A nitrogen-containing porous carbon material, and a capacitor and a manufacturing method thereof are provided. A carbon material, a macromolecular material and a modified material are mixed into a preform. The modified material includes nitrogen. A formation process is performed on the preform to obtain a formed object. High-temperature sintering is performed on the formed object to decompose and remove a part of the macromolecular material, while the other part of the macromolecular material and the carbon material together form a backbone structure including a plurality of pores. As such, the nitrogen becomes attached to the backbone structure to form a hydrogen-containing functional group to further obtain the nitrogen-containing porous carbon material. The nitrogen-containing porous carbon material may form a first nitrogen-containing porous carbon plate and a second nitrogen-containing porous carbon plate, which are placed in seawater to form a storage capacitor for seawater.

The present invention provides a lead-free piezoelectric material having a high piezoelectric constant and a high mechanical quality factor in a wide operating temperature range. The piezoelectric material includes a perovskite-type metal oxide represented by Formula (1):
(Ba.sub.1-xCa.sub.x).sub.a(Ti.sub.1-yZr.sub.y)O.sub.3 (1.00≦a≦1.01, 0.125≦x<0.155, and 0.041≦y≦0.074)
as a main component. The metal oxide contains Mn in a content of 0.12 parts by weight or more and 0.40 parts by weight or less based on 100 parts by weight of the metal oxide on a metal basis.

Isopipes (13) for making glass sheets using a fusion process are provided. The isopipes are made from alumina materials which have low levels of the elements of group IVB of the periodic chart, i.e., Ti, Zr, and Hf, as well as low levels of Sn. In this way, the alumina isopipes can be used with glasses that contain tin (e.g., as a fining agent or as the result of the use of tin electrodes for electrical heating of molten glass) without generating unacceptable levels of tin-containing defects in the glass sheets, specifically, at the sheets' fusion lines. The alumina isopipes disclosed herein are especially beneficial when used with tin-containing glasses that exhibit low tin solubility, e.g., glasses that have (RO+R.sub.2O)/Al.sub.2O.sub.3 ratios between 0.9 and 1.1, where, in mole percent on an oxide basis, (RO+R.sub.2O) is the sum of the concentrations of the glass' alkaline earth and alkali metal oxides and Al.sub.2O.sub.3 is the glass' alumina concentration.

Provided herein are nanofibers and processes of preparing carbonaceous nanofibers. In some embodiments, the nanofibers are high quality, high performance nanofibers, highly coherent nanofibers, highly continuous nanofibers, or the like. In some embodiments, the nanofibers have increased coherence, increased length, few voids and/or defects, and/or other advantageous characteristics. In some instances, the nanofibers are produced by electrospinning a fluid stock having a high loading of nanofiber precursor in the fluid stock. In some instances, the fluid stock comprises well mixed and/or uniformly distributed precursor in the fluid stock. In some instances, the fluid stock is converted into a nanofiber comprising few voids, few defects, long or tunable length, and the like.

The present document generally relates to additive manufacturing techniques for forming an article having a desired shape and other properties. More particularly, but not exclusively, in one embodiment a method for additive manufacturing an article includes adding a dispersant to an article forming material in the absence of binder to prepare a slurry or suspension including the material and the dispersant. The pH of the slurry may be adjusted to control the viscosity and/or coagulation rate of the slurry. The slurry may then be passed through an extrusion-based three-dimensional printing apparatus to form or print the article in a desired form or shape, and the article may thereafter be sintered. In one aspect, through control of the pH of the slurry, the viscosity and/or coagulation rate properties of the slurry may be tailored for use with different operating parameters of the extrusion-based three-dimensional printing apparatus.

The present disclosure relates to a dental ceramic article comprising ceramic components, the ceramic components having ZrO2 and Al2O3 and at least one component comprising Mn, Er or mixtures thereof, Al2O3 being present in an amount below about 0.15 wt.-% with respect to the weight of the ceramic article. The present disclosure relates also to kit of parts comprising a ceramic article and a coloring solution and processes for producing a dental ceramic article.

The invention relates to a coloured zirconia ceramic dental mill blank having fluorescing properties, processes of production such a mill blank and uses thereof, in particular for producing zirconia ceramic dental restorations.

The dental mill blank having a shape allowing the dental mill blank to be attached or fixed to a machining device, the dental mill blank comprising a porous zirconia material, the porous zirconia material comprising the oxides Zr oxide calculated as ZrO.sub.2: from about 80 to about 97 wt.-%, Al oxide calculated as Al.sub.2O.sub.3: from about 0 to about 0.15 wt.-%, Y oxide calculated as Y.sub.2O.sub.3: from about 1 to about 10 wt.-%, Bi oxide calculated as Bi.sub.2O.sub.3: from about 0.01 to about 0.20 wt.-%, Tb oxide calculated as Tb.sub.2O.sub.3: from about 0.01 to about 0.8 wt.-%, and optionally one or two of the following oxides: Er oxide calculated as Er.sub.2O.sub.3: from about 0.01 to about 3.0 wt.-%, Mn oxide calculated as MnO.sub.2: from about 0.0001 to about 0.08 wt.-%, wt.-% with respect to the weight of the porous zirconia material.

(i) a step of disposing a powder that includes an absorber absorbing light of a wavelength included in a laser beam to be irradiated and silicon dioxide as a main component; (ii) a step of sintering or melting and solidifying the powder by irradiating the powder with a laser beam; and (iii) a step of heat-treating a shaped object formed by repeating the steps (i) and (ii) at 1470° C. or more and less than 1730° C.

[Problem]

To support the metal without segregation on the zirconia mill blank for dental cutting and machining which has been adjusted to a hardness that enables to cut and machine by calcining at a low temperature.

[Solution]

A zirconia mill blank for dental cutting and machining is prepared by A preparing method of a zirconia mill blank for dental cutting and machining, comprising an impregnation step of impregnating a porous zirconia molded body with an impregnating solution containing at least one metal ion and at least one precipitant, and a deposition step of decomposing the precipitant in the porous zirconia molded body to deposit a metal compound.

An object of the present invention is to provide zirconium oxide nanoparticles that have excellent dispersibility in a polar solvent and are capable of increasing a core concentration in a dispersion liquid. Zirconium oxide nanoparticles according to the present invention are coated with at least one compound selected from the group consisting of R.sup.1—COOH, (R.sup.1O).sub.3-n—P(O)—(OH).sub.n, (R.sup.1).sub.3-n—P(O)—(OH).sub.n, (R.sup.1O)—S(O)(O)—(OH), R.sup.1—S(O)(O)—(OH), and (R.sup.1).sub.4-m—Si(R.sup.4).sub.m, wherein R.sup.1 represents a group comprising a carbon atom and at least one element selected from the group consisting of an oxygen atom, a nitrogen atom, and a sulfur atom, and having the total number of carbon atoms, oxygen atoms, nitrogen atoms, and sulfur atoms of 8 or less; R.sup.4 represents a halogen atom or —OR.sup.2, and R.sup.2 represents a hydrogen atom or an alkyl group; and n represents 1 or 2, and m represents an integer of 1 to 3.