A rubber composition, comprising: an uncross-linked rubber having no hydrogen-bond cross-linkable moiety; and at least one polymer component selected from the group consisting of polymers (A) each of which has a side chain (a) containing a hydrogen-bond cross-linkable moiety having a carbonyl-containing group and/or a nitrogen-containing heterocycle and has a glass-transition point of 25° C. or below and polymers (B) each of which contains a hydrogen-bond cross-linkable moiety and a covalent-bond cross-linking moiety in a side chain and has a glass-transition point of 25° C. or below; wherein an amount of the polymer component contained is 0.01 to 200 parts by mass relative to 100 parts by mass of the uncross-linked rubber, and the polymers (A) and the polymers (B) are each a reaction product of a maleic anhydride graft-modified thermoplastic polymer having a maleation ratio of 0.1 to 10% by mass and a cross-linkable compound.

A rubber composition, comprising: an uncross-linked rubber having no hydrogen-bond cross-linkable moiety; and at least one polymer component selected from the group consisting of polymers (A) each of which has a side chain (a) containing a hydrogen-bond cross-linkable moiety having a carbonyl-containing group and/or a nitrogen-containing heterocycle and has a glass-transition point of 25° C. or below and polymers (B) each of which contains a hydrogen-bond cross-linkable moiety and a covalent-bond cross-linking moiety in a side chain and has a glass-transition point of 25° C. or below; wherein an amount of the polymer component contained is 0.01 to 200 parts by mass relative to 100 parts by mass of the uncross-linked rubber, and the polymers (A) and the polymers (B) are each a reaction product of a maleic anhydride graft-modified thermoplastic polymer having a maleation ratio of 0.1 to 10% by mass and a cross-linkable compound.

The present invention relates to functionalized copolymers of isoolefins and olefinic monomers, particularly to azidated copolymers. The present invention also relates to methods of preparing such azidated copolymers. The functionalized copolymers are used in various technology areas such as surface modification, adhesion, drug delivery, compatibilization of polymer blends or motor oil and fuel additives, and in providing clean cured products without contaminant leaching and/or side products.

The present invention relates to functionalized copolymers of isoolefins and olefinic monomers, particularly to azidated copolymers. The present invention also relates to methods of preparing such azidated copolymers. The functionalized copolymers are used in various technology areas such as surface modification, adhesion, drug delivery, compatibilization of polymer blends or motor oil and fuel additives, and in providing clean cured products without contaminant leaching and/or side products.

Copolymers having a substantially heterogeneous composition distribution and strong UV absorption are the direct reaction product of an isoolefin and at least one terpene having the molecular formulae of (C.sub.5H.sub.8)n where n is equal to or greater than two, and optionally additional monomers. More specifically, the invention relates to copolymers of isobutylene and alloocimene that exhibit thermoplastic elastomeric properties and exhibit strong filler interaction. The present invention also relates to methods for producing copolymers of at least one isoolefin and at least one terepene by a two-phase living polymerization that produces a substantially linear triblock and multiblock copolymer having substantially heterogeneous distribution of the isoolefin and terpene units.

Copolymers having a substantially heterogeneous composition distribution and strong UV absorption are the direct reaction product of an isoolefin and at least one terpene having the molecular formulae of (C.sub.5H.sub.8)n where n is equal to or greater than two, and optionally additional monomers. More specifically, the invention relates to copolymers of isobutylene and alloocimene that exhibit thermoplastic elastomeric properties and exhibit strong filler interaction. The present invention also relates to methods for producing copolymers of at least one isoolefin and at least one terepene by a two-phase living polymerization that produces a substantially linear triblock and multiblock copolymer having substantially heterogeneous distribution of the isoolefin and terpene units.

Copolymers having a substantially heterogeneous composition distribution and strong UV absorption are the direct reaction product of an isoolefin and at least one terpene having the molecular formulae of (C.sub.5H.sub.8)n where n is equal to or greater than two, and optionally additional monomers. More specifically, the invention relates to copolymers of isobutylene and alloocimene that exhibit thermoplastic elastomeric properties and exhibit strong filler interaction. The present invention also relates to methods for producing copolymers of at least one isoolefin and at least one terepene by a two-phase living polymerization that produces a substantially linear triblock and multiblock copolymer having substantially heterogeneous distribution of the isoolefin and terpene units.

This invention relates to a method of preparing a brominated elastomer having a stabilized Mooney viscosity. The method includes polymerizing isomonoolefins and at least one polymerizable unit to obtain an elastomer/polymer; brominating the elastomer/polymer to form a brominated elastomer effluent; neutralizing the brominated elastomer effluent to form a neutralized effluent; volatizing off the hydrocarbon solvent; and recovering a brominated elastomer. In at least one point of the process, preferably prior to any significant temperature change in the brominated polymer, a Mooney stabilizer is added into the system. Portions of the Mooney stabilizer may be added at multiple points into the process.

This invention relates to a method of preparing a brominated elastomer having a stabilized Mooney viscosity. The method includes polymerizing isomonoolefins and at least one polymerizable unit to obtain an elastomer/polymer; brominating the elastomer/polymer to form a brominated elastomer effluent; neutralizing the brominated elastomer effluent to form a neutralized effluent; volatizing off the hydrocarbon solvent; and recovering a brominated elastomer. In at least one point of the process, preferably prior to any significant temperature change in the brominated polymer, a Mooney stabilizer is added into the system. Portions of the Mooney stabilizer may be added at multiple points into the process.

The present invention is directed to the functionalization of butyl rubber ionomer and optionally the grafting of polyamide to halobutyl rubber ionomers. Specifically, disclosed are methods and products resulting therefrom for creating functionalized ionomers and grafting polyamide to halobutyl ionomers via reactive extrusion. The process comprises reacting a halobutyl polymer with at least one nitrogen and/or phosphorous based nucleophile to provide a halobutyl ionomer comprising conjugated diene units; grafting of an amine-reactive dienophile to said ionomer to form a functionalized ionomer; and optionally blending the resulting functionalized ionomer with polyamide.