The present disclosure provides a method for coating a composite structure, comprising forming a first slurry by combining a first pre-slurry composition with a first carrier fluid, applying the first slurry on a surface of the composite structure, and heating the composite structure to a temperature sufficient to form a base layer on the composite structure. The first pre-slurry composition may comprise a first phosphate glass composition and a low coefficient of thermal expansion material, wherein the low coefficient of thermal expansion material is a material with a coefficient of thermal expansion of less than 10×10.sup.−6° C..sup.−1.

Procedure for controlling the chemical reaction in multi-layer ceramic decorations, according to interfacial and surface properties, in which the ceramic coating formulation is broken down into two separate compounds: on the one hand, a bottom layer formed by a glaze with part of the necessary oxides to obtain the ceramic effect, applied in the conventional manner over the ceramic substrate, and on the other hand, a top layer formed by an ink with the other necessary part of the oxides, applied by injection over the previous layer. The ceramic product is finished off with a firing process. This procedure has the advantage of regulating the penetration of the oxides of the top layer throughout the profile of the bottom layer, thus achieving an adequate concentration of oxides in the zone nearest to the surface, which permits optimization of the chemical reaction and thus, of the ceramic effect obtained.

The present disclosure provides a method for coating a composite structure, comprising forming a first slurry by combining a glass frit comprising a first phosphate glass composition with a first carrier fluid comprising an acid aluminum phosphate, wherein the ratio of aluminum to phosphoric acid is between 1 to 2 and 1 to 3, applying the first slurry on a surface of the composite structure to form a base layer, and heating the composite structure to a temperature sufficient to adhere the base layer to the composite structure.

The present disclosure provides a method for coating a composite structure, comprising forming a first slurry by combining a glass frit comprising a first phosphate glass composition with a first carrier fluid comprising an acid aluminum phosphate, wherein the ratio of aluminum to phosphoric acid is between 1 to 2 and 1 to 3, applying the first slurry on a surface of the composite structure to form a base layer, and heating the composite structure to a temperature sufficient to adhere the base layer to the composite structure.

The present disclosure provides a method for coating a composite structure, comprising forming a first slurry by combining a first pre-slurry composition with a first carrier fluid, applying the first slurry on a surface of the composite structure, and heating the composite structure to a temperature sufficient to form a base layer on the composite structure. The first pre-slurry composition may comprise a first phosphate glass composition and a low coefficient of thermal expansion material, wherein the low coefficient of thermal expansion material is a material with a coefficient of thermal expansion of less than 10×10.sup.−6° C..sup.−1.

The present disclosure provides a method for coating a composite structure, comprising forming a first slurry by combining a first pre-slurry composition with a first carrier fluid, applying the first slurry on a surface of the composite structure, and heating the composite structure to a temperature sufficient to form a base layer on the composite structure. The first pre-slurry composition may comprise a first phosphate glass composition and a low coefficient of thermal expansion material, wherein the low coefficient of thermal expansion material is a material with a coefficient of thermal expansion of less than 10×10.sup.−6° C..sup.−1.

To provide a method for producing a calcium carbonate block for medical use which is useful as a bone substitute or a bone substitute raw material needed in medical care, which is a method for producing a calcium carbonate block that satisfies the following desired properties: 1) the calcium carbonate block has excellent mechanical strength; 2) the calcium carbonate block can be produced by a simplified production method; 3) the calcium carbonate block contains no impurity; and 4) the calcium carbonate block has high reactivity. A method for producing a calcium carbonate block, comprising a step of shaping a water-containing calcium hydroxide block and a carbonation step of immersing the calcium hydroxide block in a carbonate ion-containing aqueous solution.

To provide a method for producing a calcium carbonate block for medical use which is useful as a bone substitute or a bone substitute raw material needed in medical care, which is a method for producing a calcium carbonate block that satisfies the following desired properties: 1) the calcium carbonate block has excellent mechanical strength; 2) the calcium carbonate block can be produced by a simplified production method; 3) the calcium carbonate block contains no impurity; and 4) the calcium carbonate block has high reactivity. A method for producing a calcium carbonate block, comprising a step of shaping a water-containing calcium hydroxide block and a carbonation step of immersing the calcium hydroxide block in a carbonate ion-containing aqueous solution.

In one aspect, the present invention comprises providing an additive or aggregate to be applied directly to one or more of the components of a ceramic coating and which is constituted by carbonate apatites particles which are maintained as aggregates within a matrix of silicoaluminates at firing temperatures of the ceramic coatings, where the main function of these aggregates is to provide the ceramic coating properties selected from the group comprising: low effusivity, wear resistance, resistance to chemical attack and resistance to staining. In other aspects, the present invention comprises providing a ceramic coating incorporating said additive and a method for providing a ceramic coating with properties selected from the group comprising: low effusivity, wear resistance, resistance to chemical attack and resistance to staining.

In one aspect, the present invention comprises providing an additive or aggregate to be applied directly to one or more of the components of a ceramic coating and which is constituted by carbonate apatites particles which are maintained as aggregates within a matrix of silicoaluminates at firing temperatures of the ceramic coatings, where the main function of these aggregates is to provide the ceramic coating properties selected from the group comprising: low effusivity, wear resistance, resistance to chemical attack and resistance to staining. In other aspects, the present invention comprises providing a ceramic coating incorporating said additive and a method for providing a ceramic coating with properties selected from the group comprising: low effusivity, wear resistance, resistance to chemical attack and resistance to staining.