Provided herein are methods for making a freeze-cast material having a internal structure, the methods comprising steps of: determining the internal structure of the material, the internal structure having a plurality of pores, wherein: each of the plurality of pores has directionality; and the step of determining comprises: selecting a temperature gradient and a freezing front velocity to obtain the determined internal structure based on the selected temperature gradient and the selected freezing front velocity; directionally freezing a liquid formulation to form a frozen solid, the step of directionally freezing comprising: controlling the temperature gradient and the freezing front velocity to match the selected temperature gradient and the selected freezing front velocity during directionally freezing; wherein the liquid formulation comprises at least one solvent and at least one dispersed species; and subliming the at least one solvent out of the frozen solid to form the material.

A dielectric ceramic composition that contains an oxide of A, R, and B and an oxide of Mn. The A is at least one selected from the group consisting of K and Na. The R is at least one selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y, and Sc. The B is at least one selected from the group consisting of Nb and Ta. The molar ratio of the A:R:B:Mn is 2−x:1+x/3:5+y:z. The x, y, and z satisfy −0.3≤x≤0.6, −0.5≤y≤0.5, and 0.001≤z≤0.5, respectively.

A method for layer-wise additive manufacturing of a shaped body made up of slices of processed layers, including the steps: creating a layer of a slurry, the slurry including binder, a dispersing medium and a particulate filler material, solidifying the slurry layer, directing electromagnetic radiation to the solidified layer for processing it by debinding and/or sintering, and repeating the above-mentioned steps to successively build the shaped body.

A laser induced forward transfer (LIFT) process utilizing a laser to direct laser beam pulses acts on a coating of slurry on a carrier to transfer droplets of slurry to a receptor surface to create the slurry layer which is then processed further by above-mentioned steps of solidifying, and debinding and/or sintering.

The invention relates to a porous zirconia article in particular for use in the dental or orthodontic field, the porous zirconia article comprising ZrO.sub.2: 80 to 87 wt. %, Y.sub.2O.sub.3: 3 to 5 wt. %, Al.sub.2O.sub.3: 10 to 14 wt. %, wt. % with respect to the weight of the porous zirconia article, the porous zirconia article being characterized by a BET surface from 15 to 100 m.sup.2/g. The invention also relates to a sintered zirconia article in particular for use in the dental or orthodontic field, the sintered zirconia article comprising ZrO.sub.2: 80 to 87 wt. %, Y.sub.2O.sub.3: 3 to 5 wt. %, Al.sub.2O.sub.3: 10 to 14 wt. %, wt. % with respect to the weight of the porous zirconia article, the sintered zirconia article being characterized by a corundum crystal phase content of 7 to 12 wt. % and a flexural strength of at least 2,000 MPa.

The present invention provides a zirconia pre-sintered body that can be fired into a sintered body having translucency and strength suited for dental use (particularly, at the dental clinic), even with a short firing time. The present invention relates to a zirconia pre-sintered body comprising: zirconia; and a stabilizer capable of inhibiting a phase transformation of zirconia, wherein the zirconia predominantly comprises a monoclinic crystal system, and the zirconia pre-sintered body comprises a plurality of layers that differ from each other in the content of the stabilizer relative to the total mole of the zirconia and the stabilizer.

The present invention relates to sintered platelet-like randomly shaped abrasive particles based on alpha alumina having a hardness H.sub.V of at least 20 GPa and a crystal structure with an average crystal size between 100 nm and 300 nm, whereby the abrasive particles comprise a body having a first surface and a second surface opposite to the first surface, both surfaces are separated from each other by a randomly shaped sidewall having a thickness (T) between 20 μm and 500 μm.

The method for manufacturing a solid electrolyte using an LLZ material for a lithium-ion battery comprises the steps of: providing a starting material in which lanthanum nitrate [La(NO.sub.3).sub.3.6H.sub.2O] and zirconium nitrate [ZrO(NO.sub.3).sub.2.6H.sub.2O] are mixed at a mole ratio of 3:2; forming an aqueous solution by dissolving the starting material; forming a precipitate by putting ammonia, which is a complex agent, and sodium hydroxide, which adjusts the pH of a reactor, into the aqueous solution, mixing the same, and then co-precipitating the mixture; forming a primary precursor powder by cleaning, drying and pulverizing the precipitate; forming a secondary precursor powder by mixing lithium powder [LiOH.H2O] with the primary precursor powder and ball-milling the mixture so as to solidify the lithium; and forming a solid electrolyte powder by heat-treating the secondary precursor powder.

A method of forming a composite material for use as an isolator or circulator in a radiofrequency device comprises providing a low temperature fireable outer material, the low fireable outer material having a garnet or scheelite structure, inserting a high dielectric constant inner material having a dielectric constant above 30 within an aperture in the low temperature fireable outer material, and co-firing the lower temperature fireable outer material and the high dielectric constant inner material together at temperature between 650-900° C. to shrink the low temperature fireable outer material around an outer surface of the high dielectric constant inner material to form an integrated magnetic/dielectric assembly without the use of adhesive or glue.

A ceramic containing, in mass %: Si.sub.3N.sub.4: 20.0 to 60.0%, ZrO.sub.2: 25.0 to 70.0%, at least one selected from SiC and AlN: 2.0 to 17.0%, where AlN is 10.0% or less, at least one selected from MgO, Y.sub.2O.sub.3, CeO.sub.2, CaO, HfO.sub.2, TiO.sub.2, Al.sub.2O.sub.3, SiO.sub.2, MoO.sub.3, CrO, CoO, ZnO, Ga.sub.2O.sub.3, Ta.sub.2O.sub.5, NiO and V.sub.2O.sub.5: 5.0 to 15.0%, wherein Fn calculated from the following equation (1) satisfies 0.02 to 0.40. This ceramic can be laser machined with high efficiency.

Fn=(SiC+3AlN)/(Si.sub.3N.sub.4+ZrO.sub.2)  (1)

A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.