Disclosed is a homogeneous catalyst having a single phase of Perovskite oxide, wherein at least one doping element is substituted at site A, site B or sites A and B in ABO.sub.3 Perovskite type oxide so that the wettability with a liquid molten carbonate electrolyte may be decreased. The catalyst may have high catalytic activity, inhibit catalyst poisoning caused by creepage and evaporation of a liquid molten carbonate electrolyte, maintain high reaction activity for a long time, provide high methane conversion, and allow production of synthetic gas having a high proportion of hydrogen.

Disclosed herein are refractory coating compositions with improved drying times, defect prevention, and gas permeability and methods for using such refractory coating compositions.

The invention relates to a material for storing and releasing oxygen, consisting of a reactive ceramic made of copper, manganese and iron oxides, wherein, subject to the oxygen partial pressure of a surrounding atmosphere and/or an ambient temperature, the reactive ceramic has a transition region that can be passed through any number of times, said transition region being between a discharge threshold state of a three-phase crednerite/cuprite/hausmannite mixed ceramic and a charge threshold state of a two-phase spinel/tenorite mixed ceramic. A passing through of the transition region from the discharge threshold state towards the charging threshold state is associated with oxygen uptake and a passing through of the transition region from the charge threshold state towards the discharge threshold state is associated with oxygen release.

Provided herein are nanofibers and processes of preparing carbonaceous nanofibers. In some embodiments, the nanofibers are high quality, high performance nanofibers, highly coherent nanofibers, highly continuous nanofibers, or the like. In some embodiments, the nanofibers have increased coherence, increased length, few voids and/or defects, and/or other advantageous characteristics. In some instances, the nanofibers are produced by electrospinning a fluid stock having a high loading of nanofiber precursor in the fluid stock. In some instances, the fluid stock comprises well mixed and/or uniformly distributed precursor in the fluid stock. In some instances, the fluid stock is converted into a nanofiber comprising few voids, few defects, long or tunable length, and the like.

Provided is a wear resistant, sintered body made of a binderless carbide, cermet or cemented carbide, e.g., WC, W2C and/or eta-phase, with a grain size less than 6.0 μm, and less than 6% binder phase (e.g., Co—Ni—Fe). At least some working surfaces of the sintered body are surface treated with a boron yielding method including applying a low viscosity liquid medium having boron or aluminum content and heating at 1200° C. to 1450° C. under a pressure less than atmospheric pressure or a hydrogen containing atmosphere to from a hardness gradient with an increased hardness of the treated working surfaces of at least 50 to 200 HV5 and favorable compressive stresses in a surface zone that gives a tougher working surfaces of the boronized sintered bodies.

The present invention relates to a zirconia mullite refractory composite comprising 55 wt.-% to 65 wt.-% Al.sub.2O.sub.3, 15 wt.-% to 25 wt.-% SiO.sub.2, 15 wt.-% to 25 wt.-% ZrO.sub.2 and less than 3 wt.-% raw material based impurities, whereby the mineralogical composition of the composite comprises 65 wt.-% to 85 wt.-% mullite and 15 wt.-% to 35 wt.-% zirconia.

Particulate high-emissivity (high-ε) refractory products include a mixture of (a) a particulate refractory base material which includes at least one particulate binder material, at least one particulate refractory raw material filler material and optionally at least one refractory additive; and (b) a high-ε pigment in an amount sufficient to impart high-ε properties to the refractory product when cured of at least 0.80. The high-ε pigment is homogenously dispersed throughout the particulate refractory base material and is thereby less susceptible to loss of high-ε properties over time. The particulate high-ε products may be formed into an castable wet mix, an aqueous slurry or an insulating aqueous foam and cured so as to provide a component part of a high temperature refractory structure (e.g., the walls or ceiling of a refractory furnace) having high-ε properties.

The present invention relates to an alumina fiber having a mass ratio (A/C) of the content (A) of iron oxide as expressed in terms of ferric oxide to the content (C) of titanium oxide of 2 to 121; and a mass ratio (B/C) of the content (B) of calcium oxide to the content (C) of titanium oxide of 0.4 to 14, with a sum total of the content (A) of iron oxide, the content (B) of calcium oxide, and the content (C) of titanium oxide being 0.0170 to 0.1180% by mass.

Methods of manufacturing a ceramic honeycomb body having a honeycomb structure with a matrix of intersecting walls, and a skin disposed on an outer peripheral portion of the matrix where the skin has a first average porosity and the interior portion of the matrix has a second average porosity that is greater than the first average porosity. The methods include coating at least the skin with a fluid formulation containing a sintering aid and subsequently firing the honeycomb structure. In certain embodiments, a glass layer is formed in the skin or in regions of the walls directly adjacent to the skin. In certain embodiments, the coating is applied to a green honeycomb structure, and in other embodiments the coating is applied to a ceramic honeycomb structure. Other honeycomb bodies and methods are described.

A sintered friction material, in which a content of a copper component is 0.5 mass % or less, is provided. The sintered friction material includes a titanate and a metal material other than copper, as a matrix. A content of the metal material other than copper is 10.0 volume % to 34.0 volume %. A method for manufacturing a sintered friction material is provided. The method includes a mixing step of mixing raw materials containing a titanate and a metal material other than copper, a molding step of molding the raw materials mixed in the mixing step, and a sintering step of sintering, at 900° C. to 1300° C., a molded product molded in the molding step. In the sintered friction material, the titanate and the metal material other than copper form a matrix, and a content of the metal material other than copper is 10.0 volume % to 34.0 volume %.