The present invention discloses an organic polymer having an asymmetric structure, a preparation method thereof and a use as a photoelectric material thereof. The organic polymer with an asymmetric structure is obtained by polymerization after performing Stille coupling reaction between an electron-donating unit D and an electron-withdrawing unit A in the presence of a solvent and a catalyst. The compound of the present application has good heat stability, controllable absorption level, and is suitable for the preparation of hole transport materials of high-performance perovskite solar cells with high efficiency, flexibility, good stability and a large area as well as donor materials of organic solar cells.

The present invention relates to the field of hydrogen energy, and more particularly to an anion-conducting polyelectrolyte comprising an amide group, a preparation method and application thereof. The method includes: polymerizing aromatic hydrocarbons and ketone comprising amide group by superacid catalysis, forming a membrane by a casting method, performing the membrane prepared under alkaline conditions to obtain the anion-conducting polyelectrolytes comprising amide group. The anion-conducting polyelectrolytes obtained have good solubility and excellent stability. It is a kind of high molecular polymer with excellent alkali stability with an amide structure on the backbone. After alkaline treatment, the polymer not only has high hydroxide conductivity, good mechanical properties, and thermal stability but also has excellent alkali stability and excellent performance of water electrolysis.

The present invention relates to a polymer comprising repeating units consisting of a substituted pyrrole ring. In particular, the repeating units consist of substituted pyrrole containing polar groups capable of interacting with carbon allotropes such as carbon nanotubes, graphene or nanographites, in order to improve the chemical-physical characteristics of the allotropes mainly by increasing their dispersibility and stability in liquid media and in polymer matrices. The invention also relates to products of addition of these polymers with carbon allotropes in order to obtain easily dispersible macromolecules.

A high selectivity and high CO.sub.2 plasticization resistant polymer comprises a plurality of repeating units of formula (I) for gas separation applications. The polymer may be synthesized from a superacid catalyzed poly(hydroalkylation) reaction.

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Membranes made from the polymer and gas separation processes using the membranes made from the polymer are also described.

A composition for forming an organic film contains a polymer having a partial structure shown by the following general formula (1) as a repeating unit, and an organic solvent. Each of AR1 and AR2 represents a benzene ring or naphthalene ring which optionally have a substituent; W.sub.1 represents a particular partial structure having a triple bond, and the polymer optionally contains two or more kinds of W.sub.1; and W.sub.2 represents a divalent organic group having 6 to 80 carbon atoms and at least one aromatic ring. This invention provides: a polymer curable even under film formation conditions in an inert gas and capable of forming an organic film which has not only excellent heat resistance and properties of filling and planarizing a pattern formed in a substrate, but also favorable film formability onto a substrate with less sublimation product; and a composition for forming an organic film, containing the polymer. ##STR00001##

An organic film forming composition, containing: a material shown by formula (I) and/or (II); and an organic solvent, where R.sub.1 and R.sub.4 each represent a hydrogen atom, an allyl or propargyl group, R.sub.2 and R.sub.5 each represent a substituent, R.sub.3 and R.sub.6 represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkynyl group having 2 to 4 carbon atoms, or an alkenyl group having 2 to 4 carbon atoms. “m” and “i” represent 0 or 1, “k” and “q” represent an integer of 0 to 2, “n” represent 1 or 2, “h”, and “j” represent an integer of 0 to 2 and satisfy the relationship 1≤h+j≤4, and “1” and “r” represent 0 or 1. W represents a single bond or divalent group shown by formulae (3). Each V independently represents a hydrogen atom or linking moiety.

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The present disclosure relates to a carbazole-based anion exchange material, a preparation method therefor and use thereof, and more particularly, to an anion exchange material used in membranes for water electrolysis, redox flow batteries, fuel cells, carbon dioxide reduction, electrochemical ammonia production and decomposition, electrodialysis (ED), reverse electrodialysis (RED) or capacitive deionization (CDI), a separator comprising the same, a preparation method therefor and use thereof. According to the present disclosure, it is possible to prepare a separation membrane with improved mechanical and chemical stability and durability by remarkably improving the molecular weight together with solubility in solvent by providing the anion exchange material in which all bonds between monomers in the main chain are C—C bonds based on the carbazole-based material with high stability.

A hard mask-forming composition which forms a hard mask used in lithography, including: a resin containing an aromatic ring and a polar group; and a compound containing at least one of an oxazine ring fused to an aromatic ring, and a fluorene ring.

A terminal functional side chain-substituted diketopyrrolopyrrole (DPP)-based terpolymer and a preparation method and use thereof is described herein. The terpolymer has the following structural formula:

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where R.sub.1 is a terminal siloxy-substituted swallow-tailed chain with 22 to 52 carbon atoms in total, and t.sub.1 and t.sub.2 each are an integer of 1 to 18; R.sub.2 is a semifluoroalkyl-substituted swallow-tailed chain with 12 to 60 carbon atoms in total and 10 to 46 fluorine atoms in total, t.sub.3 and t.sub.4 each are an integer of 1 to 16, and t.sub.5 and t.sub.6 each are an integer of 1 to 10; and Ar is any one selected from the group consisting of aryl, heteroaryl, substituent-containing aryl, and substituent-containing heteroaryl, and m and n each are an integer of 5 to 100.

Water solvated polymeric dyes and polymeric tandem dyes are provided. The polymeric dyes include a water solvated light harvesting multichromophore having a conjugated segment of aryl or heteroaryl co-monomers linked via covalent bonds, vinylene groups or ethynylene groups. The polymeric tandem dyes further include a signaling chromophore covalently linked to the multichromophore in energy-receiving proximity therewith. Also provided are labeled specific binding members that include the subject polymeric dyes. Methods of evaluating a sample for the presence of a target analyte and methods of labeling a target molecule in which the subject polymeric dyes find use are also provided. Systems and kits for practicing the subject methods are also provided.