A complex ceramic particle and ceramic composite material may be made of a pretreated coal dust and a polymer derived ceramic that is mixed together and pyrolyzed in a nonoxidizing atmosphere. Constituent portions of the particle mixture chemically react causing particles to increase in density and reduce in size during pyrolyzation, yielding a particle suitable for a plurality of uses including composite articles and proppants.

A monolithic carbon foam formed of fused onion-like carbon (OLC) nanoparticles, in which the monolithic carbon foam contains interconnected pores, has a volumetric micropore surface area of 200 m.sup.2/cc-600 m.sup.2/cc, and has an electrical conductivity of 20 cm- 140 S/cm. Also disclosed are a fractal carbon foam prepared from the monolithic carbon foam, methods of preparing both foams, and supercapacitors constructed therefrom. Specifically, the methods of preparing the foams comprising, inter alia, spark plasma sintering the OLC nanoparticles at a pressure of 30 MPa-1000 MPa and a temperature of 300° C.-800° C. for 2 seconds-30 minutes.

A negative thermal expansion material made of zirconium phosphate tungstate containing an Al atom, and having a thermal expansion coefficient of −2.0×10.sup.−6 to −3.3×10.sup.−6/K. According to the present invention, a negative thermal expansion material made of zirconium phosphate tungstate having various thermal expansion coefficients, and an industrially advantageous manufacturing method thereof can be provided.

A sulfide-based solid electrolyte contains a nickel (Ni) element and a halogen element. For example, a sulfide-based solid electrolyte can include, with respect to 100 parts by mole of a mixture of lithium sulfide (Li.sub.2S) and diphosphorus pentasulfide (P.sub.2S.sub.5), 5 parts by mole to 20 parts by mole of nickel sulfide (Ni.sub.3S.sub.2), and 5 parts by mole to 40 parts by mole of lithium halide.

The invention discloses a method of making waterproof magnesium oxychloride refractory brick using fly ash from municipal solid waste incineration (MSWFA). The solidification and stabilization of heavy metals in MSWFA is achieved by the chemical action of a sulfur-containing compound and a physical wrapping of a geopolymer. The large amount of chloride ions in MSWFA is also reused in the manufacture of magnesium oxychloride refractory brick, which requires a high chlorine environment. This method, with the inclusion of the geopolymer, also produces refractory brick exhibiting improved water resistance relative to traditional magnesium oxychloride refractory brick, thereby allowing the improved magnesium oxychloride refractory brick to be used in a wider range of applications.

The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contracts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region and spatially disposed within spatial regions not occupied by the first active regions. In an example, the catholyte material comprises a lithium, germanium, phosphorous, and sulfur (“LGPS”) containing material configured in a polycrystalline state. The device has an oxygen species configured within the LGPS containing material, the oxygen species having a ratio to the sulfur species of 1:2 and less to form a LGPSO material. The device has a protective material formed overlying exposed regions of the cathode material to substantially maintain the sulfur species within the catholyte material. Also included is a novel dopant configuration of the Li.sub.aMP.sub.bS.sub.c (LMPS) [M=Si,Ge, and/or Sn] containing material.

A method of preparation of an article having a sliding surface and comprising graphitic particles, comprises the steps of: i) impregnating open porosity in a porous body with a resin comprising graphitic particles; and ii) hardening said resin.

The present invention relates to a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries. The a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries includes a compound with an argyrodite-type crystal structure represented by the following Formula 1:

Li.sub.aPS.sub.bN.sub.cX.sub.d  [Formula 1] wherein 6≤a≤7, 3<b<6, 0<c≤1, 0<d≤2, and each X is the same or different halogen atom selected from the group consisting of chlorine (Cl), bromine (Br), and iodine (I).

The present invention relates to a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries. The a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries includes a compound with an argyrodite-type crystal structure represented by the following Formula 1:

Li.sub.aPS.sub.bN.sub.cX.sub.d  [Formula 1]

wherein 6≤a≤7, 3≤b≤6, 0≤c≤1, 0≤d≤2, and

each X is the same or different halogen atom selected from the group consisting of chlorine (Cl), bromine (Br), and iodine (I).

The present invention relates to a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries. The a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries includes a compound with an argyrodite-type crystal structure represented by the following Formula 1:

Li.sub.aPS.sub.bN.sub.cX.sub.d   [Formula 1] wherein 6≤a≤7, 3<b<6, 0<c≤1, 0<d≤2, and each X is the same or different halogen atom selected from the group consisting of chlorine (Cl), bromine (Br), and iodine (I).