Patent classifications
C07C45/83
METHOD FOR PREPARING A ß-HYDROXYKETONE
Method for preparing a -hydroxyketone having 4 to 8 carbon atoms by reacting formaldehyde with a branched or unbranched dialkyl ketone having 3 to 7 carbon atoms in the liquid phase in a reactor in the presence of a basic component at a temperature of 50 to 150 C. and a pressure of 0.2 to 10 MPa abs, in which (a) a trialkylamine having 1 to 4 carbon atoms per alkyl group is used as basic component and the reaction (b) is carried out in the presence of 1 to 25% by weight water, based on the liquid phase, and (c) at a molar ratio of trialkylamine to formaldehyde in the liquid phase of from 1 to 5.
METHOD FOR PREPARING 1-HYDROXY-2-METHYL-3-PENTANONE
Method for preparing 1-hydroxy-2-methyl-3-pentanone (I) by reacting formaldehyde with diethyl ketone in a reactor in the presence of water and a basic component at a temperature of 50 to 150 C. and a pressure of 0.2 to 10 MPa abs, in which the basic component used is a trialkylamine from the group comprising trimethylamine, N,N-dimethylethylamine, N,N-diethylmethylamine, triethylamine, N,N-dimethyl-n-propylamine, N-ethyl-N-methyl-n-propylamine, N,N-dimethylisopropylamine, N-ethyl-N-methylisopropylamine, N,N-dimethyl-n-butylamine, N,N-dimethylisobutylamine and N,N-dimethyl-sec-butylamine, and from the reaction mixture obtained, trialkylamine as low boiler and a bottom product comprising 1-hydroxy-2-methyl-3-pentanone (I) as high boiler are separated in a distillation apparatus, wherein the distillation apparatus is operated at a top pressure of 0.2 to 1 MPa abs.
METHOD FOR PREPARING 1-HYDROXY-2-METHYL-3-PENTANONE
Method for preparing 1-hydroxy-2-methyl-3-pentanone (I) by reacting formaldehyde with diethyl ketone in a reactor in the presence of water and a basic component at a temperature of 50 to 150 C. and a pressure of 0.2 to 10 MPa abs, in which the basic component used is a trialkylamine from the group comprising trimethylamine, N,N-dimethylethylamine, N,N-diethylmethylamine, triethylamine, N,N-dimethyl-n-propylamine, N-ethyl-N-methyl-n-propylamine, N,N-dimethylisopropylamine, N-ethyl-N-methylisopropylamine, N,N-dimethyl-n-butylamine, N,N-dimethylisobutylamine and N,N-dimethyl-sec-butylamine, and from the reaction mixture obtained, trialkylamine as low boiler and a bottom product comprising 1-hydroxy-2-methyl-3-pentanone (I) as high boiler are separated in a distillation apparatus, wherein the distillation apparatus is operated at a top pressure of 0.2 to 1 MPa abs.
METHOD FOR PREPARING 1-HYDROXY-2-METHYL-3-PENTANONE
Method for preparing 1-hydroxy-2-methyl-3-pentanone (I) by reacting formaldehyde with diethyl ketone in a reactor in the presence of water and a basic component at a temperature of 50 to 150 C. and a pressure of 0.2 to 10 MPa abs, in which the basic component used is a trialkylamine from the group comprising trimethylamine, N,N-dimethylethylamine, N,N-diethylmethylamine, triethylamine, N,N-dimethyl-n-propylamine, N-ethyl-N-methyl-n-propylamine, N,N-dimethylisopropylamine, N-ethyl-N-methylisopropylamine, N,N-dimethyl-n-butylamine, N,N-dimethylisobutylamine and N,N-dimethyl-sec-butylamine, and from the reaction mixture obtained, trialkylamine as low boiler and a bottom product comprising 1-hydroxy-2-methyl-3-pentanone (I) as high boiler are separated in a distillation apparatus, wherein the distillation apparatus is operated at a top pressure of 0.2 to 1 MPa abs.
Process for producing methacrylic acid or methacrylic acid esters
A process can be used for producing methacrylic acid or a methacrylic acid ester. The process involves producing acrolein, reacting the produced acrolein with hydrogen to produce propanal, reacting the propanal with formaldehyde to produce methacrolein, and oxidizing the methacrolein in the presence of an oxygen containing gas and optionally an alcohol, to obtain methacrylic acid or methacrylic acid ester.
Process for producing methacrylic acid or methacrylic acid esters
A process can be used for producing methacrylic acid or a methacrylic acid ester. The process involves producing acrolein, reacting the produced acrolein with hydrogen to produce propanal, reacting the propanal with formaldehyde to produce methacrolein, and oxidizing the methacrolein in the presence of an oxygen containing gas and optionally an alcohol, to obtain methacrylic acid or methacrylic acid ester.
PROCESS FOR SEPARATING HEAVY BY-PRODUCTS AND CATALYST LIGAN FROM A VAPOUR STREAM COMPRISING ALDEHYDE
A process for separating heavy by-products and catalyst ligand from a vapour stream comprising aldehyde, the heavy by-products and the catalyst ligand the process comprises passing the vapour stream to a fractionator in which the vapour stream is contacted with liquid aldehyde which removes at least a portion of the catalyst ligand and at least a portion of the heavy by-products from the vapour stream, recovering a liquid bottom stream, comprising removed catalyst ligand from the fractionator; recovering a scrubbed vapour stream from the fractionator, condensing a first portion of the scrubbed vapour stream to create the liquid aldehyde, and recovering a second portion of the scrubbed vapour stream as a product aldehyde stream. The liquid bottom stream is passed to a separation system to separate some aldehyde from the liquid bottom stream to create a recovered aldehyde stream, comprising the separated aldehyde.
PROCESS FOR SEPARATING HEAVY BY-PRODUCTS AND CATALYST LIGAN FROM A VAPOUR STREAM COMPRISING ALDEHYDE
A process for separating heavy by-products and catalyst ligand from a vapour stream comprising aldehyde, the heavy by-products and the catalyst ligand the process comprises passing the vapour stream to a fractionator in which the vapour stream is contacted with liquid aldehyde which removes at least a portion of the catalyst ligand and at least a portion of the heavy by-products from the vapour stream, recovering a liquid bottom stream, comprising removed catalyst ligand from the fractionator; recovering a scrubbed vapour stream from the fractionator, condensing a first portion of the scrubbed vapour stream to create the liquid aldehyde, and recovering a second portion of the scrubbed vapour stream as a product aldehyde stream. The liquid bottom stream is passed to a separation system to separate some aldehyde from the liquid bottom stream to create a recovered aldehyde stream, comprising the separated aldehyde.
ACOUSTIC STRING INSTRUMENT, AND METHODS FOR MANUFACTURING AND REPAIRING SAME
An acoustic string instrument includes a top plate, a back plate, and a body disposed between the top plate and the back plate. The body has a plurality of first positioning portions. At least one of the top plate or the back plate, or both has a plurality of second positioning portions. The first positioning portions are fixed to the second positioning portions corresponding to the first positioning portions.
ACOUSTIC STRING INSTRUMENT, AND METHODS FOR MANUFACTURING AND REPAIRING SAME
An acoustic string instrument includes a top plate, a back plate, and a body disposed between the top plate and the back plate. The body has a plurality of first positioning portions. At least one of the top plate or the back plate, or both has a plurality of second positioning portions. The first positioning portions are fixed to the second positioning portions corresponding to the first positioning portions.