Disclosed herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also disclosed herein are lithium-stuffed garnet thin films having fine grains therein. Also disclosed herein are methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also disclosed herein are methods for preparing dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also disclosed herein are sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

A dielectric composition is provided. The dielectric composition includes a tungsten bronze type complex oxide expressed by a chemical formula (K.sub.1-xNa.sub.x)Sr.sub.2Nb.sub.5O.sub.15 as a main component, x satisfying 0x0.50, wherein the dielectric composition includes a secondary phase of at least one or more selected from: MgO.SiO.sub.2; BaO.2MgO.2SiO.sub.2; and 2MgO.B.sub.2O.sub.3; or the dielectric composition includes a tungsten bronze type complex oxide expressed by a chemical formula (K.sub.1-xNa.sub.x)Sr.sub.2Nb.sub.5O.sub.15 as a main component, x satisfying 0x0.40, wherein the dielectric composition includes: MgO; BaO; B.sub.2O.sub.3; SiO.sub.2; and P.sub.2O.sub.5 as a first accessory component in a total content of 2.5 mol to 20.0 mol per 100 mol of the main component.

Embodiments of synthetic garnet materials having advantageous properties, especially for below resonance frequency applications, are disclosed herein. In particular, embodiments of the synthetic garnet materials can have high Curie temperatures and dielectric constants while maintaining low magnetization. These materials can be incorporated into isolators and circulators, such as for use in telecommunication base stations.

The present disclosure provides a ceramic material containing a vanadium oxide, and 50 to 400 ppm by mass of nitrogen with respect to the vanadium oxide. The ceramic material according to the present disclosure less varies in the amount of heat absorption. A cooling device comprising the ceramic material is also provided.

Disclosed is a ceramic material having a formula of Li.sub.wA.sub.xM.sub.2Re.sub.3-yO.sub.z, wherein w is 5-7.5; wherein A is selected from B, Al, Ga, In, Zn, Cd, Y, Sc, Mg, Ca, Sr, Ba, and any combination thereof; wherein x is 0-2; wherein M is selected from Zr, Hf, Nb, Ta, Mo, W, Sn, Ge, Si, Sb, Se, Te, and any combination thereof; wherein Re is selected from lanthanide elements, actinide elements, and any combination thereof; wherein y is 0.01-0.75; wherein z is 10.875-13.125; and wherein the material has a garnet-type or garnet-like crystal structure. The ceramic garnet based material is ionically conducting and can be used as a solid state electrolyte for an electrochemical device such as a battery or supercapacitor.

Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also, the methods set forth herein disclose novel sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

Thermoelectric materials based on tetrahedrite structures for thermoelectric devices and methods for producing thermoelectric materials and devices are disclosed.

Disclosed herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also disclosed herein are lithium-stuffed garnet thin films having fine grains therein. Also disclosed herein are methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also disclosed herein are methods for preparing dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also disclosed herein are sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

A dielectric composition and a multilayer ceramic capacitor containing the same are provided. The dielectric composition contains an oxide of Ba and Ti as a main ingredient, and the main ingredient is represented by (Ba.sub.1-x(Na, Ca).sub.x)TiO.sub.3, where 0.005x0.035 and 0.994<(Ba.sub.1-x(Na, Ca).sub.x)/Ti<1.003.

Disclosed are embodiments of isolator/circulator junctions that can be used for radio-frequency (RF) applications, and methods of manufacturing the junctions. The junctions can have excellent impedance matching, even as they are being miniaturized, providing significant advantages over previously used junctions. The junctions can be formed of both high and low dielectric constant material.