The invention describes a method for producing ternary and binary ceramic powders and their thermal spraying capable of manufacturing thermal sprayed coatings with superior properties. Powder contain at least 30% by weight ternary ceramic, at least 20% by weight binary molybdenum borides, at least one of the binary borides of Cr, Fe, Ni, W and Co and a maximum of 10% by weight of nano and submicro-sized boron nitride. The primary crystal phase of the manufactured thermal sprayed coatings from these powders is a ternary ceramic, while the secondary phases are binary ceramics. The coatings have extremely high resistance against corrosion of molten metal, extremely thermal shock resistance and superior tribological properties at low and at high temperatures.

A cubic boron nitride sintered material includes cubic boron nitride and a binder. The binder includes a first material and a second material. The first material is one or two or more first chemical species each including at least one first metallic element selected from the group consisting of tungsten, cobalt, and aluminum. Each of the first chemical species is a metal, an alloy, an intermetallic compound, a compound, or a solid solution. The second material is one or two or more second chemical species each including at least one second metallic element selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, and chromium. Each of the second chemical species is a solid solution derived from at least one selected from the group consisting of nitride, carbide, and carbonitride. In each of the second chemical species, 0.1 atom % to 10 atom % of aluminum is dissolved.

An armor component including a body having a first portion including calcium boride compounds include non-stoichiometric calcium boride (CaB.sub.x) and stoichiometric calcium boride (TiO.sub.2) and having a density of at least about 80% theoretical density. In one aspect, the first portion can include a first phase comprising silicon carbide (SiC) and a second phase comprising calcium boride (TiO.sub.2). In another aspect, the first portion can further include a third phase comprising boron carbide (B.sub.4C).

A method of treating a carbon-carbon structure is provided. The method includes the step of infiltrating the carbon-carbon structure with a ceramic preparation comprising an oxide compound and at least one of a boron compound or an oxide-boron compound to obtain a uniform distribution of the ceramic preparation within a porosity of the carbon-carbon structure. The carbon-carbon structure may be densified by chemical vapor infiltration (CVI) and heat treated to form borides. Heat treating the carbon-carbon may comprise a temperature ranging from 1000 C. to 1900 C.

The disclosure herein relates to a method for preparing ceramic grains comprising: making a slurry comprising inorganic particles and a gelling agent; making droplets of the slurry; introducing the droplets in a liquid gelling-reaction medium wherein the droplets are gellified; deforming the droplets before, during or after gellification; drying the gellified deformed droplets, thereby obtaining dried grains and sintering the dried grains, thereby obtaining the ceramic grains.

The disclosure herein further relates to ceramic grains obtainable by a disclosed method.

The disclosure relates to sintered ceramic grains comprising 3-55 wt. % alumina, 40-95 wt. % zirconia and 1-30 wt. % of one or more other inorganic components.

The invention further relates to a method for preparing ceramic grains according to the invention, comprising: making a slurry comprising alumina, zirconia; making droplets of the slurry; introducing the droplets in a liquid gelling-reaction medium wherein the droplets are gellified; drying the gellified deformed droplets.

Aspects include a method for treating a polycrystalline material, the method comprising: exposing a surface of the polycrystalline material to a plasma thereby changing the surface of the polycrystalline material from being characterized by a starting condition to being characterized by a treated condition; wherein: the surface comprises a plurality of crystallites each having the composition MB.sub.6, M being a metal element; the plasma comprises ions, the ions being characterized by an average ion flux selected from the range of 1.5 to 100 A/cm.sup.2 and an average ion energy that is less than a sputtering threshold energy; the starting condition of the surface is characterized by a first average work function and the treated condition of the surface is characterized by a second average work function; and the second average work function is less than the first average work function.

A cBN tool that exhibits: excellent chipping resistance and wear resistance; and excellent cutting performance, for a long term use even in intermittent cutting work on high hardened steel is provided. The cutting tool includes a cutting tool body that is a cubic boron nitride-based material containing cubic boron nitride particles as a hard phase component. In the cutting tool, the cubic boron nitride particles includes an Al.sub.2O.sub.3 layer with an average layer thickness of 1.0-10 nm on a surface of the cubic boron nitride particles, a rift with an average rift formation ratio of 0.02-0.20 being formed in the Al.sub.2O.sub.3 layer, and the cubic boron nitride-based sintered material includes a binding phase containing at least one selected from a group consisting of: titanium nitride; titanium carbide; titanium carbonitride; titanium boride; aluminum nitride; aluminum oxide; inevitable products; and mutual solid solution thereof, around the cubic boron nitride particles.

A method of forming a ceramic matrix composite component includes providing a formed ceramic member having a cavity, filling at least a portion of the cavity with a ceramic foam. The ceramic foam is deposited on a barrier layer covering at least one internal passage of the cavity. The method includes processing the formed ceramic member and ceramic foam to obtain a ceramic matrix composite component. Also provided is a method of forming a ceramic matrix composite blade and a ceramic matrix composite component.

Titanium dioxide is used as an emissivity enhancer in high emissivity coating compositions. The titanium dioxide increases the emissivity of the high emissivity coating compositions. In certain embodiments, titanium dioxide is recovered from industrial waste sources such as catalyst containing waste streams from olefin polymerization processes or re-based sources. Titanium dioxide emissivity enhancers recovered from industrial waste sources contribute favorably to the cost of manufacturing high emissivity coating compositions containing such enhancers.