Patent classifications
C08G61/08
CYCLOOLEFIN POLYMER, METHOD FOR PRODUCING SAME, AND OPTICAL ELEMENT
Provided are a cycloolefin polymer simultaneously having a high refractive index, a low Abbe number, and low birefringence and also a method of producing this cycloolefin polymer and an optical element in which this cycloolefin polymer is used. The cycloolefin polymer is a polymer, or hydrogenated product thereof, said polymer comprising a structural unit derived from a naphthyl group-containing alicyclic compound (A) represented by following formula (1), in a specific proportion. In formula (1), one of R.sub.2a to R.sub.5a is a naphthyl group and remaining groups among R.sub.2a to R.sub.5a and R.sub.1a are as defined in the specification.
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CYCLOOLEFIN POLYMER, METHOD FOR PRODUCING SAME, AND OPTICAL ELEMENT
Provided are a cycloolefin polymer simultaneously having a high refractive index, a low Abbe number, and low birefringence and also a method of producing this cycloolefin polymer and an optical element in which this cycloolefin polymer is used. The cycloolefin polymer is a polymer, or hydrogenated product thereof, said polymer comprising a structural unit derived from a naphthyl group-containing alicyclic compound (A) represented by following formula (1), in a specific proportion. In formula (1), one of R.sub.2a to R.sub.5a is a naphthyl group and remaining groups among R.sub.2a to R.sub.5a and R.sub.1a are as defined in the specification.
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Polycycloolefin polymer and inorganic nanoparticle compositions as optical materials
Embodiments in accordance with the present invention encompass compositions encompassing a latent catalyst and a thermal or photoactivator along with one or more monomers which undergo ring open metathesis polymerization (ROMP) when said composition is heated to a temperature from 50° C. to 100° C. or higher to form a substantially transparent film. Alternatively the compositions of this invention also undergo polymerization when subjected to suitable radiation. The monomers employed therein have a range of refractive index from 1.4 to 1.6 and thus these compositions can be tailored to form transparent films of varied refractive indices. The compositions of this invention further comprises inorganic nanoparticles which form transparent films and further increases the refractive indices of the compositions. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as coatings, encapsulants, fillers, leveling agents, among others.
Polycycloolefin polymer and inorganic nanoparticle compositions as optical materials
Embodiments in accordance with the present invention encompass compositions encompassing a latent catalyst and a thermal or photoactivator along with one or more monomers which undergo ring open metathesis polymerization (ROMP) when said composition is heated to a temperature from 50° C. to 100° C. or higher to form a substantially transparent film. Alternatively the compositions of this invention also undergo polymerization when subjected to suitable radiation. The monomers employed therein have a range of refractive index from 1.4 to 1.6 and thus these compositions can be tailored to form transparent films of varied refractive indices. The compositions of this invention further comprises inorganic nanoparticles which form transparent films and further increases the refractive indices of the compositions. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as coatings, encapsulants, fillers, leveling agents, among others.
Co-injection molded multilayer structure and method for producing same
There is provided a co-injection molded multilayer structure comprising a barrier layer and outer layers laminated to contact with the barrier layer on its both sides, wherein the barrier layer is made of a resin composition (X) comprising an ethylene-vinyl alcohol copolymer (A) and an alkali metal salt (B) of a higher fatty acid, having a melting point of 250° C. or lower; the ethylene-vinyl alcohol copolymer (A) has an ethylene unit content of 20 to 60 mol % and a saponification degree of 90% or more, and a content of the alkali metal salt (B) in the barrier layer is 50 to 1500 ppm in terms of metal atoms; and the outer layers are made of a resin composition (Y) comprising an unmodified high-density polyethylene (F) and a maleic anhydride-modified polyethylene (G), and a maleic anhydride modification rate relative to the whole resin composition (Y) is 0.005 to 0.1 wt %. This co-injection molded multilayer structure has excellent adhesiveness, so that its oxygen barrier performance can be maintained even after being subjected to an impact due to falling or the like.
THERMOPLASTIC COPOLYMERS WITH A HIGH SULPHUR CONTENT AND PROCESS FOR THE PREPARATION THEREOF
A thermoplastic copolymer with a high sulphur content, having sulphur in an amount greater than or equal to 40% by weight, in relation to the total weight of the thermoplastic copolymer with a high sulphur content and at least one monomer having general formula (I):
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wherein: R.sub.1 and R.sub.2, equal or different from each other, represent a hydrogen atom; or R.sub.1 and R.sub.2, may optionally be bound together so as to form, together with the other atoms to which they are bound, a cycloalkene containing from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with C.sub.1-C.sub.20 alkyl groups;
the monomer having general formula (I) being present in an amount less than or equal to 60% by weight;
the thermoplastic copolymer with high sulphur content having a complex dynamic viscosity (η*), at 160° C., comprised between 1×10.sup.4 Pa.s and 8×10.sup.6 Pa.s.
THERMOPLASTIC COPOLYMERS WITH A HIGH SULPHUR CONTENT AND PROCESS FOR THE PREPARATION THEREOF
A thermoplastic copolymer with a high sulphur content, having sulphur in an amount greater than or equal to 40% by weight, in relation to the total weight of the thermoplastic copolymer with a high sulphur content and at least one monomer having general formula (I):
##STR00001##
wherein: R.sub.1 and R.sub.2, equal or different from each other, represent a hydrogen atom; or R.sub.1 and R.sub.2, may optionally be bound together so as to form, together with the other atoms to which they are bound, a cycloalkene containing from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with C.sub.1-C.sub.20 alkyl groups;
the monomer having general formula (I) being present in an amount less than or equal to 60% by weight;
the thermoplastic copolymer with high sulphur content having a complex dynamic viscosity (η*), at 160° C., comprised between 1×10.sup.4 Pa.s and 8×10.sup.6 Pa.s.
ELECTRODE MATERIAL
Provided is an electrode material which is suitable for use as a material for forming electrodes for use in lithium ion secondary batteries, etc. and which makes it possible to heighten the rate characteristics of batteries. The electrode material is characterized by comprising a polymer having, in a side chain, a fluoflavin skeleton such as that shown by the formula and an inorganic active material, the polymer being contained in an amount of 1 mass % or less with respect to the solid components.
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MOLECULAR SIEVES MEDIATED UNSATURATED HYDROCARBON SEPARATION AND RELATED COMPOSITIONS, MATERIALS, METHODS AND SYSTEMS
Described herein are compositions having an eight-membered monocyclic unsaturated hydrocarbon, methods and system to separate the eight-membered monocyclic unsaturated hydrocarbon at from a hydrocarbon mixture including additional nonlinear unsaturated C.sub.8H.sub.2m hydrocarbons with 4≤m≤8, by contacting the hydrocarbon mixture with a 10-ring pore molecular sieve having a sieving channel with a 10-ring sieving aperture with a minimum crystallographic free diameter greater than 3 Å and a ratio of the maximum crystallographic free diameter to the minimum crystallographic free diameter between 1 and 2, the molecular sieve having a T1/T2 ratio ≥20:1 wherein T1 is an element independently selected from Si and Ge, and T2 is an element independently selected from Al, B and Ga, the 10-ring pore molecular sieve further having a counterion selected from NH.sub.4.sup.+, Li.sup.+, Na.sup.+, K.sup.+ and Ca.sup.+.
Compositions Comprising Cyclic Olefins and Thermally Conductive Filler
A composition is described comprising a cyclic olefin; a ring opening metathesis polymerization catalyst; and at least 40 wt. % of thermally conductive particles. The thermally conductive particles are selected such that the composition after curing has a thermal conductivity of at least 1W/M*K. In one embodiment, the thermally conductive particle comprises a combination of smaller and larger thermally conductive particles. In another embodiment, the thermally conductive particles comprise boron nitride particles. Also described are (e.g. structural) adhesives, methods of bonding and articles.