Patent classifications
C07C2523/58
Methods for making catalyst systems
According to one or more embodiments presently disclosed, a catalyst system may be made by a method that includes introducing one or more alkali or alkaline earth metals to a zincosilicate support material, and introducing one or more platinum group metals to the zincosilicate support material. The zincosilicate support material may include an MFI framework type structure incorporating at least silicon and zinc.
Production of Neopentane
Disclosed herein are processes for producing neopentane. The processes generally relate to demethylating isooctane to produce neopentane. The isooctane may be provided by the alkylation of isobutane with butylenes.
CATALYST AND PROCESS FOR THE SELECTIVE CONVERSION OF HYDROCARBONS
A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.
PROCESSES FOR REGENERATING A CATALYST FOR THE SELECTIVE CONVERSION OF HYDROCARBONS
A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.
CATALYST AND PROCESS FOR THE SELECTIVE CONVERSION OF HYDROCARBONS
A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.
PROCESSES FOR REGENERATING A CATALYST FOR THE SELECTIVE CONVERSION OF HYDROCARBONS
A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.
CATALYST REGENERATION
The present disclosure provides an air-soak containing regeneration process reducing its time. The process includes (i) removing surface carbon species from a gallium-based alkane dehydrogenation catalyst in a combustion process in the presence of a fuel gas; (ii) conditioning the gallium-based alkane dehydrogenation catalyst after (i) in air-soak treatment at a temperature of 660 C. to 850 C. with (iii) a flow of oxygen-containing gas having (iv) 0.1 to 100 parts per million by volume (ppmv) of a chlorine source selected from chlorine, a chlorine compound or a combination thereof; and achieving a predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iv) 10% to 50% sooner in air-soak treatment than that required to achieve the same predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iii), but without (iv).
CATALYST FOR PREPARING CUMENE AND USE THEREOF
Provided is a catalyst for preparing cumene and use thereof. The catalyst provided includes a carrier and an active ingredient. The active ingredient includes: ingredient (1), which is palladium element; and ingredient (2), which is one or more selected from a group consisting of alkali metal elements, alkaline earth metals and molybdenum element. When the catalyst is used for preparing cumene by ?-methyl styrene hydrogenation, AMS conversion rate is high, and a product cumene has high selectivity.
Processes for Dehydrogenating Alkanes and Alkyl Aromatic Hydrocarbons
A hydrocarbon can be contacted with dehydrogenation catalyst particles to produce an effluent that can include coked catalyst particles and dehydrogenated hydrocarbon(s). A first stream rich in coked catalyst particles and a second stream rich in dehydrogenated hydrocarbon(s) and containing entrained catalyst particles can be separated from the effluent. The second stream can be contacted with a first quench medium to produce a cooled stream. The cooled stream can be contacted with a second quench medium within a quench tower. A gaseous stream that includes the dehydrogenated hydrocarbon(s), a first quench medium stream, and a slurry stream that includes the second quench medium and the entrained catalyst particles can be separated from the tower. The first quench medium can be recycled. The entrained catalyst particles can be separated from the slurry to provide recovered second quench medium and recovered entrained catalyst particles. The recovered second quench medium can be recycled.
Method for preparing dehydrogenation catalyst for linear chain light hydrocarbons with high regeneration efficiency
The present invention relates to a catalyst used in a dehydrogenation reaction of a linear hydrocarbon gas in a range of C3 to C4, and provides a dehydrogenation catalyst which is deposited on a carrier obtained by changing the phase of platinum, an auxiliary metal and an alkali metal, wherein the platinum and the auxiliary metal are present as a single complex within a certain thickness from the outer edges of the catalyst in an alloy form.