The present disclosure relates to a hydrocracking catalyst for preparing a C.sub.6-C.sub.9 light aromatic hydrocarbons having an increased BTX content from a polycyclic aromatic hydrocarbon, a method for preparing the same and a method for preparing a C.sub.6-C.sub.9 light aromatic hydrocarbons having an increased BTX content by using the same. More specifically, an effect of obtaining a C.sub.6-C.sub.9 light aromatic hydrocarbons having an increased BTX content with a high yield from the byproducts of oil refining and petrochemical processes, which contain polycyclic aromatic hydrocarbons such as naphthalene, alkylnaphthalene, etc., can be achieved by using a catalyst in which one or more metal selected from group VIII and one or more metal selected from group VIB are supported on a composite zeolite support of zeolite beta and zeolite ZSM-5.

Method of making BTX compounds including benzene, toluene, and xylene, including feeding heavy reformate to a reactor containing a composite zeolite catalyst. The composite zeolite catalyst includes a mixture of layered mordenite (MOR-L) comprising a layered or rod-type morphology with a layer thickness less than 30 nm and ZSM-5. The MOR-L, the ZSM-5, or both include one or more impregnated metals. The method further includes producing the BTX compounds by simultaneously performing transalkylation and dealkylation of the heavy reformate in the reactor. The composite zeolite catalyst is able to simultaneously catalyze both the transalkylation and dealkylation reactions.

The present disclosure provides an aromatization catalyst, a preparation method, a regeneration method and an aromatization method thereof. The preparation method comprises steps of: mixing a zeolite molecular sieve with a binder to obtain a catalyst precursor; the catalyst precursor is successively subjected to an ion exchange modification and a first modification treatment, and then subjected to a hydrothermal treatment, and further subjected to active metal loading and a second modification treatment, to obtain the aromatization catalyst. The aromatization catalyst has good carbon deposition resistance and high aromatization activity, and enables an aromatization reaction to be completed under mild conditions, and has high aromatic selectivity, and the liquid yield is above 98.5%.

Disclosed are processes for conversion of a feedstock comprising C.sub.8+ aromatic hydrocarbons to lighter aromatic products in which the feedstock and optionally hydrogen are contacted in the presence of the catalyst composition under conversion conditions effective to dealkylate and transalkylate said C.sub.8+ aromatic hydrocarbons to produce said lighter aromatic products comprising benzene, toluene and xylene. The catalyst composition comprises a zeolite, a first metal, and a second metal, and is treated with a source of sulfur and/or a source of steam.

A process for activating an aromatization catalyst includes contacting an aromatization catalyst with a carburizing gas in a carburization reactor at a carburization pressure in a range of greater than 300 kPa to 800 kPa, or 500 kPa to 600 kPa, to obtain a calcined aromatization catalyst. The carburizing gas provides a carbon source, preferably the carburizing gas comprises at least one of methane, ethane, propane, butane, or carbon monoxide.

Disclosed are a bifunctional catalyst and a preparation method therefor, the bifunctional catalyst being suitable to produce high-value aromatic hydrocarbons by subjecting alkylaromatic hydrocarbons to a disproportionation/transalkylation/dealkylation reaction while suppressing aromatic loss or subjecting C8 aromatic hydrocarbons to an isomerization reaction while suppressing xylene loss.

A method of oxidative dehydrogenating of butane stream comprises contacting the same with a bimetallic catalyst in the presence of oxygen, wherein the bimetallic catalyst containing nickel and bismuth or oxides thereof supported on solid support such as zirconium oxide, low aluminum MFI zeolite, and mesoporous silica foam. Various embodiments of the method of oxidative dehydrogenating the butane-containing hydrocarbon stream and the bimetallic catalyst are also provided.

Composite catalysts includes zeolite particles at least partially embedded in a catalyst support material and at least one catalytically active compound deposited on the outer surfaces and pore surfaces of the catalyst support material, zeolite particles, or both. A method of making the composite catalysts may include preparing a catalyst precursor mixture that includes the zeolite, catalyst support material, triblock copolymer surfactant, and the catalytically active compound precursor and spray drying the catalyst precursor mixture. The composite catalysts may be used as a single catalyst for conducting olefin metathesis and cracking reactions. A method for producing propene may include contacting a butene-containing feed with the composite catalysts.

A method of making a xylene isomerization catalyst comprises the steps of (i) contacting a ZSM-5 zeolite starting material having a silica to alumina molar ratio of 20 to 50 and having a mesopore surface area in the range of 50 m.sup.2/gram to 200 m.sup.2/gram in a reactor with a base to provide an intermediate zeolite material; (ii) recovering the intermediate ZSM-5 zeolite material of step (i); (iii) contacting the intermediate zeolite material with an acid to provide an acid treated ZSM-5 zeolite product; (iv) recovering the acid treated ZSM-5 zeolite material; and (v) calcining the acid treated ZSM-5 zeolite material to provide a desilicated ZSM-5 zeolite product having a silica to alumina molar ratio of 20 to 150 and having a mesopore surface area in the range of 100 m.sup.2/gram to 400 m.sup.2/gram.

A process for producing valuable aromatic hydrocarbons from a crude or semi-crude shale gas stream. A crude or semi-crude shale gas stream including methane is introduced into a reactor that converts at least a portion of the ethane component into aromatic hydrocarbons. Unreacted methane, other hydrocarbons, and hydrogen may then be easily separated from the aromatic hydrocarbons. Because methane is not separated from the shale gas stream, the expensive and resource-consuming shale gas C1/C2+ separation step is avoided.