Patent classifications
C07C217/92
Diphenylamine compounds and production method thereof
An inexpensive and convenient production method of diphenylamine compounds is provided, that can solve problems in the conventional technology such as decrease in reactivity, restriction of substituents, high temperature, high pressure, by-products or the like. Further, diphenylamine compounds useful as intermediates of medicine and agricultural chemicals are provided. Diphenylamine compounds are produced, represented by general formula (3): ##STR00001##
which is characterized by reacting aniline compounds represented by general formula (2): ##STR00002##
under the presence of base and ethers solvent, with 2,6-dichloronitrobenzene compound represented by general formula (1): ##STR00003##
and a diphenylamine compound represented by general formula (3).
Diphenylamine compounds and production method thereof
An inexpensive and convenient production method of diphenylamine compounds is provided, that can solve problems in the conventional technology such as decrease in reactivity, restriction of substituents, high temperature, high pressure, by-products or the like. Further, diphenylamine compounds useful as intermediates of medicine and agricultural chemicals are provided. Diphenylamine compounds are produced, represented by general formula (3): ##STR00001##
which is characterized by reacting aniline compounds represented by general formula (2): ##STR00002##
under the presence of base and ethers solvent, with 2,6-dichloronitrobenzene compound represented by general formula (1): ##STR00003##
and a diphenylamine compound represented by general formula (3).
Nickel containing hydrosilylation catalysts and compositions containing the catalysts
A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.
Nickel containing hydrosilylation catalysts and compositions containing the catalysts
A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.
Ferroelectric fluorescent self-assembly compound and organic electronic element including the same
Provided are a ferroelectric fluorescent self-assembly compound and an organic electronic element including the same. The organic electronic element of the present invention includes the ferroelectric fluorescent self-assembly compound to which a specific skeleton and a specific function group are introduced, thereby having excellent light-emitting property, ferroelectricity, and piezoelectricity.
Ferroelectric fluorescent self-assembly compound and organic electronic element including the same
Provided are a ferroelectric fluorescent self-assembly compound and an organic electronic element including the same. The organic electronic element of the present invention includes the ferroelectric fluorescent self-assembly compound to which a specific skeleton and a specific function group are introduced, thereby having excellent light-emitting property, ferroelectricity, and piezoelectricity.
HIGH AND MULTIPLE REDOX POTENTIAL, STABLE, AND SOLUBLE BIS-DIARYLAMINE DERIVATIVES AND USES THEREOF
The present disclosure concerns the synthesis and investigation of a series of bis-triaryl amine compounds that span a range of multi-electron oxidation potentials. The compounds feature good solubility in acetonitrile and an exceptionally high oxidation potential compared to usual low oxidation potentials of such compounds. Radical cations of the compounds were synthesized and isolated as PF.sub.6.sup. salts and characterized. Use of the compounds in a symmetrical RFB showed high cycling stability and capacity retention.
HIGH AND MULTIPLE REDOX POTENTIAL, STABLE, AND SOLUBLE BIS-DIARYLAMINE DERIVATIVES AND USES THEREOF
The present disclosure concerns the synthesis and investigation of a series of bis-triaryl amine compounds that span a range of multi-electron oxidation potentials. The compounds feature good solubility in acetonitrile and an exceptionally high oxidation potential compared to usual low oxidation potentials of such compounds. Radical cations of the compounds were synthesized and isolated as PF.sub.6.sup. salts and characterized. Use of the compounds in a symmetrical RFB showed high cycling stability and capacity retention.
Compound, preparation method and use thereof and perovskite solar cell containing same
The present disclosure provides a compound having a structure of formula (I), where R1 and R2 are defined in the specification. In addition, the present disclosure further provides a preparation method and use of the compound of formula (I), in particular to a perovskite solar cell including the compound of formula (I). This compound as a hole transport material has the advantages in that the use of additives can be avoided, thereby improving the photoelectric conversion efficiency and stability of the cell. ##STR00001##
Compound, preparation method and use thereof and perovskite solar cell containing same
The present disclosure provides a compound having a structure of formula (I), where R1 and R2 are defined in the specification. In addition, the present disclosure further provides a preparation method and use of the compound of formula (I), in particular to a perovskite solar cell including the compound of formula (I). This compound as a hole transport material has the advantages in that the use of additives can be avoided, thereby improving the photoelectric conversion efficiency and stability of the cell. ##STR00001##