In general the present invention relates to polyurethanes based on the reaction of (a) a disocianate composition with (b) depolymerized lignin containing lignin-derived monomers, or the products of their respective functionalization; (c) a polyol composition, if desired (d) chain extenders, if desired. (e) additives, if desired. More specifically, this process relates to the use of depolymerized lignins containing varying amounts of 4-hydroxylalkylphenols or 4-alkylphenols and their derivatives. The polyurethanes can be partially or fully bio-based. Furthermore, the invention relates to a method for preparing these polyurethanes and to their use.

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

The invention relates to a method for producing a composite film with a polyurethane-based reactive hot-melt layer using a coating facility, having the steps of a) optionally applying a primer onto a support material; b) applying the polyurethane-based reactive hot-melt layer onto the primer or directly onto the support material; c) applying a lacquer layer onto the polyurethane-based reactive hot-melt layer in order to produce the composite film on the support material; d) optionally embossing the composite film on the support material; and e) separating the composite film from the support material. The invention additionally relates to a composite film which can be obtained by such a method and to the use thereof.

The present invention relates to a hydrophilic acrylic-modified polyurethane and a method for preparing same, and a water-based paint composition using same and a manufacturing method thereof and, more specifically, to a hydrophilic acrylic-modified polyurethane and a method for preparing same, and a water-based paint composition using same and a manufacturing method thereof, the hydrophilic acrylic-modified polyurethane comprising: a polymerization unit derived from an anhydrosugar alcohol-alkylene oxide adduct; a polymerization unit derived from polyisocyanate; and a polymerization unit derived from hydroxyalkyl (meth)acrylate, and capable of providing a water-based paint composition in which eco-friendliness, adhesiveness (adhesion), crack resistance and water resistance are all improved.

A window module including a window, a first print layer, an ink layer, and a protective layer covering the ink layer. The protective layer includes a polymer resin polymerized from monomers including a first monomer which is an acrylic monomer substituted with a hydroxy group, a second monomer having an epoxy group, and at least one of a third monomer having a substituted or unsubstituted phenyl group or a fourth monomer which is an acrylic monomer having a substituted or unsubstituted bicyclic alkyl group, and thus, has excellent durability, chemical resistance, and abrasion resistance.

An adhesive set is disclosed. This adhesive set includes a main agent containing a compound having two or more isocyanate groups and a curing agent containing a compound having two or more hydroxyl groups. At least one of the compound having two or more isocyanate groups and the compound having two or more hydroxyl groups has a disulfide bond in the molecule. At least one of the main agent and the curing agent further contains a curing catalyst. At least one of the main agent and the curing agent further contains a photoradical generator.

A flexible gastight material for a landfill site includes a component A and a component B, the component A including: at least one of polypropylene glycol with a molecular weight of 600-4000, polytetrahydrofuran diol with a molecular weight of 1000-3000, polycaprolactone diol with a molecular weight of 1000-3000, and polycarbonate diol with a molecular weight of 1000-3000; and at least one of 2,4′-diphenylmethane diisocyanate, 4,4′-diphenylmethane diisocyanate, toluene diisocyanate, isophorone diisocyanate, and hexamethylene diisocyanate. The flexible gastight material for the landfill site provided in the present application has a micro-closed-cell foam structure. The closed-cell elastic structure of the flexible gastight material may block the volatilization of toxic and harmful odors, and may cut off the diffusion path of the odors by combining with gas treatment systems at the landfill site. The flexible gastight material has excellent water blocking and gas sealing performance.

A flexible gastight material for a landfill site includes a component A and a component B, the component A including: at least one of polypropylene glycol with a molecular weight of 600-4000, polytetrahydrofuran diol with a molecular weight of 1000-3000, polycaprolactone diol with a molecular weight of 1000-3000, and polycarbonate diol with a molecular weight of 1000-3000; and at least one of 2,4′-diphenylmethane diisocyanate, 4,4′-diphenylmethane diisocyanate, toluene diisocyanate, isophorone diisocyanate, and hexamethylene diisocyanate. The flexible gastight material for the landfill site provided in the present application has a micro-closed-cell foam structure. The closed-cell elastic structure of the flexible gastight material may block the volatilization of toxic and harmful odors, and may cut off the diffusion path of the odors by combining with gas treatment systems at the landfill site. The flexible gastight material has excellent water blocking and gas sealing performance.

A thermoplastic polyurethane (TPU) foam product with high flatness, and a preparation method and a use thereof are provided. The TPU foam product is prepared by processing aliphatic thermoplastic polyurethane (ATPU) beads with a melting range of 20° C. to 50° C. and a melting point of 90° C. to 160° C. by a physical gas foaming process to obtain foamed ATPU beads and heating the foamed ATPU beads with a heat source to make the foamed ATPU beads fused. The TPU foam product with high flatness has a density of 0.08 g/cm.sup.3 to 0.8 g/cm.sup.3 and a flatness value of less than 2 mm, and the flatness value is determined by a fixed-length ruler. The TPU foam product not only has high flatness such that diversified designs are allowed for a surface of the product, but also has high resilience.

A thermoplastic polyurethane (TPU) foam product with high flatness, and a preparation method and a use thereof are provided. The TPU foam product is prepared by processing aliphatic thermoplastic polyurethane (ATPU) beads with a melting range of 20° C. to 50° C. and a melting point of 90° C. to 160° C. by a physical gas foaming process to obtain foamed ATPU beads and heating the foamed ATPU beads with a heat source to make the foamed ATPU beads fused. The TPU foam product with high flatness has a density of 0.08 g/cm.sup.3 to 0.8 g/cm.sup.3 and a flatness value of less than 2 mm, and the flatness value is determined by a fixed-length ruler. The TPU foam product not only has high flatness such that diversified designs are allowed for a surface of the product, but also has high resilience.