Provided is a carboxymethylated microfibrillated cellulose fiber having a Canada standard freeness of less than 200 mL and an average fiber diameter of not less than 500 nm. Said fiber provides a composition having excellent water retention ability.

Provided is a carboxymethylated microfibrillated cellulose fiber having a Canada standard freeness of less than 200 mL and an average fiber diameter of not less than 500 nm. Said fiber provides a composition having excellent water retention ability.

Provided is a novel conjugate of a primary or secondary amine compound with an acidic polysaccharide, which is a compound represented by Formula (I) or a pharmaceutically acceptable salt thereof, where in Formula (I), D, R.sup.1, R.sup.2, A, and Poly are as defined in the specification.

A manufacturing method which includes: (1) an alkali cellulose reaction step wherein a mixed solvent having a mixing ratio (a mass ratio) of an alcohol having a carbon number of 3 or less and water of 75:25 to 95:5 is used, and the concentration of the base to the water is 25 to 40 mass %; (2) an etherification reaction step wherein a reaction is carried out under an excess base of 0.2 to 0.5 moles per unit of an anhydroglucose of the cellulose; (3) a neutralization step wherein acid is added to adjust the pH of the reaction mixture to 6.0 to 8.0; and (4) a heating step wherein the mixed solvent is removed, and a base is added to adjust the pH of the reaction mixture to 8.0 to 9.0, and then a heat treatment is performed at 40 to 70° C. for 30 to 120 minutes.

A manufacturing method which includes: (1) an alkali cellulose reaction step wherein a mixed solvent having a mixing ratio (a mass ratio) of an alcohol having a carbon number of 3 or less and water of 75:25 to 95:5 is used, and the concentration of the base to the water is 25 to 40 mass %; (2) an etherification reaction step wherein a reaction is carried out under an excess base of 0.2 to 0.5 moles per unit of an anhydroglucose of the cellulose; (3) a neutralization step wherein acid is added to adjust the pH of the reaction mixture to 6.0 to 8.0; and (4) a heating step wherein the mixed solvent is removed, and a base is added to adjust the pH of the reaction mixture to 8.0 to 9.0, and then a heat treatment is performed at 40 to 70° C. for 30 to 120 minutes.

The present document describes a process for the preparation of a low functionalization polysaccharide having carboxyl groups, comprising a) swelling of a polysaccharide granule in boiling water or a water/polyol mixture, to obtain a swollen polysaccharide; b) partial gelatinization of said swollen polysaccharide in an alkaline solvent mixture of water and alcohol and/or polyol, to obtain a partially gelatinized polysaccharide; and c) partial functionalization of said partially gelatinized polysaccharide with a functionalizing agent, to obtain the low functionalization polysaccharide.

The present document describes a process for the preparation of a low functionalization polysaccharide having carboxyl groups, comprising a) swelling of a polysaccharide granule in boiling water or a water/polyol mixture, to obtain a swollen polysaccharide; b) partial gelatinization of said swollen polysaccharide in an alkaline solvent mixture of water and alcohol and/or polyol, to obtain a partially gelatinized polysaccharide; and c) partial functionalization of said partially gelatinized polysaccharide with a functionalizing agent, to obtain the low functionalization polysaccharide.

Pulps, cellulose ether products, and methods of making pulps are described.

Provided is a fibrillated chemically modified cellulose fiber, which has a type-I cellulose crystallinity of at least 50%, an anionic charge density of 0.10-2.00 meq/g, and an average fiber diameter of greater than 500 nm. Also, provided is a fibrillated chemically modified cellulose fiber, wherein the value (A/B) obtained by dividing the viscosity A measured at a shear rate of 0.01/sec by the viscosity B measured at a shear rate of 1000/sec in an aqueous dispersion having a solid content of 1 mass % is at least 100. These fibers have high water retention and high thixotropy.

Provided is a fibrillated chemically modified cellulose fiber, which has a type-I cellulose crystallinity of at least 50%, an anionic charge density of 0.10-2.00 meq/g, and an average fiber diameter of greater than 500 nm. Also, provided is a fibrillated chemically modified cellulose fiber, wherein the value (A/B) obtained by dividing the viscosity A measured at a shear rate of 0.01/sec by the viscosity B measured at a shear rate of 1000/sec in an aqueous dispersion having a solid content of 1 mass % is at least 100. These fibers have high water retention and high thixotropy.