Disclosed are an organic thin film including a semiconducting polymer including a ligand that is metal-coordination bondable or is metal-coordination bonded and an elastomer including a ligand that is metal-coordination bondable or is metal-coordination bonded, wherein the semiconducting polymer and the elastomer are configured to be dynamic intermolecular bonded by a metal-coordination bond, an organic sensor, and an electronic device.

The present invention relates to a novel polymer and an organic electronic device using same. In the polymer according to the present invention, a cyclic electron-donor, including thiophene, selenophene, or a combination thereof, is introduced into a central skeleton having an A-D-A structure including an electron-donor and electron-acceptor unit. Thus, the polymer has not only excellent chemical and thermal stability, but also good crystallinity. Moreover, intermolecular stacking is possible, and thus charge mobility can be maximized.

This hole collection layer composition for an organic photoelectric conversion elements comprises: a charge-transporting substance formed of a polyaniline derivative represented by formula (1); fluorochemical surfactant; metal oxide nanoparticles; and a solvent. The hole collection layer composition provides a thin film having excellent adhesiveness to an active layer of an organic photoelectric conversion element. ##STR00001## {R.sup.1-R.sup.6 are each independently a hydrogen atom, a halogen atom, a nitro group, a cyano group, a sulfonic acid group, a C.sub.1-C.sub.20 alkoxy group, a C.sub.1-C.sub.20 thioalkoxy group, a C.sub.1-C.sub.20 alkyl group, etc. Meanwhile, one of R.sup.1-R.sup.4 is a sulfonic acid group and at least one of the remaining R.sup.1-R.sup.4 is a C.sub.1-C.sub.20 alkoxy group, a C.sub.1-C.sub.20 thioalkoxy group, a C.sub.1-C.sub.20 alkyl group, etc., and m and n are numbers that satisfy 0≤m≤1, 0≤n≤1, and m+n=1.}

A light-emitting composition comprising: a light-emitting group and a polymer comprising: a repeat unit of formula Ar.sup.1 wherein Ar.sup.1 is an arylene repeat unit which is unsubstituted or substituted with one or more substituents; and a repeat unit of formula (I): (I) wherein Ar.sup.2 and Ar.sup.3 each independently represent a C.sub.6-20 arylene group or a 5-20 membered heteroarylene group which is unsubstituted or substituted with one or more substituents and CB represents a conjugation-breaking group which does not provide a conjugation path between Ar.sup.2 and Ar.sup.3; wherein the polymer has a solubility in water or a C.sub.1-8 alcohol at 20° C. of at least 0.1 mg/ml. The composition may be a light-emitting polymer in which the polymer contains the light-emitting group. The light-emitting composition may be part of a particle containing the polymer and a matrix material, e.g. silica. The light-emitting composition may be used in an assay for detection of a target analyte.

A polymer, a quantum dot composition, and a light-emitting device employing the same are provided. The polymer includes a first repeat unit that has a structure represented by Formula (I):

##STR00001##

wherein the definitions of R.sup.1, R.sup.2, A.sup.1, A.sup.2, A.sup.3, and Z.sup.1 and n are as defined in the specification.

A polymer comprising

##STR00001## wherein m+n=1.

The present disclosure provides a non-fullerene acceptor polymer, which includes a structure represented by formula (I). Formula (I) is defined as in the specification. The non-fullerene acceptor polymer has an electron donating unit and an electron attracting end group. The non-fullerene acceptor polymer uses phenyl or its derivatives as the linker to form the polymer.

An organic semiconductor device is revealed. The organic semiconductor device includes a first electrode, an electron transport layer, an active layer, a hole transport layer, and a second electrode. The active layer includes an electron donor and at least one electron acceptor. The energy barrier between HOMO level of the electron donor and the energy level of PEDOT:PSS or derivatives in the electron transport layer is less than 0.4 eV. The use of the organic semiconductor device and a formulation of materials for the active layer are also disclosed.

Polymer embodiments comprising nanohoop-containing polymer backbones are described, along with methods of making and using the same. The polymer embodiments exhibit unique radial and linear conjugation and can be used in a variety of devices, such as electronic and/or optoelectronic devices.

The present invention discloses an organic polymer having an asymmetric structure, a preparation method thereof and a use as a photoelectric material thereof. The organic polymer with an asymmetric structure is obtained by polymerization after performing Stille coupling reaction between an electron-donating unit D and an electron-withdrawing unit A in the presence of a solvent and a catalyst. The compound of the present application has good heat stability, controllable absorption level, and is suitable for the preparation of hole transport materials of high-performance perovskite solar cells with high efficiency, flexibility, good stability and a large area as well as donor materials of organic solar cells.