Methods for producing a polymer with end groups of formula (I), which is free of isocyanate groups, ##STR00001##
wherein at least one hydrosilane of formula (II) is reacted with at least one polyurethane polymer containing isocyanate groups, ##STR00002##
where R.sup.1 stands for an alkyl group having 1 to 12 C atoms, R.sup.2 stands for a hydrogen atom or for an alkyl group having 1 to 12 C atoms, which optionally comprises ether oxygen or amine nitrogen, R.sup.3 stands for a linear or a branched alkylene or cycloalkylene residue having 1 to 20 C atoms, optionally with aromatic parts, and optionally with one or more heteroatoms, R.sup.4 stands for an alkyl group having 1 to 6 C atoms, R.sup.5 stands for an alkyl group having 1 to 10 C atoms, which optionally comprises one or more ether oxygens, n stands for 2 or 3 or 4, and x stands for 0 or 1.

The invention relates to a composition and to a process for preparing moisture-crosslinking polymers under catalysis by at least one metal-siloxane-silanol(ate) compound, and to the use of the composition in the CASE sector (coatings, adhesives, sealants and elastomers), especially in the field of adhesives and sealants.

Disclosed is a polyurethane for use in a polishing layer, including a carboxylic acid ester group, and a polyurethane preferably having a carboxylic acid ester group in at least one of a side chain, a main chain terminal, and a main chain skeleton is preferably used. Also disclosed is a method for modifying a polishing layer, including the steps of: preparing a polishing layer including a polyurethane having a carboxylic acid ester group; and hydrolyzing the carboxylic acid ester group of the polyurethane, to produce a carboxyl group.

The present invention is directed to provide a corrosion-resistant coating composition that is capable of forming a coating film with superior moisture resistance and a superior corrosion-resistant property for a long period, particularly over a long period even under acidic environmental conditions, further with superior storage stability.

The corrosion-resistant coating composition of the present invention comprises a coating film-forming resin (A), a crosslinking agent (B), and a magnesium hydroxide (C), wherein the oil absorption of the magnesium hydroxide (C) is 70 g/100 g or less and wherein the BET specific surface area is 4.0 m.sup.2/g or less.

A paint composition contains (A) a binder component, (B) a first rheology control agent, and (C) a second rheology control agent, wherein the first rheology control agent (B) is a non-aqueous dispersion resin (b); the second rheology control agent (C) contains a reaction product of (c1) a polyisocyanate compound, (c2) a primary monoamine having a number average molecular weight of 300 or less, and (c3) a polyether amine having two or more amino groups and having a number average molecular weight of 1000 or more and less than 6000; and the proportion of the polyether amine having two or more amino groups and having a number average molecular weight of 1000 or more and less than 6000 (c3) is within the range of 10 to 30 mass % based on the total amount of the components (c1) to (c3).

The present invention relates to a selective process for the preparation of NCO-functionalized polyols, to their use in the preparation of silylated polyurethanes, to processes for preparing silylated polyurethanes and to silylated polyurethanes obtainable by a reaction of NCO-functionalized polyol with amino silane and to their use in CASE applications (coatings, adhesives, sealants and elastomers).

A rheology control agent contains a reaction product of a polyisocyanate compound (a1), a primary monoamine having a number average molecular weight of 300 or less (a2), and a polyether amine having two or more amino groups and having a number average molecular weight of 1000 or more and less than 6000 (a3), wherein the proportion of the polyether amine having a number average molecular weight of 1000 or more and less than 6000 (a3) is within the range of 10 to 30 mass % based on the total amount of the components (a1) to (a3).

A trimerization catalyst composition comprising a trimerization catalyst compound selected from one or more organic metal salt, preferably alkali or earth alkali metal salts, and one or more compounds selected from compounds which comprise a carboxamide group having the structure —CO—NH.sub.2 and/or from compounds which comprise a group having the structure —CO—NH—CO— is disclosed.

Further a stable polyisocyanate composition comprising the catalyst composition and a process for making the polyisocyanate composition is disclosed.

A curable polyisocyanate composition is obtained comprising the catalyst composition, a polyisocyanate composition, an epoxy resin and optionally a polyol/monool composition and a polyisocyanurate comprising material made by allowing the curable composition to react at elevated temperature and a process for making the polyisocyanurate comprising material.

Provided are a carbodiimide-based, waterborne resin crosslinking agent that not only is excellent in the storage stability when the crosslinking agent and a waterborne resin are caused to coexist, but also can improve physical properties such as solvent resistance and water resistance of a cured product of the waterborne resin, and a waterborne resin crosslinking agent-containing liquid and a waterborne resin composition comprising the same. The waterborne resin crosslinking agent of the present invention comprises a predetermined polycarbodiimide compound (A) having an oxyalkylene group, a predetermined polycarbodiimide compound (B), and a surfactant (C), each polycarbodiimide compound has a structure in which an isocyanate group is capped with a predetermined end-capping compound at each of both terminals, a total content of the oxyalkylene group in (A) is 15% by mass or more, a total content of the oxyalkylene group in (A) and (B) based on a total amount of (A) and (B) is 10% by mass or less, and a content of (C) is 0.1 to 20 parts by mass based on a total content of (A) and (B) of 100 parts by mass.

A photochromic hydroxyurethane compound of the present invention is characterized in that, on condition of having at least one photochromic moiety as the photochromic minimal unit in a molecule, it has a hydroxyurethane constitutional unit represented by Formula (1):

—X—O—CO—NH—  (1)

In the formula, X is an oxygen-containing chain organic group having a hydroxyl group as a substituent, or a hydrogen atom in the hydroxyl group is substituted by any one of (A): a photochromic group having the photochromic moiety; (B): a polymerization reactive group having a polymerizable substituent; (C) an alkyl group having 1 to 10 carbon atoms; (D) a cycloalkyl group having 3 to 10 carbon atoms; or (E): an aryl group having 6 to 14 carbon atoms (each of the groups (C)-(E) can be bonded to an oxygen atom derived from the hydroxyl group via the oxygen-containing chain organic group).