Patent classifications
C08F214/267
Co-cured fluoroelastomers with improved chemical resistance
Co-cured blends of fluoroelastomers of tetrafluoroethylene-propylene copolymer with cure site monomer and terpolymers of Vinylidene fluoride (VDF), Hexafluoropropylene (HFP) and Tetrafluoroethylene (TFE) with peroxide as initiator and coagent TAIC as crosslinker show improved curing performance, improved mechanical properties and improved compression set as well. The co-cured fluoroelastomers show improved chemical resistance to the solvent aging systems and better retention of mechanical properties after aging at high temperature in the solvents system.
POLYMER, COMPOSITION, COATING FILM, LAYERED PRODUCT, BACK SHEET, AND SOLAR CELL MODULE
Provided is a polymer capable of providing a coating film that has good initial adhesiveness to a base material and good adhesiveness thereto after a pressure cooker test, and has excellent abrasion resistance as determined by a falling sand abrasion test. The polymer includes a perhaloolefin unit, a vinyl ester unit that contains neither a hydroxy group nor an aromatic ring; and a hydroxy group-containing monomer unit. The polymer has a hydroxyl value of 110 mgKOH/g or greater.
FLUOROELASTOMERS WITH IMPROVED CHEMICAL RESISTANCE
Co-cured blends of fluoroelastomers of tetrafluoroethylene-propylene copolymer with cure site monomer and a pentapolymer of vinylidene fluoride (VDF), hexafluoropropylene (HFP), tetrafluoroethylene (TFE), perfluorinated methyl vinyl ether (PMVE) and ethylene (PE) with peroxide as initiator and coagent TAIC as crosslinker show improved curing performance, improved mechanical properties and improved compression set as well. The co-cured fluoroelastomers show improved chemical resistance to the solvent aging systems and better retention of mechanical properties after aging at high temperature in the solvents system.
Wafer cup
A wafer cup including a copolymer containing a tetrafluoroethylene unit and a fluoro(alkyl vinyl ether) unit. A water contact angle of at least a part of an inner surface of the wafer cup is 80 degrees or less.
Solvent-based paint composition and fluorine-containing copolymer
Provided is a paint composition which can give a coating having excellent stretchability and further having excellent contamination resistance. A solvent-based paint composition comprises a fluorocopolymer (I), and an organic solvent (II), the fluorocopolymer (I) including: a perhaloolefin structural unit (a) that contains two carbon atoms, a vinyl acetate structural unit (b), a hydroxyl group-containing vinyl monomer structural unit (c) represented by the following formula (1): CH.sub.2CHO(CH.sub.2).sub.nOH wherein n is an integer of 2 or more, and a carboxyl group-containing monomer structural unit (d) represented by the following formula (2): R.sup.1R.sup.2CCR.sup.3(CH.sub.2).sub.mCOOH wherein R.sup.1, R.sup.2, and R.sup.3 are the same as or different from one another, and each a hydrogen atom or a C1-C10 linear or branched alkyl group; and m is an integer of 2 or more.
Photocurable fluorinated polymer composition
To provide a photocurable fluorinated polymer composition which has a high curing rate, shows little shrinkage before and after photocuring and requires no post treatment such as heat treatment after photocuring and whereby it is possible to obtain a cured resin excellent in heat resistance and weather resistance. According to the photocurable fluorinated polymer composition comprising a fluorinated polymer (A) containing polymerized units derived from a fluoroolefin and polymerized units derived from an unsaturated monomer having an oxetanyl group or a substituted oxetanyl group, and a photoreaction initiator (B), of the present invention, it is possible to provide a photocurable fluorinated polymer composition which has a high curing rate, shows little shrinkage before and after photocuring and requires no post treatment such as heat treatment after photocuring and whereby it is possible to obtain a cured resin excellent in heat resistance and weather resistance.
Binder for storage battery device
To provide a binder for a storage battery device whereby favorable adhesion is obtainable and swelling by an electrolytic solution can favorably be suppressed. A binder for a storage battery device, which is made of a fluorinated copolymer comprising structural units (A), structural units (B) and structural units (C), wherein the molar ratio of the structural units (C) to the total of all the structural units excluding the structural units (C) is from 0.01/100 to 3/100: structural units (A): structural units derived from a monomer selected from the group consisting of tetrafluoroethylene, hexafluoropropylene, vinylidene fluoride and chlorotrifluoroethylene; structural units (B): structural units derived from ethylene or propylene; and structural units (C): structural units derived from a C.sub.5-30 organic compound having at least two double bonds and at least one of the double bonds being a double bond of a vinyl ether group or a double bond of a vinyl ester group.
Method for producing fluorine-containing polymer
Provided is a method for producing a fluoropolymer in the presence of a specific non-fluorinated compound having surface activity. The method shows a high polymerization rate, and suppresses formation of sticking polymerization materials after production of a polymer product. The method includes aqueous dispersion polymerization of a fluoroolefin in the presence of a compound (1) represented by formula (1): ##STR00001## wherein R.sup.1 and R.sup.2 are the same as or different from each other, and each represent a C4 to C12 non-fluorinated saturated hydrocarbon group; and M is an alkali metal, an ammonium salt, or an amine salt.
FLUORORESIN LONG FILM, METAL-CLAD LAMINATE AND SUBSTRATE FOR CIRCUIT
Provided is a fluororesin long film that has high uniformity and does not deform when bonded to metal foil. A fluororesin long film including a fluororesin in which the number of unstable functional groups is less than 350 per 110.sup.6 carbon atoms, where a difference between each average film thickness in a travel direction at every 5 mm in a width direction and an average film thickness of entire surface is within 2 m.
Method for producing fluorine-containing polymer, aqueous dispersion liquid, and fluorine-containing polymer composition
A method for producing a fluorinated polymer which does not require an emulsifier as an essential component while an aqueous medium with little environmental burden is used. A method for producing a fluorinated polymer, which includes polymerizing a fluorinated monomer selected from tetrafluoroethylene, chlorotrifluoroethylene and vinylidene fluoride, in an aqueous medium in the presence of a first polymer having units based on a compound represented by formula (1): CXYCR.sup.1-L-R.sup.2.