Patent classifications
C07C211/50
ORGANIC AMINE COLLECTION METHOD
A method is provided for collecting a compound of formula (III) (in which R31 is a monovalent to trivalent organic group and n31 is an integer of 1 to 3) from a liquid phase component that is formed as a by-product in a method for producing a compound of general formula (I) (in which R11 is a monovalent to trivalent organic group and n11 is an integer of 1 to 3), wherein the collection method contains steps (1) to (3) or steps (A) and (B), and step (4). Step (1): a step for reacting the liquid phase component with at least one active hydrogen-containing compound in a reactor. Step (2): a step for returning a condensed liquid obtained by cooling gas phase components in the reactor to the reactor. Step (3): a step for discharging gas phase components that are not condensed in the step (2) to the outside of the reactor. Step (A): a step for mixing the liquid phase component, water, and a compound of general formula (III). Step (B): a step for reacting the liquid phase component with water inside the reactor. Step (4): a step for discharging, as a liquid phase component inside the reactor, the reaction liquid containing the compound of general formula (III) to the outside of the reactor.
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Aromatic Amine Resin, Epoxy Resin Composition And Cured Product Thereof
There are provided an aromatic amine resin represented by the following formula (1) wherein a plurality of R.sub.1's each independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, provided that a case where all R.sub.1's represent each a hydrogen atom is excluded, m represents an integer of 1 to 4, n represents an integer, and the average value (A) of n represents: 1≦A≦5, which can be utilized for a high-reliability semiconductor, a high-performance fiber-reinforced composite material, and others; an epoxy resin composition containing the aromatic amine resin; and an epoxy resin cured product having properties excellent in high heat resistance and low hygroscopicity, which is obtained by curing the epoxy resin composition.
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Aromatic Amine Resin, Epoxy Resin Composition And Cured Product Thereof
There are provided an aromatic amine resin represented by the following formula (1) wherein a plurality of R.sub.1's each independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, provided that a case where all R.sub.1's represent each a hydrogen atom is excluded, m represents an integer of 1 to 4, n represents an integer, and the average value (A) of n represents: 1≦A≦5, which can be utilized for a high-reliability semiconductor, a high-performance fiber-reinforced composite material, and others; an epoxy resin composition containing the aromatic amine resin; and an epoxy resin cured product having properties excellent in high heat resistance and low hygroscopicity, which is obtained by curing the epoxy resin composition.
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CATALYTIC MATERIAL COMPRISING Ni SUPPORTED ON AN OXIDIC SUPPORT COMPRISING Zr AND Si
A catalytic material comprising Ni supported on an oxidic support comprising Zr in oxidic form and Si in oxidic form, wherein the catalytic material comprises equal to or greater than 65 weight-% of Ni, calculated as elemental Ni, wherein the catalytic material exhibits a Ni:Zr atomic ratio in the range of from 8.5 to 50.0.
CATALYTIC MATERIAL COMPRISING Ni SUPPORTED ON AN OXIDIC SUPPORT COMPRISING Zr AND Si
A catalytic material comprising Ni supported on an oxidic support comprising Zr in oxidic form and Si in oxidic form, wherein the catalytic material comprises equal to or greater than 65 weight-% of Ni, calculated as elemental Ni, wherein the catalytic material exhibits a Ni:Zr atomic ratio in the range of from 8.5 to 50.0.
Organic compound, light emitting diode and light emitting device having the compound
The present disclosure relates to an organic compound having a fused aromatic or hetero aromatic ring including a carbazole or fluorene moiety and a group having excellent charge mobility property, and a light emitting diode and a light emitting device having the organic compound. The organic compound can be applied into the light emitting diode by using solution process and has very deep HOMO energy level. When the organic compound is applied into a chare transfer layer, a HOMO energy level bandgap between the charge transfer layer and an emitting material layer is reduced so that holes and electrons can be injected into the emitting material layer in a balanced manner.
Organic compound, light emitting diode and light emitting device having the compound
The present disclosure relates to an organic compound having a fused aromatic or hetero aromatic ring including a carbazole or fluorene moiety and a group having excellent charge mobility property, and a light emitting diode and a light emitting device having the organic compound. The organic compound can be applied into the light emitting diode by using solution process and has very deep HOMO energy level. When the organic compound is applied into a chare transfer layer, a HOMO energy level bandgap between the charge transfer layer and an emitting material layer is reduced so that holes and electrons can be injected into the emitting material layer in a balanced manner.
Iron oxide supported rhodium catalyst for nitroarene reduction
A supported catalyst having rhodium particles with an average diameter of less than 1 nm disposed on a support material containing magnetic iron oxide (e.g. Fe.sub.3O.sub.4). A method of producing the supported catalyst and a process of reducing nitroarenes to corresponding aromatic amines employing the supported catalyst with a high product yield are also described. The supported catalyst may be recovered with ease using an external magnet and reused.
Process for the preparation of di- and polyamines from the diphenylmethane series
The present invention provides a process for preparing di- and polyamines from the diphenylmethane series by converting aniline and formaldehyde in the absence of an acid catalyst to give aminal and water, removing the aqueous phase and further processing the organic aminal phase to give the di- and polyamines of the diphenylmethane series, in which use of a coalescence aid in the phase separation of the process product obtained in aminal reaction reduces the proportion of water and hence also of water-soluble impurities in the organic phase containing the aminal. The di- and polyamines of the diphenylmethane series obtained by acid-catalyzed rearrangement and workup after further processing of the aminal phase are outstanding suitably for preparation of the corresponding isocyanates.
Process for the preparation of di- and polyamines from the diphenylmethane series
The present invention provides a process for preparing di- and polyamines from the diphenylmethane series by converting aniline and formaldehyde in the absence of an acid catalyst to give aminal and water, removing the aqueous phase and further processing the organic aminal phase to give the di- and polyamines of the diphenylmethane series, in which use of a coalescence aid in the phase separation of the process product obtained in aminal reaction reduces the proportion of water and hence also of water-soluble impurities in the organic phase containing the aminal. The di- and polyamines of the diphenylmethane series obtained by acid-catalyzed rearrangement and workup after further processing of the aminal phase are outstanding suitably for preparation of the corresponding isocyanates.