The present invention relates to a compound having the general formula (1) wherein in the general formula (1) the residues R.sub.1 to R.sub.8 and Ar are the same or different and are independently from each other selected from the group consisting of hydrogen, unsubstituted hydrocarbon groups, substituted hydrocarbon groups and inorganic groups, wherein at least one of the residues R.sub.1 to R.sub.8 and Ar is a hydrophilic group, such as for instance a group comprising one or more polyethylene groups.

##STR00001##

Disclosed herein are embodiments of aryl compounds and polymers thereof that are made using methods that do not require harsh conditions or expensive reagents. The methods disclosed herein utilize precursor compounds that can be polymerized to form polycyclic aromatic hydrocarbons and polymers, such as carbon-based polymers like nanostructures (e.g., graphene or graphene-like nanoribbons).

The present invention relates to compounds suitable for use in electronic devices, and to electronic devices, especially organic electroluminescent devices, comprising these compounds.

Methods are provided for the synthesis of cannabinoids, including cannabidiol (CBD), cannabinol (CBN), cannabichromene (CBC), cannabidiolic acid (CBDA), cannabigerol (CBG), cannabigerolic acid (CBGA), cannabidivarin (CBDV), cannabidibutol (CBD-C4), dihydrocannabidiol (DCBD), tetrahydrocannabivarin (THCV), analogs thereof, and precursors to the foregoing. One method employs phloroglucinol or a phloroglucinol analog as a starting material. The syntheses are stereospecific, efficient, selective, and cost-effective, with little or no potential for generation of THC ((-)-trans-Δ.sup.9-tetrahydro-cannabinol) or any other psychoactive side product. Telescoped syntheses are also provided, as are new cannabinoids, pharmaceutical formulations, and methods of use.

Methods are provided for the synthesis of cannabinoids, including cannabidiol (CBD), cannabinol (CBN), cannabichromene (CBC), cannabidiolic acid (CBDA), cannabigerol (CBG), cannabigerolic acid (CBGA), cannabidivarin (CBDV), cannabidibutol (CBD-C4), dihydrocannabidiol (DCBD), tetrahydrocannabivarin (THCV), analogs thereof, and precursors to the foregoing. One method employs phloroglucinol or a phloroglucinol analog as a starting material. The syntheses are stereospecific, efficient, selective, and cost-effective, with little or no potential for generation of THC ((-)-trans-Δ.sup.9-tetrahydro-cannabinol) or any other psychoactive side product. Telescoped syntheses are also provided, as are new cannabinoids, pharmaceutical formulations, and methods of use.

To provide a photopolymerization sensitizer which will not cause problems of dusting or coloring of a cured product by bleeding of additives such as the photopolymerization sensitizer on the surface e.g. by blooming at the time of photo-curing or during storage of the cured product, and which imparts a practically sufficient photo-curing rate. An oligomer of a 9,10-bis(substituted oxy)anthracene compound having repeating units represented by the following formula (1): ##STR00001##
wherein n represents a repetition number and is from 2 to 50, each of X and Y which may be the same or different, is a hydrogen atom, a C.sub.1-8 alkyl group or a halogen atom, and A is a bivalent substituent.

Disclosed herein are embodiments of aryl compounds and polymers thereof that are made using methods that do not require harsh conditions or expensive reagents. The methods disclosed herein utilize precursor compounds that can be polymerized to form polycyclic aromatic hydrocarbons and polymers, such as carbon-based polymers like nanostructures (e.g., graphene or graphene-like nanoribbons).

A polyalkylene glycol-based compound may have formula (1):

##STR00001##

wherein R.sup.1 is a monovalent aromatic hydrocarbon group having 6 to 42 ring carbon atoms; R.sup.2 is a monovalent aromatic hydrocarbon group having 6 to 42 carbon atoms or a hydrogen atom; R.sup.3 is a divalent hydrocarbon group having 2 to 4 carbon atoms; and m is a number in a range of from 1 to 40.

A process for etherification of aldehydes and/or ketones in the presence of a catalyst and an iodine source. In particular, a process for the synthesis of an ether compound, comprising reacting an aldehyde and/or a ketone with an alcohol, in the presence of (i) a metal/support heterogeneous catalyst and an iodine source, or (ii) a metal-iodine catalyst, in a reactor, whereby the ether compound is obtained. A catalytic system comprising a metal/support heterogeneous catalyst and an iodine source, and a process for its preparation.

A process for etherification of aldehydes and/or ketones in the presence of a catalyst and an iodine source. In particular, a process for the synthesis of an ether compound, comprising reacting an aldehyde and/or a ketone with an alcohol, in the presence of (i) a metal/support heterogeneous catalyst and an iodine source, or (ii) a metal-iodine catalyst, in a reactor, whereby the ether compound is obtained. A catalytic system comprising a metal/support heterogeneous catalyst and an iodine source, and a process for its preparation.