer formed on the composite substrate and a silicon-glass layer formed over the boron-glass layer. Each of the boron-glass layer and the silicon-glass layer includes a glass former.

Systems and methods for forming an oxidation protection system on a composite structure are provided. In various embodiments, the oxidation protection system comprises a boron-glass layer formed on the composite substrate and a silicon-glass layer formed over the boron-glass layer. Each of the boron-glass layer and the silicon-glass layer includes a glass former.

An article includes a ceramic-based substrate and a barrier layer on the ceramic-based substrate. The barrier layer includes a matrix phase and gettering particles in the matrix phase. The gettering particles with an aspect ratio greater than one are aligned such that a maximum dimension of the gettering particles extends along an axis that is generally parallel to the substrate. The barrier layer includes a dispersion of diffusive particles in the matrix phase. A composite material and a method of applying a barrier layer to a substrate are also disclosed.

The present invention relates to a method for producing ceramic gas-separation membranes, which comprises depositing, by means of inkjet printing, water-based inks that form layers of a gas separation membrane. More specifically, the method comprises at least the following steps forming a porous support (i) compatible with a functional separation layer; depositing on the support (i), by means of inkjet printing, at least one functional separation layer (ii) formed by at least two inks, and depositing at least one porous catalytic activation layer (iii) on the functional separation layer (ii); and performing at least one heat treatment, which produces sintering. The functional separation layer (ii) is deposited in a manner to produce a surface with fadings, patterns, or combinations thereof he invention also relates to a gas separation membrane produced using the described method.

The present invention relates to a method for producing ceramic gas-separation membranes, which comprises depositing, by means of inkjet printing, water-based inks that form layers of a gas separation membrane. More specifically, the method comprises at least the following steps forming a porous support (i) compatible with a functional separation layer; depositing on the support (i), by means of inkjet printing, at least one functional separation layer (ii) formed by at least two inks, and depositing at least one porous catalytic activation layer (iii) on the functional separation layer (ii); and performing at least one heat treatment, which produces sintering. The functional separation layer (ii) is deposited in a manner to produce a surface with fadings, patterns, or combinations thereof he invention also relates to a gas separation membrane produced using the described method.

Articles may be protected against halide plasma, by applying a rare earth-containing glaze to the surface of the article. The glaze may be a coating comprising; 20 to 90 mol % SiO.sub.2, 0 to 60 mol % Al.sub.2O.sub.3, 10 to 80 mol % rare earth oxides and/or rare earth fluorides (REX), wherein SiO.sub.2+Al.sub.2O.sub.3+REX≥60 mol %.

Articles may be protected against halide plasma, by applying a rare earth-containing glaze to the surface of the article. The glaze may be a coating comprising; 20 to 90 mol % SiO.sub.2, 0 to 60 mol % Al.sub.2O.sub.3, 10 to 80 mol % rare earth oxides and/or rare earth fluorides (REX), wherein SiO.sub.2+Al.sub.2O.sub.3+REX≥60 mol %.

A plurality of photocatalytic coated ceramic granules comprising base ceramic granules, each having an outer surface, and a photocatalytic coating disposed on the outer surface. The photocatalytic coating comprising an inorganic binder and a plurality of photocatalytic particles selected from TiO.sub.2, ZnO, Ti(OH).sub.4, doped derivatives thereof and combinations thereof. The photocatalytic particles have a surface area per weight of tire particles of no more than 30 square meters per gram (m.sup.2/g). The coated ceramic granules have a Total Solar Reflectance of at least 0.7.

A plurality of photocatalytic coated ceramic granules comprising base ceramic granules, each having an outer surface, and a photocatalytic coating disposed on the outer surface. The photocatalytic coating comprising an inorganic binder and a plurality of photocatalytic particles selected from TiO.sub.2, ZnO, Ti(OH).sub.4, doped derivatives thereof and combinations thereof. The photocatalytic particles have a surface area per weight of tire particles of no more than 30 square meters per gram (m.sup.2/g). The coated ceramic granules have a Total Solar Reflectance of at least 0.7.

An article includes a ceramic-based substrate and a barrier layer on the ceramic-based substrate. The barrier layer includes a matrix of barium-magnesium alumino-silicate or SiO.sub.2, a dispersion of silicon oxycarbide particles in the matrix, and a dispersion of particles, of the other of barium-magnesium alumino-silicate or SiO.sub.2, in the matrix.