The present invention relates to alkoxysilane-functionalized and allophanate-functionalized urethanes, methods for the preparation thereof, coating compositions comprising these and to the use thereof.

An alkoxysilane-functionalized and allophanate-functionalized coating material including a) a binder component of 10-99 wt % of at least one reaction product of I. and II. wherein I includes A) at least one alkoxysilane-containing monourethane A) of the formula 1 R.sub.n(OR.sub.1).sub.3-nSi—R.sup.2—NH—(C═O)—OR.sup.3 wherein R, R.sup.1, R.sup.2 and R.sup.3 represent hydrocarbon radicals having 1-8 carbon atoms, and n represents 0-2, and B) at least one diisocyanate B), and II includes the subsequent reaction of C) with at least one diol and/or polyol C), in a ratio of NCO groups of reaction product I to OH groups of the diol and/or polyol II. C) of 1.0:1.5 to 1.0:0.6; b) 1-90 wt % of at least one further binder component distinct from a) a hydroxyl-containing or amino-containing binder component, c) 0-50 wt % of at least one polyisocyanate having an NCO functionality of at least 2, d) 0-5 wt % of at least one catalyst, wherein components a)-d) add up to 100 wt %.

The present invention relates to alkoxysilane-functionalized allophanates, to methods for production thereof, and to the use thereof. In particular, the alkoxysilane-functionalized allophanate includes the reaction product of A) at least one alkoxysilane group-containing monourethane A) of the formula 1

R.sub.n(OR.sup.1).sub.3-nSi—R.sup.2—NH—(C═O)—OR.sup.3   formula 1,

where R, R.sup.1, R.sup.2 and R.sup.3 are each independently hydrocarbyl radicals having 1-8 carbon atoms, which may be linear, branched or cyclic, or else may be integrated together to form a cyclic system, and n is 0-2, and B) at least one diisocyanate B), in a molar ratio of A) to B) of 3:1 to 1.5:1.

The invention relates to the use of an adhesive composition to provide a bonding in a wet environment. The invention also relates to a method for providing a bonding in a wet environment.

The invention relates to the use of an adhesive composition to provide a bonding in a wet environment. The invention also relates to a method for providing a bonding in a wet environment.

A rubber composition for a tire according to an embodiment of the present technology includes: 100 parts by mass of a diene rubber and from 1 to 30 parts by mass of a thermally expandable microcapsule composite body, and the thermally expandable microcapsule composite body contains one or more thermally expandable microcapsules and an acrylonitrile butadiene copolymer and/or a crosslinked body thereof covering the one or more thermally expandable microcapsules.

A silylated polyurethane obtainable by a process comprising the following steps: (a) reacting at least one polyol with at least one triisocyanate to form a hydroxyl-terminated polyurethane prepolymer, and (b) reacting said polyurethane prepolymer with at least one isocyanatosilane of the formula (1): OCN—R—Si—(X).sub.m(R.sup.1).sub.3-m, wherein m is 0, 1 or 2, each R.sup.1 is independently from each other a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, an acyloxy group having 1 to 10 carbon atoms, or —OCH(R.sup.2)COOR.sup.3, wherein R.sup.2 is hydrogen or an alkyl group having 1 to 4 carbon atoms and R.sup.3 is a straight-chain or branched alkyl group having 1 to 8 carbon atoms, each X is independently from each other and optionally substituted hydrocarbon group having 1 to 10 carbon atoms, which can be interrupted by at least one heteroatom, and R is a difunctional organic group, to endcap the hydroxyl groups on said prepolymer with said isocyanatosilane. The silylated polyurethanes are suitable for use in a preparation as an adhesive, sealant, or coating agent.

A silylated polyurethane obtainable by a process comprising the following steps: (a) reacting at least one polyol with at least one triisocyanate to form a hydroxyl-terminated polyurethane prepolymer, and (b) reacting said polyurethane prepolymer with at least one isocyanatosilane of the formula (1): OCN—R—Si—(X).sub.m(R.sup.1).sub.3-m, wherein m is 0, 1 or 2, each R.sup.1 is independently from each other a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, an acyloxy group having 1 to 10 carbon atoms, or —OCH(R.sup.2)COOR.sup.3, wherein R.sup.2 is hydrogen or an alkyl group having 1 to 4 carbon atoms and R.sup.3 is a straight-chain or branched alkyl group having 1 to 8 carbon atoms, each X is independently from each other and optionally substituted hydrocarbon group having 1 to 10 carbon atoms, which can be interrupted by at least one heteroatom, and R is a difunctional organic group, to endcap the hydroxyl groups on said prepolymer with said isocyanatosilane. The silylated polyurethanes are suitable for use in a preparation as an adhesive, sealant, or coating agent.

The present invention relates to a selective process for producing polyurethane prepolymers, to the polyurethane prepolymers obtainable from this process, and also to a process for producing moisture-crosslinking silylated polymers, more particularly silane-functional hybrid polymers, and also to the use thereof in CASE sectors (coatings, adhesives, sealants and elastomers).

The present invention relates to a heat-crosslinkable adhesive composition comprising: —from 20% to 84% by weight of composition (A); —from 15% to 79% by weight of a compatible tackifying resin (B), —from 0.01% to 5% by weight of a crosslinking catalyst (C). The invention also relates to a self-adhesive item obtained by preheating said composition, coating on a support layer, then crosslinking by heating.