Disclosed is a fluoropolyether compound comprising a C.sub.4-10 aliphatic hydrocarbon chain present in the middle of the fluoropolyether compound and at least two perfluoropolyethers.

A hydrofluoroolefin compound represented by the following general formula (I): where, Rh is CHCH.sub.2 or C(CH.sub.3)CH.sub.2; and (i) x is O; n is 1; Y is F; Rf.sub.2 is F; and Rf.sub.1 is a linear or branched fluorinated alkyl group having 1-10 carbon atoms and optionally includes one or more catenated heteroatoms selected from O, N, and S; or ({umlaut over ()}) x is N, n is 2, Y is F or CF.sub.3; Rf.sub.2 is F or CF.sub.3; and (a) each Rf.sub.1 is bonded to x, and is independently a linear or branched fluorinated alkyl group having 1-8 carbon atoms and optionally includes one or more catenated heteroatom selected from O, N or S; or (e) the Rf.sub.1 groups are bonded together to form a ring structure having 4 to 8 carbon atoms that optionally includes one or more catenated heteroatoms selected from O, N, or S; with the proviso that when YCF.sub.3, then Rf.sub.2F.

##STR00001##

A hydrofluoroolefin compound represented by the following general formula (I): where, Rh is CHCH.sub.2 or C(CH.sub.3)CH.sub.2; and (i) x is O; n is 1; Y is F; Rf.sub.2 is F; and Rf.sub.1 is a linear or branched fluorinated alkyl group having 1-10 carbon atoms and optionally includes one or more catenated heteroatoms selected from O, N, and S; or ({umlaut over ()}) x is N, n is 2, Y is F or CF.sub.3; Rf.sub.2 is F or CF.sub.3; and (a) each Rf.sub.1 is bonded to x, and is independently a linear or branched fluorinated alkyl group having 1-8 carbon atoms and optionally includes one or more catenated heteroatom selected from O, N or S; or (e) the Rf.sub.1 groups are bonded together to form a ring structure having 4 to 8 carbon atoms that optionally includes one or more catenated heteroatoms selected from O, N, or S; with the proviso that when YCF.sub.3, then Rf.sub.2F.

##STR00001##

Novel polyfluoroalkylated alkenes compounds prepared therefrom are described.

Novel polyfluoroalkylated alkenes compounds prepared therefrom are described.

The present application provides, among other things, compounds and methods for metathesis reactions. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and/or stereoselectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and Z-selectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and E-selectivity. In some embodiments, provided technologies are particularly useful for preparing alkenyl fluorides. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-a. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-b.

The present application provides, among other things, compounds and methods for metathesis reactions. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and/or stereoselectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and Z-selectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and E-selectivity. In some embodiments, provided technologies are particularly useful for preparing alkenyl fluorides. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-a. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-b.

The present application provides, among other things, compounds and methods for metathesis reactions. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and/or stereoselectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and Z-selectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and E-selectivity. In some embodiments, provided technologies are particularly useful for preparing alkenyl fluorides. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-a. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-b.

Novel polyfluoroalkylated alkenes and silicone compounds prepared therefrom are described.

Novel polyfluoroalkylated alkenes and silicone compounds prepared therefrom are described.