A preparation method for an ultraviolet-responsive coumarin controlled-release and self-repairing anti-fouling paint includes: reacting double-end-group reactive polydimethylsiloxane, polyisocyanate, and an organic diluting solvent; adding a dihydroxycoumarin compound, a cross-linking agent and an organotin catalyst; adding a simple coumarin compound, and irradiating the mixture with 365 nm ultraviolet light to obtain the anti-fouling paint. An anti-fouling coat formed by the paint of the present invention has the advantages of controllable release of a coumarin green anti-fouling agent in response to external ultraviolet stimulation and self-repairing, and the problems that the release of the conventional anti-fouling agents in the anti-fouling coat is difficult to control, and that the low-surface-energy anti-fouling coat is difficult to repair after being damaged are solved. The anti-fouling application requirements of various shallow sea light-transmitting constructions can be met, the service life is prolonged, and the application performance in a complex real sea environment is enhanced.

A method for preparing a novel waterborne polyurethane foam layer for synthetic leather is disclosed. The method includes first preparing a charged cellulose nanofiber by using a wood pulp as a raw material; meanwhile, subjecting a polyisocyanate, a macromolecular diol, a hydrophilic chain extender and a small molecular chain extender to a polyaddition reaction and an acid-base neutralization reaction in sequence, to obtain a cationic or anionic waterborne polyurethane; adding the charged cellulose nanofiber and a certain amount of a crosslinking agent to the oppositely charged ionic waterborne polyurethane emulsion, stirring the resulting mixture, forming a bimolecular layer at the gas/liquid interface by a self-assembly of the cellulose nanofiber and waterborne polyurethane nanoparticles through electrostatic interactions to obtain a stable Pickering foam; using the stable Pickering foam as a template, drying and solidifying to obtain the waterborne polyurethane foam layer for synthetic leather.

The present invention relates to aspartic acid ester-functional polysiloxanes, their use in the manufacture of curable compositions using polyisocyanate crosslinkers, in particular, in the manufacture of coating compositions, cured compositions obtained from said curable compositions and articles comprising the cured compositions.

The present invention relates to an NCO-terminated polysiloxane prepolymer of the general formula (I) [(Q).sub.q]-(M).sub.m-(P).sub.p—(R).sub.r].sub.t, in which R, P, M, Q, r, p, m, q and t are defined as follows: R in each case independently is at least one polyisocyanate unit and/or at least one diisocyanate unit, P in each case independently is at least one polyol unit, M in each case independently is at least one diisocyanate unit and/or at least one polyisocyanate unit, Q is at least one polysiloxane unit, r in each case independently is a number from 1 to 10, p in each case independently is a number from 1 to 10, m in each case independently is a number from 1 to 10, q in each case independently is a number from 1 to 10, t is an integer from 2 to 5, and the M units present are attached directly to the unit Q; to a process for producing said prepolymer, and to use as curing agent in a coating formulation.

The present invention relates to an NCO-terminated polysiloxane prepolymer of the general formula (I) [(Q).sub.q]-(M).sub.m-(P).sub.p—(R).sub.r].sub.t, in which R, P, M, Q, r, p, m, q and t are defined as follows: R in each case independently is at least one polyisocyanate unit and/or at least one diisocyanate unit, P in each case independently is at least one polyol unit, M in each case independently is at least one diisocyanate unit and/or at least one polyisocyanate unit, Q is at least one polysiloxane unit, r in each case independently is a number from 1 to 10, p in each case independently is a number from 1 to 10, m in each case independently is a number from 1 to 10, q in each case independently is a number from 1 to 10, t is an integer from 2 to 5, and the M units present are attached directly to the unit Q; to a process for producing said prepolymer, and to use as curing agent in a coating formulation.

The present invention provides nanometer-sized fibers that are produced by an electrospinning method with use of a spinning solution for electrospinning, said spinning solution being environmentally friendly and taking the effects of an organic solvent on the human body into consideration. The fibers are formed from a resin that contains a silicone-modified polyurethane resin which is a reaction product of (A) a polyol, (B) a water dispersant, (C) an active hydrogen group-containing organopolysiloxane represented by formula (1)

R.sup.1R.sup.2R.sup.3SiO(SiR.sup.2R.sup.3O).sub.nSiR.sup.1R.sup.2R.sup.3  (1)

(wherein R.sup.1 represents a monovalent hydrocarbon group which may have an oxygen atom in the chain, while having from 1 to 10 carbon atoms and a hydroxyl group or a mercapto group, or a monovalent hydrocarbon group which has a primary amino group or a secondary amino group, while having from 1 to 10 carbon atoms; each of R.sup.2 and R.sup.3 represents a group that is selected from among an alkyl group having from 1 to 10 carbon atoms, an aralkyl group having from 7 to 10 carbon atoms, an aryl group having from 6 to 12 carbon atoms and a vinyl group; and n represents an integer from 1 to 200), and (D) a polyisocyanate.

The present invention provides nanometer-sized fibers that are produced by an electrospinning method with use of a spinning solution for electrospinning, said spinning solution being environmentally friendly and taking the effects of an organic solvent on the human body into consideration. The fibers are formed from a resin that contains a silicone-modified polyurethane resin which is a reaction product of (A) a polyol, (B) a water dispersant, (C) an active hydrogen group-containing organopolysiloxane represented by formula (1)

R.sup.1R.sup.2R.sup.3SiO(SiR.sup.2R.sup.3O).sub.nSiR.sup.1R.sup.2R.sup.3  (1)

(wherein R.sup.1 represents a monovalent hydrocarbon group which may have an oxygen atom in the chain, while having from 1 to 10 carbon atoms and a hydroxyl group or a mercapto group, or a monovalent hydrocarbon group which has a primary amino group or a secondary amino group, while having from 1 to 10 carbon atoms; each of R.sup.2 and R.sup.3 represents a group that is selected from among an alkyl group having from 1 to 10 carbon atoms, an aralkyl group having from 7 to 10 carbon atoms, an aryl group having from 6 to 12 carbon atoms and a vinyl group; and n represents an integer from 1 to 200), and (D) a polyisocyanate.

A polyether-modified siloxane represented by an average composition formula (1): (R.sub.3SiO.sub.1/2).sub.a(R.sub.2R′SiO.sub.1/2).sub.a′(R.sub.2SiO.sub.2/2).sub.b(RR′SiO.sub.2/2).sub.b′(RSiO.sub.3/2).sub.c(SiO.sub.4/2).sub.d. In the formula (1), “R”s each represent a hydrogen atom, a hydroxy group, a monovalent hydrocarbon group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 10 carbon atoms, “R” 's each represent an organic group selected from groups represented by —C.sub.qH.sub.2q—O—(C.sub.2H.sub.4O).sub.e(C.sub.3H.sub.6O).sub.f—R.sup.1, R.sup.1s each represent a hydrogen atom, a hydrocarbon group having 1 to 30 carbon atoms, or an organic group represented by R.sup.6—(CO)—, and R.sup.6 represents a hydrocarbon group having 1 to 30 carbon atoms. This can provide a novel polyether-modified siloxane that has little environmental impact and that provides excellent antifouling performance.

A stretchable film is made of, at least as a top surface of the stretchable film, a cured product of a stretchable film material containing a silicone polyurethane resin. The top surface of the stretchable film has a repeated uneven pattern formed with depths of 0.1 μm to 2 mm and pitches of 0.1 μm to 5 mm. Thus, the present invention provides a stretchable film having excellent stretchability, with the film top surface being excellent in water repellency and free from sticking; and a method for forming the stretchable film.

A stretchable wiring film includes: (A) a stretchable film made of, at least as a top surface of the stretchable film, a cured product of a stretchable film material containing a silicone polyurethane resin; and (B) a stretchable wiring. The top surface of the stretchable film has a repeated uneven pattern formed with depths of 0.1 μm to 5 mm and pitches of 0.1 μm to 10 mm. The stretchable wiring is formed on the top surface of the stretchable film where the repeated uneven pattern is formed. Thus, the present invention provides: a stretchable wiring film having less decrease in electric conductivity in stretching and excellent water repellency on the film top surface; and a method for forming the stretchable wiring film.