Patent classifications
C08G18/80
Two-component polyurethane adhesive composition and bonding method thereof
The present disclosure provides a two-component polyurethane adhesive composition and a bonding method thereof. The two-component polyurethane adhesive composition includes A) a polyol component, and B) an isocyanate component. The polyol component includes A1) one or more polyether polyols, and the isocyanate component includes B1) a first isocyanate prepolymer, wherein the first isocyanate prepolymer is polymerized from isocyanate and a non-linear chain extender. The two-component polyurethane adhesive composition of the present disclosure has good mechanical properties, in particular, high G modulus and high elongation. The polyol component in the two-component polyurethane adhesive composition has good phase stability, and good miscibility with the isocyanate component. The two-component polyurethane adhesive composition of the present disclosure can be used for the production and manufacture of mechanical parts such as automobile components.
STORAGE-STABLE POLYISOCYANATE COMPOSITION AND PREPARATION METHOD
The present application provides a storage-stable polyisocyanate composition and a preparation method. The polyisocyanate composition is obtained by selecting one or more diisocyanate from aliphatic diisocyanates and alicyclic diisocyanates, and reacting same with an alcohol compound; the polyisocyanate composition contains an isocyanurate group, a uretdione group, a carbamate group, and an allophanate group; within the polyisocyanate composition, the molar ratio of the carbamate group/(uretdione group+isocyanurate group) is 0.01-0.2, and preferably 0.01-0.1. Compared to existing techniques, the present application has the advantage of a noticeable increase in system viscosity of uretdione polyisocyanate during storage. With the present application, by means of controlling the ratio of the carbamate group/(uretdione group+isocyanurate group) within the system, the increase in viscosity of a product during storage is inhibited, thereby improving the storage stability of the product.
Ultralow Monomer Polyurethanes
The present invention relates to ultralow monomer PU prepolymers containing free NCO groups obtainable from polyols, diisocyanates and NCO-reactive compounds, obtainable by reacting at least one polyol with at least one polyisocyanate, wherein the at least one polyisocyanate is used in molar excess relative to the hydroxyl groups of the at least one polyol to obtain a polyurethane prepolymer containing free isocyanate groups; and adding at least one compound having at least one H-acidic functional group to the polyurethane prepolymer containing free isocyanate groups in an amount such that the molar ratio of the free isocyanate groups to H-acidic functional groups (NCO:XH ratio) is 2 to 15, preferably 2.5 to 10, more preferably 3 to 8. Also encompassed are methods for its production, laminating adhesives containing said prepolymer, methods of bonding substrates and the use of the described adhesives for laminating two or more films.
BLOCKED POLYISOCYANATE COMPOSITION, HEAT-CURABLE RESIN COMPOSITION, CURED PRODUCT, AND PRODUCTION METHOD THEREFOR
The present invention provides a blocked polyisocyanate composition comprising a blocked polyisocyanate compound and an amidate compound represented by the following Formula (2):
##STR00001##
wherein B, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are as defined in the specification.
Hydroxymethyl-carboxamido-substituted silane and its use for curable, silane-terminated polymers
Specific hydroxysilanes of formula (I), a method for the production thereof, the use thereof as a constituent of moisture-curing compositions, and silane-functional compounds produced therefrom, in particular silane-functional polymers and isocyanatosilanes. The hydrosilanes can be produced in a simple process with a high degree of purity and are storage-stable after production. Production from the reaction of lactides with aminosilanes is particularly advantageous. Hydroxysilane of formula (I), where n is 1 or 2.
HIGH REMOVAL RATE CHEMICAL MECHANICAL POLISHING PADS AND METHODS OF MAKING
A chemical mechanical polishing pad for polishing a semiconductor substrate is provided containing a polishing layer that comprises a polyurethane reaction product of a reaction mixture comprising (i) one or more diisocyanate, polyisocyanate or polyisocyanate prepolymer, (ii) from 40 to 85 wt. % based on the total weight of (i) and (ii) of one or more blocked diisocyanate, polyisocyanate or polyisocyanate prepolymer which contains a blocking agent and has a deblocking temperature of from 80 to 160° C., and (iii) one or more aromatic diamine curative. The reaction mixture has a gel time at 80° C. and a pressure of 101 kPa of from 2 to 15 minutes; the polyurethane reaction product has a residual blocking agent content of 2 wt. % or less; and the polishing layer exhibits a density of from 0.6 to 1.2 g/cm.sup.3.
Polyurea that is particularly useful as an adhesion primer for adhering metal to rubber
A polyurea comprises at least urea base units of formula —NH—CO—NH— and additional units. The additional units comprise at least, on the one hand, a secondary alcohol functional group and, on the other hand, an ether, thioether or secondary amine functional group in the alpha position with respect to the secondary alcohol functional group. Such a polymer can be used as an adhesion primer for the adhesive bonding of a substrate, for example, glass or metal, to an unsaturated rubber or as corrosion-resistant protective coating for a metal substrate. Metal reinforcers, such as thread, cord, film or plate, coated can also be coated with such a polymer.
NONAQUEOUS COATING MATERIAL COMPOSITIONS, COATINGS PRODUCED THEREFROM AND HAVING IMPROVED ADHESION AND SCRATCH RESISTANCE AND ALSO USE THEREOF
A nonaqueous coating material composition and a coating produced from the coating material composition are provided. The coating material composition contains at least one polyhydroxyl group-containing component, at least one polyisocyanate group-containing component, at least one catalyst, and at least one urethane additive (PF) which has specific groups. The urethane additive (PF) is prepared by reacting 0.5 to 20 mol % of the isocyanate groups originally present in a polyisocyanate (PI) with a component (Ia) and 10 to 99.5 mol % of the isocyanate groups originally present in the polyisocyanate (PI) with a component (IIa). The component (Ia) contains at least one perfluoroalkyl group of a specific formula and one group reactive toward the isocyanate groups. The component (IIa) contains at least one silane group of a specific formula and one group reactive toward the isocyanate groups.
COATING MATERIAL COMPOSITIONS AND COATINGS PRODUCED THEREFROM AND ALSO USE THEREOF
The present invention relates to nonaqueous coating material compositions comprising (A) at least one polyhydroxyl group-containing component (A), (B1) at least one isocyanate and silane group-containing component (B1), and (D) at least one catalyst (D) for the crosslinking of silane groups,
which composition comprises (B2) at least one isocyanate group-containing component (B2) which is different from component (B1) and which additionally has at least one perfluoroalkyl group of the formula (I)
CR.sup.1.sub.3—(CR.sup.2.sub.2).sub.f— (I) where R.sup.1 and R.sup.2 independently of one another are H, F and/or CF.sub.3, but R.sup.1 and R.sup.2 may not both be H, and f is 1 to 20, preferably 3 to 11, more preferably 5 to 7.
A further subject of the present invention are the coatings produced from these coating material compositions, and also their use.
COMPOSITION FOR MAGNETIC RECORDING MEDIUM AND MAGNETIC RECORDING MEDIUM
An aspect of the present invention relates to a composition, which is a composition for a magnetic recording medium and comprises an isocyanate compound in the form of an adduct of a polyhydroxyl compound having one or more aromatic carbon rings and three or more hydroxyl groups per molecule with a polyisocyanate having two or more isocyanate groups per molecule.