Novel singly protected 2,2′-dihydroxybiaryls, electrochemical process for preparation of singly protected 2,2′-dihydroxybiaryls.

Novel singly protected 2,2′-dihydroxybiaryls, electrochemical process for preparation of singly protected 2,2′-dihydroxybiaryls.

The invention relates to the generation of compounds, e.g., fragrance molecules with desirable olfactory properties that can be derived from readily available fatty acids.

The present invention is related to substituted butanol derivatives of the formula: ##STR00001##
wherein R is an unsubstituted or substituted C.sub.1-6 straight chain alkyl, an unsubstituted or substituted C.sub.3-6 branched chain alkyl, an unsubstituted or substituted C.sub.3-6 straight chain alkenyl, an unsubstituted or substituted C.sub.3-6 branched chain alkenyl, an unsubstituted or substituted C.sub.3-6 cycloalkyl, an unsubstituted or substituted C.sub.1-6 alkoxy, nitrile, halo, amino, an unsubstituted or substituted C.sub.1-6 alkylamino, an unsubstituted or substituted C.sub.1-6 dialkylamino, carboxy-C.sub.1-6 alkylamino, carboxy-C.sub.1-6 dialkylamino, an unsubstituted or substituted acetoxy, carboxy, an unsubstituted or substituted carboxyethyl, an unsubstituted or substituted C.sub.1-6 alkylcarbonyl, an unsubstituted or substituted C.sub.1-6 alkylcarboxy, an unsubstituted or substituted C.sub.1-6 alkylthio, an unsubstituted or substituted C.sub.1-6 alkyloxy, carboxamido, an unsubstituted or substituted C.sub.1-6 alkylcarboxamido or an unsubstituted or substituted C.sub.1-6 dialkylcarboxamido. Such compounds are useful in flavor or flavor compositions.

The present invention is related to substituted butanol derivatives of the formula: ##STR00001##
wherein R is an unsubstituted or substituted C.sub.1-6 straight chain alkyl, an unsubstituted or substituted C.sub.3-6 branched chain alkyl, an unsubstituted or substituted C.sub.3-6 straight chain alkenyl, an unsubstituted or substituted C.sub.3-6 branched chain alkenyl, an unsubstituted or substituted C.sub.3-6 cycloalkyl, an unsubstituted or substituted C.sub.1-6 alkoxy, nitrile, halo, amino, an unsubstituted or substituted C.sub.1-6 alkylamino, an unsubstituted or substituted C.sub.1-6 dialkylamino, carboxy-C.sub.1-6 alkylamino, carboxy-C.sub.1-6 dialkylamino, an unsubstituted or substituted acetoxy, carboxy, an unsubstituted or substituted carboxyethyl, an unsubstituted or substituted C.sub.1-6 alkylcarbonyl, an unsubstituted or substituted C.sub.1-6 alkylcarboxy, an unsubstituted or substituted C.sub.1-6 alkylthio, an unsubstituted or substituted C.sub.1-6 alkyloxy, carboxamido, an unsubstituted or substituted C.sub.1-6 alkylcarboxamido or an unsubstituted or substituted C.sub.1-6 dialkylcarboxamido. Such compounds are useful in flavor or flavor compositions.

An unsaturated double bond-containing compound represented by the general formula (I) or the general formula (II), an oxygen absorbent containing the compound, and a resin composition. ##STR00001##

An unsaturated double bond-containing compound represented by the general formula (I) or the general formula (II), an oxygen absorbent containing the compound, and a resin composition. ##STR00001##

The present invention relates to the use of an ether or an ester of a tertiary alkanol or of mixtures of two or more ethers or esters of tertiary alkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof as aromachemicals; to the use thereof for modifying the scent character of a fragranced composition; to an aroma chemical composition containing an ether or an ester of tertiary alkanol or of mixtures of two or more ethers or esters of tertiary alkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof; and to a method of preparing a fragranced composition or for modifying the scent character of a fragranced composition. The invention further relates to specific ethers or esters of tertiary alkanols.

The present invention relates to the use of an ether or an ester of a tertiary alkanol or of mixtures of two or more ethers or esters of tertiary alkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof as aromachemicals; to the use thereof for modifying the scent character of a fragranced composition; to an aroma chemical composition containing an ether or an ester of tertiary alkanol or of mixtures of two or more ethers or esters of tertiary alkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof; and to a method of preparing a fragranced composition or for modifying the scent character of a fragranced composition. The invention further relates to specific ethers or esters of tertiary alkanols.

Catalyst compositions are prepared by contacting a palladium source and 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane and a methoxyocta-diene compound, in a primary aliphatic alcohol, under suitable conditions including a ratio of equivalents of palladium to equivalents of 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane ranging from greater than 1:1 to 1:1.3. The result is a complex of palladium, a 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaada-mantane ligand, and a ligand selected from a methoxyoctadiene ligand, an octadienyl ligand, or a protonated octadienyl. Such complexes may, in solution, exhibit surprising solubility and storage stability and are useful in the telomerization of butadiene, which is a step in the production of 1-octene.