A man-made aggregate or a masonry unit may be made by adding impound residues and mixing the impound residues with other residues, ceramic materials and/or additives to form an admixture. The impound residues may also be mixed with synthetic or organic polymers. The impound residues may not conform to the requirements of ASTM C618-15. The admixture may be subjected to a thermal process that allows for a ceramic conversion of the ceramic components of the mix used.

A dental block for producing a dental prosthesis comprises a green body including zirconia and having a chemical composition including containing between 6.0 wt % or 7.5 wt % to 20 wt % of yttria (Y.sub.2O.sub.3). The green body has multiple different layers having a different chemical composition between adjacent layers. The green body has a pre-sintered translucency that is substantially the same across the multiple different layers, and subsequently has a post-sintered translucency and a post-sintered color intensity/chroma with an inverse relationship with the post-sintered translucency increasing in one direction across the multiple different layers and the post-sintered color intensity/chromes decreasing in the same direction across the multiple different layers. The green body can have a color component and a diameter of at least 90 mm and thickness of 10-25 mm.

A ceramic slurry for forming a ceramic article includes a binder, a first plurality of ceramic particles having a first morphology, a second plurality of ceramic particles having a second morphology that is different from the first morphology; and a photoinitiator. A method for using this slurry for fabricating ceramic articles is presented as well.

A process for producing a non-dense sintered ceramic molded body having at least two layers, wherein a first powdery ceramic material forming a layer is contacted with at least a second powdery material forming at least a second layer; said first powdery material has a presintering temperature T.sub.1 that is higher than the presintering temperature T.sub.s of said at least second powdery ceramic material; the course of a curve of shrinkage S.sub.1 of said at least first powdery ceramic material differs from the course of a curve of shrinkage S.sub.2 of said at least second powdery material, wherein curve of shrinkage S.sub.1 is shifted towards higher temperatures as compared to curve of shrinkage S.sub.2; and the layers are subjected to a common temperature treatment at a presintering temperature T.sub.s that is lower than the presintering temperature T.sub.1 and at least equal to T.sub.3 to cause sintering that remains in a stage of sintering that has not proceeded to the theoretical density; wherein the curve of shrinkage S.sub.1 is modified by admixing at least one component having a curve of shrinkage S.sub.3 which material is compatible with said powdery ceramic material into said first powdery ceramic material, i. e. has a grain size smaller than the first powdery ceramic material, to equalize the curves of shrinkage S.sub.1 and S.sub.2 in the region of the presintering temperature T.sub.s.

In an embodiment a method for producing a substrate includes forming a green sheet stack including first green sheets and second green sheets, wherein each of the first green sheets and the second green sheets contains a ceramic material as a main component, and wherein the second green sheets further contain a sintering aid in addition to the ceramic material.

A system and method of constructing a 4D-printed ceramic object includes extruding inks including particles and polymeric ceramic precursors through a nozzle to deposit the inks on a heating plate, whereby a 3D-printed elastomeric object is formed on the heating plate, folding the 3D-printed elastomeric object into a complex structure to form a 4D-printed pre-strained elastomeric object, and converting the 4D-printed elastomeric object into the 4D-printed ceramic object.

Provided is a light-transmissive zirconia sintered body, obtained by preparing a green body from a powder for the light-transmissive zirconia sintered body by means of isostatic pressing, and sintering the green body at a high temperature and normal pressure after degreasing and biscuit firing. The light-transmissive zirconia sintered body is prepared by dispersing zirconia powder in water, adding an appropriate amount of a dispersant and a binder, mixing the mixture to form a slurry, and spray-granulating same, wherein the molar percentage of yttrium oxide in the zirconia powder is 3-5%. The light-transmissive zirconia sintered body can be used for preparing a fixed dental prosthesis.

A method of producing a component of a composite of diamond and a binder, wherein a Hot Isostatic gas Pressure process (HIP) is used, includes the step of enclosing a de-bound green body having compacted diamond particles in an infiltrant. The method includes the further steps of enclosing the de-bound green body and the infiltrant in a Zr-capsule that has Zirconium as a main constituent and sealing the Zr-capsule, and applying a predetermined pressure-temperature cycle on the unit formed by the de-bound green body, infiltrant and capsule in which the infiltrant infiltrates the de-bound green body and the de-bound green body is further densified in the sense that the volume thereof is decreased.

A composition for a refractory material comprising a base mixture having a composition in oxide (mol %) as follows: SiO2 between 69% and 73%; Al2O3 between 22% and 28%; TiO2 between 0.4% and 1%; Fe2O3 between 0.2% and 1%; CaO between 0.1% and 1%; MgO between 0.1% and 1%; K.sub.2O between 0.5% and 2%; Na.sub.2O between 0.1% and 0.5%; and comprising a filler mixture comprising at least one from between a schamotte and a smelting agent.

A dental block for producing a dental prosthesis comprises a green body including zirconia and having a chemical composition including increasing amounts of a chroma component, such as manganese, through a thickness of the green body. The green body is substantially white with a substantially consistent optical characteristic of chroma across the thickness, and is subsequently millable and sinterable to form the dental prosthesis with an optical characteristic of decreasing gray color through a thickness of the dental prosthesis.