At least partial substitution of zirconium by hafnium in ion-conducting zirconium-based ceramics provides enhanced chemical stability in alkaline and acid environments.

The present disclosure provides a method for producing beta-tricalcium phosphate spherical particles containing magnetic ions. The method includes mixing acidic amino acid monomers, metal salt of magnetic ions and metal salt of calcium ions in de-ionized water to form a first solution; dissolve phosphate in de-ionized water to form a second solution; mixing the first and second solutions to form a third solution; and performing hydrothermal synthesis of the third solution.

This disclosure relates to an inorganic-organic metal phosphate ceramic coating from the reaction of an inorganic phosphate of the formulas (i) A.sub.m(H.sub.2PO.sub.4).sub.m.nH.sub.2O or (ii) AH.sub.3(PO.sub.4).sub.2.nH.sub.2O; where A is ammonium or an m-valent metal element; m=1, 2, or 3; and n is 0 to 25; and at least one metal oxide or hydroxide represented by the formula B.sub.2mO.sub.m or B(OH).sub.2m, where B is a 2m-valent metal; and m=1 or 1.5; thereof; and at least one polymer capable of reacting with at least the one metal oxide or hydroxide; or a first organic precursor combined with the inorganic phosphate and a second organic precursor combined with the at least one metal oxide or hydroxide, the second organic precursor configured to chemically react with the one or more first organic precursor.

The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contracts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region and spatially disposed within spatial regions not occupied by the first active regions. In an example, the catholyte material comprises a lithium, germanium, phosphorous, and sulfur (“LGPS”) containing material configured in a polycrystalline state. The device has an oxygen species configured within the LGPS containing material, the oxygen species having a ratio to the sulfur species of 1:2 and less to form a LGPSO material. The device has a protective material formed overlying exposed regions of the cathode material to substantially maintain the sulfur species within the catholyte material. Also included is a novel dopant configuration of the Li.sub.aMP.sub.bS.sub.c (LMPS) [M=Si, Ge, and/or Sn] containing material.

Highly dense lithium based ceramics can be prepared by a low temperature process including combining a lithium based ceramic with a polar solvent having a lithium based salt dissolved therein and applying pressure and heat to the combination to form a salt-ceramic composite. Advantageously, the lithium salt is one that dissolves in the polar solvent and the heat applied to the combination is no greater than about 250° C. Such composites can also have high ionic conductivity.

Method for manufacturing a composite material part includes injecting a slurry containing a refractory ceramic particle powder into a fibrous texture, draining the liquid from the slurry that passed through the fibrous texture and retaining the refractory ceramic particle powder inside said texture so as to obtain a fibrous preform loaded with refractory ceramic particles, and demoulding of the fibrous preform. The method includes, after demoulding the fibrous preform, checking the compliance of the demoulded fibrous preform. If the preform is noncompliant, the method also includes, before a sintering, immersing the demoulded fibrous preform in a bath of a liquid suitable for decompacting the refractory ceramic particles present in the fibrous preform, and additionally injecting a slurry containing a refractory ceramic particle powder into the fibrous preform present in the mould cavity.

A nano-inorganic composition according to an embodiment of the present disclosure includes and is not limited to excellent mechanical characteristics such as surface hardness and wear characteristics, chemical stability such as water resistance, acid resistance, and alkali resistance, and excellent thermal stability, as the composition is comprised of inorganic materials. In addition, the nano-inorganic composition may be controlled to have super-hydrophilic, hydrophilic, or hydrophobic properties, depending on coating methods. The nano-inorganic composition also has excellent surface contamination resistance and easy-clean properties depending on the characteristics of the thin film coating. Also, the nano-inorganic composition has excellent optical properties such as light transmittance and light reflectance.

Methods of making a ceramic of a Group 13-15 type or a Group 13-15-16 type by thermolyzing a discrete molecular precursor to the ceramic in an oxygen-containing atmosphere. In some embodiments, the discrete molecular precursor is bench-stable and comprises a Lewis acid-base pair or small cyclic compound containing at last one Group 13 element and at least one Group 15 element but does not include indium and phosphorus in combination with one another unless a Group 16 element is present. The thermolysis can be carried out in air, at atmospheric pressure, and at a temperature below about 400° C., if desired. In some embodiments, the discrete molecular precursor can be placed in a mold having a desired shape and the thermolysis performed while the discrete molecular precursor is in the mold so as to produce a ceramic product having the desired shape.

A main object of the present disclosure is to provide a sulfide solid electrolyte with excellent water resistance. The present disclosure achieves the object by providing a sulfide solid electrolyte including a LGPS type crystal phase, and containing Li, Ge, P, and S, wherein: when an X-ray photoelectron spectroscopy measurement is conducted to a surface of the sulfide solid electrolyte, a proportion of Ge.sup.2+ with respect to total amount of Ge is 20% or more.

A multilayer ceramic capacitor that includes a ceramic body including a stack of a plurality of dielectric layers and a plurality of first and second internal electrodes; and first and second external electrodes provided at each of both end faces of the ceramic body. Each of the plurality of dielectric layers contain Ba, Ti, P and Si. The plurality of dielectric layers include an outer dielectric layer located on an outermost side in the stacking direction; an inner dielectric layer located between the first and second internal electrodes; and a side margin portion in a region where the first and second internal electrodes do not exist. In at least one of the outer dielectric layer, the inner dielectric layer and the side margin portion, the P and the Si segregate in at least one of grain-boundary triple points of three ceramic particles.