Patent classifications
C07C43/13
Compositions and Methods for Preparation and Utilization of Acid-Generating Materials
An oilwell treatment composition comprising (i) a solubilizing agent wherein the solubilizing agent comprises a saturated compound of the formula:
H—(OC.sub.aH.sub.2a).sub.x(OC.sub.bH.sub.2b).sub.y—OC.sub.cH.sub.2c+1
where a and b are each independently 1, 3, or 4; c is 1, 2 or 3; x and y each independently, are numbers ranging from 1 to 5; (ii) a solid acid precursor and (iii) an aqueous fluid wherein the mass ratio of the solubilizing agent to the aqueous solution is within the range of about 1:3 to about 1:5 and the mass ratio of the solubilizing agent to the solid acid precursor is within the range of about 3:1 to about 2:1.
CO2-MEDIATED ETHERIFICATION OF BIO-BASED DIOLS
A method of etherifying glycols or other diols by employing renewable reagents is disclosed. In particular, the method involves contacting a diol with an alkylating agent in an alcoholic solvent, catalyzed with a catalyst (carbonic acid) generated in situ (from CO.sub.2). The mono- and di-ether products can serve as valued precursors to an array of renewable surfactants, dispersants, and lubricants, among others.
CO2-MEDIATED ETHERIFICATION OF BIO-BASED DIOLS
A method of etherifying glycols or other diols by employing renewable reagents is disclosed. In particular, the method involves contacting a diol with an alkylating agent in an alcoholic solvent, catalyzed with a catalyst (carbonic acid) generated in situ (from CO.sub.2). The mono- and di-ether products can serve as valued precursors to an array of renewable surfactants, dispersants, and lubricants, among others.
Narrow range alcohol alkoxylates and derivatives thereof
The present invention relates generally to narrow range alcohol alkoxylates and derivatives thereof, such as alkyl ether sulfates.
Narrow range alcohol alkoxylates and derivatives thereof
The present invention relates generally to narrow range alcohol alkoxylates and derivatives thereof, such as alkyl ether sulfates.
Methods for making functionalized fluorinated monomers, fluorinated monomers, and compositions for making the same
A method of making a functionalized fluorinated monomer for use in making oligomers and polymers that can be used to improve surface properties of polymer-derived systems, such as coatings. The method of making a functionalized fluorinated monomer includes reacting at least one fluorinated nucleophilic reactant, such as a fluorinated alcohol, with at least one compound containing at least one epoxide group. Other methods include reaction of a fluorinated alcohol with a cyclic carboxylic anhydride. In another embodiment, a method includes reacting a fluorinated mesylate, tosylate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method includes reacting a fluorinated alcohol with an alkyl halide, or reacting a fluorinated alkyl halide with an amine. The functionalized fluorinated monomers may be used as intermediates and reacted to modify the functional groups thereon. Further, the functionalized fluorinated monomers may be reacted to form polymers or oligomers, or with polymers or oligomers having functional groups to modify the polymer or oligomer through the functional group thereon.
Preparation and application method of bio-based long-chain alcohol-ether oxygenate diesel additives
A biomass-based long-chain alcohol ether oxygenated additive and a preparation method and application thereof are disclosed. The additive used agricultural and forestry wastes as raw materials, and has a general chemical formula of R—(O—C.sub.1-3).sub.n—R—OH. The preparation method includes the following steps: step 1, performing drying pretreatment on biomass raw materials, performing rapid pyrolysis under an inert atmosphere to obtain a pyrolysis product containing water, gases, water-phase bio-oil and oil-phase bio-oil, separating out the water-phase bio-oil and performing catalytic hydrogenation on the water-phase bio-oil to obtain polyols; step 2, performing catalytic dehydration on the polyols obtained in step 1 under a basic catalyst system to obtain epoxyalkane; and step 3, making the epoxyalkane obtained in step 2 and methanol undergo a reaction under a molecular sieve catalyst and removing the solid catalyst by separation to obtain the long-chain alcohol ether oxygenated additive.
Preparation and application method of bio-based long-chain alcohol-ether oxygenate diesel additives
A biomass-based long-chain alcohol ether oxygenated additive and a preparation method and application thereof are disclosed. The additive used agricultural and forestry wastes as raw materials, and has a general chemical formula of R—(O—C.sub.1-3).sub.n—R—OH. The preparation method includes the following steps: step 1, performing drying pretreatment on biomass raw materials, performing rapid pyrolysis under an inert atmosphere to obtain a pyrolysis product containing water, gases, water-phase bio-oil and oil-phase bio-oil, separating out the water-phase bio-oil and performing catalytic hydrogenation on the water-phase bio-oil to obtain polyols; step 2, performing catalytic dehydration on the polyols obtained in step 1 under a basic catalyst system to obtain epoxyalkane; and step 3, making the epoxyalkane obtained in step 2 and methanol undergo a reaction under a molecular sieve catalyst and removing the solid catalyst by separation to obtain the long-chain alcohol ether oxygenated additive.
Lubricant compositions
Provided herein is a lubricant including a compound of Formula I
L-(CF.sub.2CF.sub.2O).sub.n—CF.sub.2CH.sub.2O—N—OCH.sub.2CF.sub.2O—(CF.sub.2CF.sub.2O).sub.m-M (Formula I)
wherein L is selected from the group consisting of ##STR00001## M is selected from the group consisting of ##STR00002##
wherein each instance of R.sup.1, R.sup.2, and R.sup.3 is independently selected from the group consisting of hydroxyl, alkoxyl, carbocycyl, phenyl, heterocycyl, piperonyl, carboxyl, alkylamido, acetamido, carbamoyl, N-alkylcarbamoyl, N,N-dialkylcarbamoyl, 2,3-dihydroxy-1-propoxyl, acryloyl, alkacryloyl, methacryloyl, a substituent of methyl methacrylate, and a substituent of glycidyl ether; and
wherein n≧1, m≧1, and n and m are the same or different.
Polyether diol and method for producing the same
A method for producing a polyether diol includes the step of subjecting a compound represented by the following general formula (1) to hydrogenation reduction in the presence of a hydrogenation catalyst to provide a specific polyether diol. ##STR00001##