Patent classifications
C07C1/043
A COMPOSITION COMPRISING A MIXED METAL OXIDE AND A MOLDING COMPRISING A ZEOLITIC MATERIAL HAVING FRAMEWORK TYPE CHA AND AN ALKALINE EARTH METAL
The present invention relates to a composition comprising a) a molding comprising a zeolitic material having framework type CHA, wherein the zeolitic material comprises one or more alkaline earth metals M and b) a mixed metal oxide comprising chromium, zinc, and aluminium. It also relates to the use of the composition in a process for producing C2 to C4 olefins from syngas.
A COMPOSITION COMPRISING A MIXED METAL OXIDE AND A MOLDING COMPRISING A ZEOLITIC MATERIAL HAVING FRAMEWORK TYPE CHA AND AN ALKALINE EARTH METAL
The present invention relates to a composition comprising a) a molding comprising a zeolitic material having framework type CHA, wherein the zeolitic material comprises one or more alkaline earth metals M and b) a mixed metal oxide comprising chromium, zinc, and aluminium. It also relates to the use of the composition in a process for producing C2 to C4 olefins from syngas.
Catalyst and Method Related Thereto
The present disclosures and inventions relate to a catalyst and method for producing and using the catalyst for the selective conversion of a hydrogen/carbon monoxide mixture (syngas) to C2+ hydrocarbons, while reducing the production of carbon dioxide.
Catalyst and Method Related Thereto
The present disclosures and inventions relate to a catalyst composition for the selective conversion of a hydrogen/carbon monoxide mixture (syngas) to C2+ hydrocarbons.
Noble metal-promoted IN2O3 catalyst for the hydrogenation of CO2 to methanol
Method to prepare a catalyst for use in a process for the synthesis of methanol, comprising indium oxide in the form of In.sub.2O.sub.3, and at least one additional metal selected from a noble metal; and in that the average particle size of said noble metal phase is, preferably at least 0.05 nm, and less than 5 nm as determined by STEM-EDX, characterized in that the catalyst is prepared by co-precipitation of a saline solution at a pH above 8.5 comprising an indium salt and a salt of the at least one additional metal selected from a noble metal and optionally further comprising a salt of the at least one alkaline earth metal.
CATALYST CONTAINING LF-TYPE B ACID AND METHOD FOR PREPARING ETHYLENE USING DIRECT CONVERSION OF SYNGAS
A catalyst containing LF-type B acid preparing ethylene using direct conversion of syngas is a composite catalyst and formed by compounding component A and component B in a mechanical mixing mode. The active ingredient of the component A is a metal oxide; the component B is a zeolite of MOR topology; and a weight ratio of the active ingredients in the component A to the component B is 0.1-20. The reaction process has an extremely high product yield and selectivity, with the selectivity for light olefin reaching 80-90%, wherein ethylene has high space time yield and can reach selectivity of 75-80%. Meanwhile, the selectivity for a methane side product is extremely low (<15%).
CATALYST CONTAINING LF-TYPE B ACID AND METHOD FOR PREPARING ETHYLENE USING DIRECT CONVERSION OF SYNGAS
A catalyst containing LF-type B acid preparing ethylene using direct conversion of syngas is a composite catalyst and formed by compounding component A and component B in a mechanical mixing mode. The active ingredient of the component A is a metal oxide; the component B is a zeolite of MOR topology; and a weight ratio of the active ingredients in the component A to the component B is 0.1-20. The reaction process has an extremely high product yield and selectivity, with the selectivity for light olefin reaching 80-90%, wherein ethylene has high space time yield and can reach selectivity of 75-80%. Meanwhile, the selectivity for a methane side product is extremely low (<15%).
ORGANIC BASE MODIFIED COMPOSITE CATALYST AND METHOD FOR PRODUCING ETHYLENE BY HYDROGENATION OF CARBON MONOXIDE
An organic base modified composite catalyst for producing ethylene by hydrogenation of carbon monoxide is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of the component I is a metal oxide; the component II is an organic base modified zeolite of MOR topology; and a weight ratio of the active ingredients in the component I to the component II is 0.1-20, and preferably 0.3-8. The reaction process has an extremely high product yield and selectivity. The selectivity of C.sub.2-C.sub.3 olefins is as high as 78-87%; the selectivity of hydrocarbon products with more than 4 C atoms is less than 10%; the selectivity of a methane side product is extremely low (<9%); and meanwhile, the selectivity of the ethylene is 75-82%.
ORGANIC BASE MODIFIED COMPOSITE CATALYST AND METHOD FOR PRODUCING ETHYLENE BY HYDROGENATION OF CARBON MONOXIDE
An organic base modified composite catalyst for producing ethylene by hydrogenation of carbon monoxide is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of the component I is a metal oxide; the component II is an organic base modified zeolite of MOR topology; and a weight ratio of the active ingredients in the component I to the component II is 0.1-20, and preferably 0.3-8. The reaction process has an extremely high product yield and selectivity. The selectivity of C.sub.2-C.sub.3 olefins is as high as 78-87%; the selectivity of hydrocarbon products with more than 4 C atoms is less than 10%; the selectivity of a methane side product is extremely low (<9%); and meanwhile, the selectivity of the ethylene is 75-82%.
Method for directly preparing aromatics from syngas
A method for preparing aromatics from syngas, which includes a) contacting a raw material stream containing syngas with a catalyst in a reaction zone under reaction conditions sufficient to convert at least part of the raw material to obtain a reaction effluent; b) separating the reaction effluent to obtain at least a recycle stream containing gas-phase hydrocarbons having 1 to 4 carbon atoms and unconverted syngas and a liquid stream containing hydrocarbons having 5 or more carbon atoms; c) returning the recycle stream to the reaction zone; and d) separating aromatic products from the liquid stream, wherein the catalyst includes at least one of an inert carrier-confined highly dispersed metal oxide material, an acidic molecular sieve, and, optionally, graphite powder and a dispersant.