One aspect of this invention is a novel functional polymer having a polydispersity from 1 to about 1.12 comprising at least one reactive moiety, selected from a moiety comprising at least one N-coordinative functional group having at least one lone pair of electrons, a moiety comprising a dialkylsilyl group, or a mixture of both groups, wherein said reactive moiety is present in said functional styrenic polymer either on a repeat unit, on an end group or on both, and said N-coordinative functional group is either a monodentate N-coordinative functional group, a polydendate N-coordinative group or a mixture of thereof, and said monodentate coordinative functional group is an azide moiety (—N.sub.3) or a cyano moiety (—CN). Another aspect of this invention is the use of these novel polymer to selectively deposit a DSA directing layer on a metallic substrate.

One aspect of this invention is a novel functional polymer having a polydispersity from 1 to about 1.12 comprising at least one reactive moiety, selected from a moiety comprising at least one N-coordinative functional group having at least one lone pair of electrons, a moiety comprising a dialkylsilyl group, or a mixture of both groups, wherein said reactive moiety is present in said functional styrenic polymer either on a repeat unit, on an end group or on both, and said N-coordinative functional group is either a monodentate N-coordinative functional group, a polydendate N-coordinative group or a mixture of thereof, and said monodentate coordinative functional group is an azide moiety (—N.sub.3) or a cyano moiety (—CN). Another aspect of this invention is the use of these novel polymer to selectively deposit a DSA directing layer on a metallic substrate.

Disclosed are a resin composition comprising 20 to 50 mass % of a polyphenylene ether-based resin (a), 0.1 to 9 mass % of a polyphenylene ether-based resin modified with an unsaturated carboxylic acid or acid anhydride thereof (b), 15 to 50 mass % of a homopolystyrene (c), 1 to 25 mass % of one or more selected from the group consisting of a hydrogenated block copolymer (d-1) and a rubber-modified polystyrene (d-2), and 5 to 35 mass % of glass fibers (e) which are surface-treated, a resin composition comprising 20 to 50 mass % of a polyphenylene ether-based resin (a), 15 to 50 mass % of a homopolystyrene (c), 5 to 35 mass % of glass fibers (e), and 0.01 to 1 mass % of compounds (f), a method of producing the same, a molded article, and a mechanical component and housing.

Disclosed are a resin composition comprising 20 to 50 mass % of a polyphenylene ether-based resin (a), 0.1 to 9 mass % of a polyphenylene ether-based resin modified with an unsaturated carboxylic acid or acid anhydride thereof (b), 15 to 50 mass % of a homopolystyrene (c), 1 to 25 mass % of one or more selected from the group consisting of a hydrogenated block copolymer (d-1) and a rubber-modified polystyrene (d-2), and 5 to 35 mass % of glass fibers (e) which are surface-treated, a resin composition comprising 20 to 50 mass % of a polyphenylene ether-based resin (a), 15 to 50 mass % of a homopolystyrene (c), 5 to 35 mass % of glass fibers (e), and 0.01 to 1 mass % of compounds (f), a method of producing the same, a molded article, and a mechanical component and housing.

The present disclosure relates to a rubber composition and a method of preparing the same, the rubber composition comprising a viscosity modifier and a modified polymer having a structure in which a molecular weight regulator is coupled to at least one of both ends of an at least partially hydrogenated or non-hydrogenated petroleum resin. The rubber composition according to the present disclosure has improved processability and thus may replace process oil, and may markedly improve gas impermeability.

The present disclosure relates to a rubber composition and a method of preparing the same, the rubber composition comprising a viscosity modifier and a modified polymer having a structure in which a molecular weight regulator is coupled to at least one of both ends of an at least partially hydrogenated or non-hydrogenated petroleum resin. The rubber composition according to the present disclosure has improved processability and thus may replace process oil, and may markedly improve gas impermeability.

Metal oxide having a surface onto which a multitude of individual polymers are grafted, each polymer comprising an addition polymer having a first and a second end, and a first moiety comprising a terminal phosphonate group, which first moiety is bonded to the first end, which phosphonate group attaches to the metal oxide surface in such a way that the multitude of the grafted polymers comprises at least one group of adjacent polymers that have a stretched chain conformation wherein the adjacent stretched chains have a substantially parallel orientation, such that the polymers within said group together form a brush structure. Method of grafting a multitude of individual polymers onto a surface of a metal oxide.

This invention relates to processes for forming hydrogen mediated saline hydride initiated anionic polystyrene distributions via novel polymerization conditions. This invention also relates to novel hydrocarbon soluble super active saline hydride catalyst and reagent compositions useful in conducting the hydrogen mediated saline hydride initiated polymerizations of this invention. This invention also relates to novel low molecular weight polystyrene polymer composition formed exclusively from styrene and molecular hydrogen as the monomers.

This invention relates to processes for forming hydrogen mediated saline hydride initiated anionic polystyrene distributions via novel polymerization conditions. This invention also relates to novel hydrocarbon soluble super active saline hydride catalyst and reagent compositions useful in conducting the hydrogen mediated saline hydride initiated polymerizations of this invention. This invention also relates to novel low molecular weight polystyrene polymer composition formed exclusively from styrene and molecular hydrogen as the monomers.

This invention relates to processes for forming hydrogen mediated saline hydride initiated anionic polystyrene distributions via novel polymerization conditions. This invention also relates to novel hydrocarbon soluble super active saline hydride catalyst and reagent compositions useful in conducting the hydrogen mediated saline hydride initiated polymerizations of this invention. This invention also relates to novel low molecular weight polystyrene polymer composition formed exclusively from styrene and molecular hydrogen as the monomers.