The present invention relates to a catalyst used in a dehydrogenation reaction of a linear hydrocarbon gas in a range of C3 to C4, and provides a dehydrogenation catalyst which is deposited on a carrier obtained by changing the phase of platinum, an auxiliary metal and an alkali metal, wherein the platinum and the auxiliary metal are present as a single complex within a certain thickness from the outer edges of the catalyst in an alloy form.

In an aspect, a method for the aromatization of hydrocarbons comprises contacting a hydrocarbon feedstream with a catalyst; wherein the catalyst comprises a zeolite comprising Si, Al, and Ge in the framework with Pt deposited thereon; wherein the zeolite further comprises Na; and wherein the catalyst has an Si:Al.sub.2 mole ratio of greater than or equal to 125, an Si:Ge mole ratio of 40 to 400, and an Na:Al mole ratio of 0.9 to 2.5, wherein the catalyst has an aluminum content of less than or equal to 0.75 wt % excluding any binder and extrusion aide.

Disclosed is a catalyst for producing the olefin. The catalyst includes a support including alumina and a sub-support component, and a metal oxide impregnated on the support. The metal oxide includes anyone selected from an oxide of chromium, vanadium, manganese, iron, cobalt, molybdenum, copper, zinc, cerium and nickel; and the sub-support component includes anyone selected from zirconium, zinc and platinum.

According to one or more embodiments, olefins may be produced by contacting a hydrocarbon feed stream with a particulate solid in a reaction vessel. The reaction vessel may be connected to a riser. The riser may extend through a riser port of an outer shell of a particulate solid separation section such that the riser may comprise an interior riser segment and an exterior riser segment. The particulate solid separation section may include a gas outlet port, a riser port, and a particulate solid outlet port. The particulate solid separation section may house a gas/solids separation device and a solid particulate collection area. The riser port may be positioned on a sidewall of the outer shell such that it is not located on a central vertical axis of the particulate solid separation section. The particulate solid may be separated from an olefin-containing product stream in the gas/solids separation device.

According to one or more embodiments of the present disclosure, a fluidization promoter useful for dehydrogenation includes from 0.1 wt. % to 10 wt. % gallium, from 5 ppm to 500 ppm platinum, less than 5 wt. % alkali metal or alkaline earth metal, and a support material. A median particle size of the fluidization promoter is from 20 ?m to 50 ?m. Catalyst systems useful for dehydrogenation and methods for producing olefins using the same are also disclosed.

The present invention relates to a method for preparing, activating and regenerating a metal supported catalyst, comprising: treating a M.sub.a-M.sub.b-M.sub.c metal supported catalyst at 10-700? C. by using an ammonia or nitrogen-containing organic matter, wherein the M.sub.a metal is an active metal selected from one or more of a noble metal atom or a transition metal, the support is a common industrial porous catalyst, and the M.sub.a metal is dispersed on the support in a state of single atomic site. According to the M.sub.d-M.sub.b-M.sub.c metal supported noble metal/zinc catalyst treated by the method of the present invention, the direct dehydrogenation conversion rate and selectivity of catalyzing light alkanes are remarkably improved; the method for preparing the catalyst is simple in process, the catalytic activity after regeneration is still kept, and the catalyst can be industrially produced on a large scale.

In an aspect, a method for the aromatization of hydrocarbons comprises contacting a hydrocarbon feedstream with a catalyst; wherein the catalyst comprises a zeolite comprising Si, Al, and Ge in the framework with Pt deposited thereon; wherein the zeolite further comprises Na; and wherein the catalyst has an Si:Al.sub.2 mole ratio of greater than or equal to 125, an Si:Ge mole ratio of 40 to 400, and an Na:Al mole ratio of 0.9 to 2.5, wherein the catalyst has an aluminum content of less than or equal to 0.75 wt % excluding any binder and extrusion aide.

In an embodiment, A catalyst comprises a zeolite comprising Si, Al, and Ge in the framework with Pt deposited thereon; wherein the catalyst has an Si:Al.sub.2 mole ratio of greater than or equal to 125, an Si:Ge mole ratio of 40 to 400, and an Na:Al mole ratio of 0.9 to 2.5; wherein the catalyst has an aluminum content of less than or equal to 0.75 wt %; wherein the catalyst is non-acidic.

The disclosure provides a method of dehydrogenating hydrocarbons, such as C.sub.2 or C.sub.3 hydrocarbons, selectively and efficiently, to provide the corresponding alkylenes. The method is based on a Pt nanolayer catalyst over MXene (Pt/MXene) that shows resistance to coke deposition. The dehydrogenation conditions developed provided about 22% propane conversion and over 90% selectivity toward the desired propylene product, and the catalyst was stable for a 24-hour continuous run. The byproducts were ethane, ethylene, and methane, and only trace amounts of coke deposition over the catalyst were detected. Similar dehydrogenation conditions provided about 18% ethane conversion and over 90% selectivity toward the desired ethylene product. A mass balance of greater than 96% was achieved in each case.

Disclosed herein are methods of preparing dehydrogenation catalysts using non-halogen containing metal sources. The methods generally comprise the steps of providing a first solution comprising anions of a first metal selected from Group 14 of the Periodic Table of Elements, and impregnating an inorganic support with the first solution to obtain a first impregnated inorganic support, wherein the first solution has a pH value of less than the isoelectric point of the inorganic support. The dehydrogenation catalysts prepared in accordance with the methods of the present disclosure are typically free or substantially free of halogen species. Such catalysts may be particularly useful in the dehydrogenation of a feed comprising cyclohexane and/or methylcyclopentane.