C07C2/60

Ionic liquid catalyst regeneration
10625252 · 2020-04-21 · ·

Processes for regenerating ionic liquid catalyst in which reaction vessel is operated under conditions sufficient to perform, in the presence of an ionic liquid catalyst, a hydrocarbon conversion reaction and provide a reaction effluent. The reaction effluent is separated into a hydrocarbon phase and a spent ionic liquid catalyst, wherein the spent ionic liquid catalyst includes conjunct polymer. The spent ionic liquid catalyst is contacted with hydrogen in a regeneration zone at conditions sufficient to reduce an amount of conjunct polymer in the spent ionic liquid catalyst to provide a regenerated effluent. The regenerated effluent is separated into a liquid phase comprising regenerated ionic liquid catalyst and a vapor phase comprising hydrogen and hydrogen chloride. The hydrocarbon phase is separated into a plurality of liquid hydrocarbon streams. The vapor phase is isolated from the liquid hydrocarbon streams. Alkylation processes are also disclosed.

Ionic liquid catalyst regeneration
10625252 · 2020-04-21 · ·

Processes for regenerating ionic liquid catalyst in which reaction vessel is operated under conditions sufficient to perform, in the presence of an ionic liquid catalyst, a hydrocarbon conversion reaction and provide a reaction effluent. The reaction effluent is separated into a hydrocarbon phase and a spent ionic liquid catalyst, wherein the spent ionic liquid catalyst includes conjunct polymer. The spent ionic liquid catalyst is contacted with hydrogen in a regeneration zone at conditions sufficient to reduce an amount of conjunct polymer in the spent ionic liquid catalyst to provide a regenerated effluent. The regenerated effluent is separated into a liquid phase comprising regenerated ionic liquid catalyst and a vapor phase comprising hydrogen and hydrogen chloride. The hydrocarbon phase is separated into a plurality of liquid hydrocarbon streams. The vapor phase is isolated from the liquid hydrocarbon streams. Alkylation processes are also disclosed.

Ionic liquid reactor with hydrocyclones
10618858 · 2020-04-14 · ·

A method of alkylating a hydrocarbon stream including: providing a feed stream that includes hydrocarbons and ionic liquid catalyst; passing the feed stream through a low efficiency mixer to create a mixed stream, whereby the low efficiency mixer creates droplets within the feed stream that are primarily within a predetermined size range; passing the mixed stream and an olefin stream into a reactor; performing an alkylation reaction within the reactor, thereby forming a reacted stream; and separating the reacted stream into a settled ionic liquid catalyst stream and a hydrocarbon stream through the use of at least one hydrocyclone.

Ionic liquid reactor with hydrocyclones
10618858 · 2020-04-14 · ·

A method of alkylating a hydrocarbon stream including: providing a feed stream that includes hydrocarbons and ionic liquid catalyst; passing the feed stream through a low efficiency mixer to create a mixed stream, whereby the low efficiency mixer creates droplets within the feed stream that are primarily within a predetermined size range; passing the mixed stream and an olefin stream into a reactor; performing an alkylation reaction within the reactor, thereby forming a reacted stream; and separating the reacted stream into a settled ionic liquid catalyst stream and a hydrocarbon stream through the use of at least one hydrocyclone.

Ionic liquid reactor with hydrocyclones
10618858 · 2020-04-14 · ·

A method of alkylating a hydrocarbon stream including: providing a feed stream that includes hydrocarbons and ionic liquid catalyst; passing the feed stream through a low efficiency mixer to create a mixed stream, whereby the low efficiency mixer creates droplets within the feed stream that are primarily within a predetermined size range; passing the mixed stream and an olefin stream into a reactor; performing an alkylation reaction within the reactor, thereby forming a reacted stream; and separating the reacted stream into a settled ionic liquid catalyst stream and a hydrocarbon stream through the use of at least one hydrocyclone.

Modified HF alkylation reaction zone for ionic liquid alkylation
10584079 · 2020-03-10 · ·

An alkylation process and apparatus are described. The alkylation process includes pre-mixing a paraffin stream with an ionic liquid catalyst stream from a settler. The premixed paraffin and ionic liquid catalyst stream is mixed in a low-efficiency pump to form a paraffin and ionic liquid catalyst mixture. An olefin feed stream is introduced into a riser reactor. The paraffin and ionic liquid catalyst mixture is introduced into the riser reactor to form a reaction mixture comprising alkylate and the ionic liquid catalyst. The reaction mixture is separated in a settler into an ionic liquid catalyst stream and a hydrocarbon stream.

Modified HF alkylation reaction zone for ionic liquid alkylation
10584079 · 2020-03-10 · ·

An alkylation process and apparatus are described. The alkylation process includes pre-mixing a paraffin stream with an ionic liquid catalyst stream from a settler. The premixed paraffin and ionic liquid catalyst stream is mixed in a low-efficiency pump to form a paraffin and ionic liquid catalyst mixture. An olefin feed stream is introduced into a riser reactor. The paraffin and ionic liquid catalyst mixture is introduced into the riser reactor to form a reaction mixture comprising alkylate and the ionic liquid catalyst. The reaction mixture is separated in a settler into an ionic liquid catalyst stream and a hydrocarbon stream.

Modified HF alkylation reaction zone for ionic liquid alkylation
10584079 · 2020-03-10 · ·

An alkylation process and apparatus are described. The alkylation process includes pre-mixing a paraffin stream with an ionic liquid catalyst stream from a settler. The premixed paraffin and ionic liquid catalyst stream is mixed in a low-efficiency pump to form a paraffin and ionic liquid catalyst mixture. An olefin feed stream is introduced into a riser reactor. The paraffin and ionic liquid catalyst mixture is introduced into the riser reactor to form a reaction mixture comprising alkylate and the ionic liquid catalyst. The reaction mixture is separated in a settler into an ionic liquid catalyst stream and a hydrocarbon stream.

Hydrocarbon conversion processes using non-cyclic amide and thioamide based ionic liquids

A hydrocarbon conversion process is described. The process involves contacting a hydrocarbon feed with a non-cyclic amide or thioamide based ionic liquid catalyst in a reaction zone under reaction conditions to form a mixture comprising reaction products, and the non-cyclic amide or thioamide based ionic liquid catalyst. Typical hydrocarbon conversion processes include alkylation, oligomerization, isomerization, disproportionation, and reverse disproportionation.

Hydrocarbon conversion processes using non-cyclic amide and thioamide based ionic liquids

A hydrocarbon conversion process is described. The process involves contacting a hydrocarbon feed with a non-cyclic amide or thioamide based ionic liquid catalyst in a reaction zone under reaction conditions to form a mixture comprising reaction products, and the non-cyclic amide or thioamide based ionic liquid catalyst. Typical hydrocarbon conversion processes include alkylation, oligomerization, isomerization, disproportionation, and reverse disproportionation.