To form, on a ceramic member or a metal member, a thermal spray ceramic coating film which achieves both the quality of a ceramic coating film and gas barrier property, and with which a composite oxide having a melting point lower than the ambient temperature will not form when used as a coating film on a ceramic member or a metal member constituting a glass article manufacturing apparatus. A ceramic coating film-provided member comprising a ceramic member or a metal member and a thermal spray ceramic coating film formed on at least a part of the surface of the ceramic member or the metal member, wherein the thermal spray ceramic coating film contains Al.sub.2O.sub.3 and 12CaO.7Al.sub.2O.sub.3, and the weight ratio of CaO to Al.sub.2O.sub.3 (CaO/Al.sub.2O.sub.3) is more than 0.11 to 0.50.

An article for high temperature service is presented herein. One embodiment is an article including a substrate having a silicon-bearing ceramic matrix composite; and a layer disposed over the substrate, wherein the layer includes silicon and a dopant, the dopant including aluminum. In another embodiment, the article includes a ceramic matrix composite substrate, wherein the composite includes a silicon-bearing ceramic and a dopant, the dopant including aluminum; a bond coat disposed over the substrate, where the bond coat includes elemental silicon, a silicon alloy, a silicide, or combinations including any of the aforementioned; and a coating disposed over the bond coat, the coating including a silicate (such as an aluminosilicate or rare earth silicate), yttria-stabilized zirconia, or a combination including any of the aforementioned.

An article for high temperature service is presented herein. One embodiment is an article including a substrate having a silicon-bearing ceramic matrix composite; and a layer disposed over the substrate, wherein the layer includes silicon and a dopant, the dopant including aluminum. In another embodiment, the article includes a ceramic matrix composite substrate, wherein the composite includes a silicon-bearing ceramic and a dopant, the dopant including aluminum; a bond coat disposed over the substrate, where the bond coat includes elemental silicon, a silicon alloy, a silicide, or combinations including any of the aforementioned; and a coating disposed over the bond coat, the coating including a silicate (such as an aluminosilicate or rare earth silicate), yttria-stabilized zirconia, or a combination including any of the aforementioned.

A component of a plasma processing chamber having a coating on at least one surface that comprises yttrium aluminum. The coating is an aerosol deposited coating from a powder mixture of an yttrium oxide powder and an aluminum-containing powder and having an yttrium to aluminum ratio of 4:1 to 1:4 by molar number. The coating can be annealed to form a porous ternary oxide.

Granules for a roof coating, wherein said granules comprise particles that have a coating, wherein said coating comprises at least one layer of an inorganic powder in a binder, wherein said inorganic powder has a d50 grain size of from 0.5 to 25 μm, and wherein a hydrophobizing and/or oleophobizing agent is present on said coating.

Granules for a roof coating, wherein said granules comprise particles that have a coating, wherein said coating comprises at least one layer of an inorganic powder in a binder, wherein said inorganic powder has a d50 grain size of from 0.5 to 25 μm, and wherein a hydrophobizing and/or oleophobizing agent is present on said coating.

A coating method includes depositing a slurry including a coarsely particulate ceramic and a finely particulate ceramic on a base material configured with an oxide-based ceramics matrix composite such that a proportion of coarse particles decreases towards a surface of the base material; forming a bond coating by performing a heat treatment on the base material on which the slurry has been deposited; and forming a top coating by thermally spraying a ceramic onto the bond coating. The oxide-based ceramics matrix composite is an alumina silica type oxide-based ceramics matrix composite. The coarsely particulate ceramic and the finely particulate ceramic are alumina-based powder.

A coating method includes depositing a slurry including a coarsely particulate ceramic and a finely particulate ceramic on a base material configured with an oxide-based ceramics matrix composite such that a proportion of coarse particles decreases towards a surface of the base material; forming a bond coating by performing a heat treatment on the base material on which the slurry has been deposited; and forming a top coating by thermally spraying a ceramic onto the bond coating. The oxide-based ceramics matrix composite is an alumina silica type oxide-based ceramics matrix composite. The coarsely particulate ceramic and the finely particulate ceramic are alumina-based powder.

A coated component, along with methods of its formation and use, is provided. The coated component includes a ceramic matrix composite (CMC) substrate comprising silicon carbide and having a mullite bondcoat on its surface. The mullite bondcoat includes an oxygen getter phase contained within a mullite phase. For example, the mullite bondcoat may include 60% to 98% by volume of the mullite phase. An environmental barrier coating is on the mullite bondcoat.

A gas turbine engine article includes a substrate and a silicate-resistant barrier coating disposed on the substrate. The silicate-resistant barrier coating has an engineered microstructure that includes a refractory matrix formed of grains and calcium aluminosilicate additive (CAS additive) dispersed in grain boundaries between the grains.