This invention relates to an in-situ formed polyol blend having an overall functionality of 2 to 3 and an overall hydroxyl number of 50 to 150. A process for preparing these polyol blends is also disclosed. These in-situ formed polyol blends are suitable for preparing viscoelastic flexible polyurethane foams. A process for preparing these foams is also disclosed.

A waterborne one-component coating composition capable of self-crosslinking and exhibiting a gloss and hardness improvement when cured that is similar to a solventborne two-component composition. The composition includes a urethane phase including a polyurethane polymer with at least polyester diol monomer units, polycarbonate diol monomer units, and ketone-functionalized diol monomer units. The composition may include an optional acrylic phase including an acrylic polymer having monomer units selected from one of alkyl (meth)acrylate monomer units, vinyl acetate monomer units, styrene monomer units, ketone-functional vinyl monomer units, or combinations thereof. The composition includes a hydrazine-functionalized crosslinking agent configured to crosslink one of the ketone-functionalized diol monomer units, the ketone-functional vinyl monomer units, or both. The composition further includes one or more tertiary amine reaction moderators or neutralizing agents.

Polyether polyols are prepared by polymerizing unsaturated monomers in a continuous phase of a base polyol. A macromer or polymerization produce of such a macromer is present during the polymerization to stabilize the polymer particles as they form. The macromer is a polyether capped with certain unsaturated epoxide compounds.

The invention pertains generally to a shelf-stable polyurethane HFO-blown two-component polyurethane foam composition which includes controlling the ratio of tin-containing catalyst(s) to potassium-containing catalyst(s).

Flexible polyurethane foams are made by reacting a hydrophilic quasi-prepolymer, water and a polymer polyol in the presence of a silicone surfactant and an ethylene oxide/higher alkylene oxide block copolymer. The foams exhibit desirably low densities and compression sets, and have good thermal and moisture-wicking properties. The foams are useful in bedding and other comfort applications in which they are exposed to body heat and bear at least a portion of the weight of the user. The thermal and moisture wicking properties contribute to perceived comfort for the user.

Flexible polyurethane foams are made by reacting a hydrophilic quasi-prepolymer, water and a polymer polyol in the presence of a silicone surfactant and an ethylene oxide/higher alkylene oxide block copolymer. The foams exhibit desirably low densities and compression sets, and have good thermal and moisture-wicking properties. The foams are useful in bedding and other comfort applications in which they are exposed to body heat and bear at least a portion of the weight of the user. The thermal and moisture wicking properties contribute to perceived comfort for the user.

New shape memory polymer compositions, methods for synthesizing new shape memory polymers, and apparatus comprising an actuator and a shape memory polymer wherein the shape memory polymer comprises at least a portion of the actuator. A shape memory polymer comprising a polymer composition which physically forms a network structure wherein the polymer composition has shape-memory behavior and can be formed into a permanent primary shape, re-formed into a stable secondary shape, and controllably actuated to recover the permanent primary shape. Polymers have optimal aliphatic network structures due to minimization of dangling Chains by using monomers that are symmetrical and that have matching amine and hydroxl groups providing polymers and polymer foams with clarity, tight (narrow temperature range) single transitions, and high shape recovery and recovery force that are especially useful for implanting in the human body.

Very soft, launderable polyurethane foams for pillow and other bedding applications are made using a quasi-prepolymer of diphenylmethane diisocyanate and a polyether polyol having a high oxyethylene content. The quasi-prepolymer is reacted with isocyanate-reactive components that include a certain monoalcohol but is devoid of or nearly devoid of a polyether polyol having a high oxyethylene content.

The present invention provides a synthetic leather including at least a base material (i), an adhesive layer (ii), and a skin layer (iii), wherein the adhesive layer (ii) is formed of an anionic urethane resin composition containing an anionic urethane resin (S) having an anionic group concentration of 0.25 mmol/g or less, water (T), and an anionic surfactant (U), and the skin layer (iii) is formed of a urethane resin composition containing a urethane resin (A), for which a raw material is reactive silicone (a1) having a functional group that reacts with an isocyanate group, and containing water (B). Preferably, the urethane resin (A) is an anionic urethane resin having an acid value of 20 mgKOH/g or less.

The present invention provides a flexible wrapping material comprising a coolant gel composition comprising, i) at least one hydrophilic polyurethane prepolymer, ii) a coolant agent, iii) water, and iv) thermally conductive filler.