Patent classifications
C07C13/465
Mononuclear iron complex and organic synthesis reaction using same
A mononuclear iron bivalent complex having iron-silicon bonds, which is represented by formula (1), can exhibit an excellent catalytic activity in at least one reaction selected from three reactions, i.e., a hydrosilylation reaction, a hydrogenation reaction and a reaction for reducing a carbonyl compound. ##STR00001## (In the formula, R.sup.1 to R.sup.6 independently represent a hydrogen atom, an alkyl group which may be substituted by X, or the like; X represents a halogen atom, or the like; L.sup.1 represents at least one two-electron ligand selected from an isonitrile ligand, an amine ligand, an imine ligand, a nitrogenated heterocyclic ring, a phosphine ligand, a phosphite ligand and a sulfide ligand, wherein, when multiple L.sup.1's are present, two L.sup.1's may be bonded to each other; L.sup.2 represents a two-electron ligand that is different from a CO ligand or the above-mentioned L.sup.1, wherein, when multiple L.sup.2's are present, two L.sup.2's may be bonded to each other; and m.sup.1 represents an integer of 1 to 4 and m.sup.2 represents an integer of 0 to 3, wherein the sum total of m.sup.1 and m.sup.2 (i.e., m.sup.1+m.sup.2) satisfies 3 or 4.)
MULTI- OR DUAL-HEADED COMPOSITIONS USEFUL FOR CHAIN SHUTTLING AND PROCESS TO PREPARE THE SAME
The present disclosure relates to a multi- or dual-headed composition having the formula (I) or (II). The present disclosure also relates to a process for preparing the multi- or dual-headed composition having the formula (I) or (II), the process including combining 1,2,4-trivinylcyclochexane, an organometallic compound, and a catalyst precursor. The present disclosure further relates to use of the composition having the formula (I) or (II) in olefin polymerization.
MULTI- OR DUAL-HEADED COMPOSITIONS USEFUL FOR CHAIN SHUTTLING AND PROCESS TO PREPARE THE SAME
The present disclosure relates to a multi- or dual-headed composition having the formula (I) or (II). The present disclosure also relates to a process for preparing the multi- or dual-headed composition having the formula (I) or (II), the process including combining 1,2,4-trivinylcyclochexane, an organometallic compound, and a catalyst precursor. The present disclosure further relates to use of the composition having the formula (I) or (II) in olefin polymerization.
Cycloalkylnorbornene monomers, polymers derived therefrom and their use in pervaporation
A variety of polycycloalkyl polynorbornene monomers and polymers derived therefrom are disclosed and claimed. The polymers and copolymers as disclosed herein are useful for forming pervaporation membranes, among other uses.
Cycloalkylnorbornene monomers, polymers derived therefrom and their use in pervaporation
A variety of polycycloalkyl polynorbornene monomers and polymers derived therefrom are disclosed and claimed. The polymers and copolymers as disclosed herein are useful for forming pervaporation membranes, among other uses.
PROCESS FOR SYNTHESIS OF INDENES
The present invention relates to a new process for the synthesis of 2,3,4,5,6,7-substituted indenes, which are useful precursors for the formation of certain ansa-metallocene catalysts.
PROCESS FOR SYNTHESIS OF INDENES
The present invention relates to a new process for the synthesis of 2,3,4,5,6,7-substituted indenes, which are useful precursors for the formation of certain ansa-metallocene catalysts.
PROCESS FOR SYNTHESIS OF INDENES
The present invention relates to a new process for the synthesis of 2,3,4,5,6,7-substituted indenes, which are useful precursors for the formation of certain ansa-metallocene catalysts.
PREPARING UNSATURATED CARBOCYCLIC COMPOUNDS
Disclosed are methods of preparing unsaturated carbocyclic compounds through dehydrogenation of corresponding saturated carbocyclic compounds.
PREPARING UNSATURATED CARBOCYCLIC COMPOUNDS
Disclosed are methods of preparing unsaturated carbocyclic compounds through dehydrogenation of corresponding saturated carbocyclic compounds.