A method of forming an article that includes a composite including graphite is disclosed. The article is suitable for containing or processing a molten metal such as aluminum. The method includes forming at least one granulated mixture by mixing at least carbon black, flake graphite, needle coke with at least one resin, the at least one resin has a flow distance, as measured by ISO 8619:2003, from 20 mm to 150 mm. The method further includes shaping the granulated mixture into a shaped body and firing the shaped body.

A single crystal ceramic core composition has an inorganic portion and an organic portion. The inorganic portion makes up about 85% by weight of the total weight of the ceramic core composition, and the organic portion makes up about 15% by weight of the total weight of the ceramic core composition. The inorganic portion includes about 94 to about 98% by weight spherical fused silica, and about 2 to about 6% by weight zircon. The organic portion includes about 84 to 88% by weight binder, about 1 to 2% by weight dye, about 6 to about 12% by weight surfactant, and about 1 to about 5% by weight polymeric fiber.

A device and method of reclaiming refractory material from a lining of a refractory includes assembling a first refractory component of the lining with a first refractory product, and assembling a second refractory component of the working lining with a second refractory product different from the first refractory product, the second refractory product including magnetic material dispersed therein. Upon the lining reaching a service life, the lining is demolished to produce a mixture of the first refractory component pieces and the second refractory component pieces. Magnetic separation is performed on the mixture to separate the second refractory component pieces from the first refractory component pieces.

The present disclosure concerns printable refractory compositions, more particularly ceramic-based pastes for three-dimensional printing of molds for additive metal casting, that are based on inorganic binders having several, temperature dependent polymerization states, to permit improved adhesion between stacked mold regions in an additive printing process utilizing compositions of the present disclosure.

A metallurgical vessel structure and method is provided for producing low-impurity Magnesia-Carbon reclaimed aggregate suitable for reuse in the production of high purity Magnesia-Carbon refractory. A metallurgical vessel is assembled with a non-reactive or chemically similar backup lining. The entire height of the working lining wall is Magnesia-Carbon brick suitable for reuse. The working lining is exposed to a metal making high temperature process, and the working lining is sequentially demolished. Due to the assembly of vessel, metallurgical practice, and ease of demolishing the vessel, there is little to no need for sorting, such that the used Magnesia-Carbon brick are easily converted into low impurity Magnesia-Carbon reclaimed aggregate. A refractory composed of low-impurity Magnesia aggregate reclaimed from the method is also contemplated.

A crucible having a heat treated body. The heat treated body comprises a composition including an oxide material, from 5 wt % to 50 wt % a nitride material, and optionally a sintering aid. A weight ratio of the nitride material to the oxide material ranges from 0.02:1 to 2.0:1. The heat treated body has an oxide material lattice structure with nitride material at least partially encapsulated therein.

A method includes forming an article from a silicon-rich refractory mixture. The silicon-rich refractory mixture includes a silicon-rich silicon carbide preceramic polymer and a silicon carbide powder. The method includes heating the preform to pyrolyze the silicon-rich silicon carbide preceramic polymer and form a silicon-rich refractory material. The silicon-rich refractory material includes the silicon carbide powder and excess silicon in a silicon carbide matrix. The method further includes heating the silicon-rich refractory material to oxidize at least a portion of the excess silicon and form a reinforced refractory material. The reinforced refractory material includes a silicon dioxide phase at grain boundaries of the silicon carbide powder.

A method of separating a mixture of used refractory components of different chemistry types obtained from a demolished refractory includes hydrating the mixture of refractory components to destructively hydrate at least some components of the mixture of refractory components, and separating, based on size, the at least some components from other components of the mixture of refractory components.