C08G63/18

DYEABLE POLYOLEFIN FIBER AND FIBROUS STRUCTURE COMPRISING SAME
20190071797 · 2019-03-07 ·

A dyeable polyolefin fiber includes a sea-island structure in which a polyolefin (A) is the sea component and a copolyester (B) obtained by copolymerizing cyclohexanedicarboxylic acid is the island component, the polyolefin fiber characterized in that the dispersion diameter of the island component in a lateral cross section of the fiber is 30 to 1000 nm. The dyeable polyolefin fiber is bright, deep coloring is imparted to the lightweight polyolefin fiber, oxidative decomposition during tumbler drying and yellowing during long-term storage are minimized, and the polyolefin fiber can be suitably used as a fibrous structure.

Resin compositions for thermosetting powder coating compositions

The invention relates to a resin composition comprising at least an organophosphorous compound and a branched amorphous carboxylic acid functional polyester, said polyester having a T.sub.g of at least 40 C., said polyester comprising at least 1 to 45% mol of 2,2-dimethyl-1,3-propanediol; a C.sub.3 to C.sub.5 aliphatic diol AD1 not including 2,2-dimethyl-1,3-propanediol; a C.sub.6 to C.sub.50 aliphatic or cycloaliphatic diol AD2; 0.1 to 10% mol of an at least trifunctional monomer; 1 to 55% mol of terephthalic acid, wherein the % mol is based on the polyester. The powder coatings of the present invention derived upon curing at low temperature of the thermosetting powder coating compositions of the invention that were storage stable and comprised said resin composition and a crosslinker having functional groups that are reactive with the carboxylic acid groups of the polyester, have limited or no blooming, good smoothness sufficient reverse impact resistance and preferably have also good degassing limit.

Resin compositions for thermosetting powder coating compositions

The invention relates to a resin composition comprising at least an organophosphorous compound and a branched amorphous carboxylic acid functional polyester, said polyester having a T.sub.g of at least 40 C., said polyester comprising at least 1 to 45% mol of 2,2-dimethyl-1,3-propanediol; a C.sub.3 to C.sub.5 aliphatic diol AD1 not including 2,2-dimethyl-1,3-propanediol; a C.sub.6 to C.sub.50 aliphatic or cycloaliphatic diol AD2; 0.1 to 10% mol of an at least trifunctional monomer; 1 to 55% mol of terephthalic acid, wherein the % mol is based on the polyester. The powder coatings of the present invention derived upon curing at low temperature of the thermosetting powder coating compositions of the invention that were storage stable and comprised said resin composition and a crosslinker having functional groups that are reactive with the carboxylic acid groups of the polyester, have limited or no blooming, good smoothness sufficient reverse impact resistance and preferably have also good degassing limit.

POLYVINYL CHLORIDE AND COPOLYESTER COMPOSITIONS AND ARTICLES MADE USING THESE COMPOSITIONS
20180371233 · 2018-12-27 · ·

This disclosure pertains to novel polyvinyl chloride compositions containing polyvinyl chloride resins and copolyesters. More particularly, the present disclosure pertains to polyvinyl chloride compositions including high glass transition temperature (Tg) copolyesters to increase the Tg and the heat distortion temperature under load (HDTUL) of the polyvinyl chloride compositions.

Functionalized polyester polymers and film articles

Polyester polymers are described comprising polymerized units comprising a hydroxy functional aromatic group wherein the hydroxy group has been functionalized with an adhesion promoting group. In some embodiments, the polyester polymer comprises polymerized units have the general structure (A) wherein L.sub.1 and L.sub.2 are independently divalent linking groups comprising an ester group; and R.sub.A is an adhesion promoting group bonded to the oxygen atom by means of an ionic or covalent bond. In other embodiments, film articles, laminates are described and methods of making functionalized polyester polymers are described. ##STR00001##

Functionalized polyester polymers and film articles

Polyester polymers are described comprising polymerized units comprising a hydroxy functional aromatic group wherein the hydroxy group has been functionalized with an adhesion promoting group. In some embodiments, the polyester polymer comprises polymerized units have the general structure (A) wherein L.sub.1 and L.sub.2 are independently divalent linking groups comprising an ester group; and R.sub.A is an adhesion promoting group bonded to the oxygen atom by means of an ionic or covalent bond. In other embodiments, film articles, laminates are described and methods of making functionalized polyester polymers are described. ##STR00001##

Biodegradable copolyesters
10106642 · 2018-10-23 · ·

The present invention relates to biodegradable copolyesters with molecular weight Mn from 10 000 to 100 000 measured by GPC, obtainable via reaction of i) from 51 to 84% by weight, based on the copolyester, of a branched polyester middle block produced from aliphatic or aliphatic and aromatic dicarboxylic acids and from aliphatic dihydroxy compounds with molecular weight Mn from 5000 to 25 000 measured by .sup.1H NMR with from 15.9 to 48.9% by weight, based on the copolyester, of a lactide in the presence of a catalyst, and then the resultant polyester triblock with molecular weight Mn measured by .sup.1H NMR from 5800 to 49 500 with ii) from 0.1 to 3% by weight, based on the copolyester, of a diisocyanate. The present invention further relates to a process for the production of, and to the use of, the abovementioned biodegradable copolyesters.

Biodegradable copolyesters
10106642 · 2018-10-23 · ·

The present invention relates to biodegradable copolyesters with molecular weight Mn from 10 000 to 100 000 measured by GPC, obtainable via reaction of i) from 51 to 84% by weight, based on the copolyester, of a branched polyester middle block produced from aliphatic or aliphatic and aromatic dicarboxylic acids and from aliphatic dihydroxy compounds with molecular weight Mn from 5000 to 25 000 measured by .sup.1H NMR with from 15.9 to 48.9% by weight, based on the copolyester, of a lactide in the presence of a catalyst, and then the resultant polyester triblock with molecular weight Mn measured by .sup.1H NMR from 5800 to 49 500 with ii) from 0.1 to 3% by weight, based on the copolyester, of a diisocyanate. The present invention further relates to a process for the production of, and to the use of, the abovementioned biodegradable copolyesters.

PLASTICIZER COMPOSITION, RESIN COMPOSITION AND METHODS OF PREPARING THE SAME

The present invention relates to a plasticizer composition, a resin composition and methods of preparing the same, and provides a plasticizer which is environmentally friendly so as to be suitable for use, exhibits excellent transparency and adhesiveness, and can be improved in basic properties such as tensile strength, an elongation rate, hardness and the like when used as a plasticizer for a resin composition, and a resin composition including the same.

Polyester composition, electronic device, and method of forming film

Disclosed is a method for manufacturing a film. 50 wt % to 85 wt % of a first polyester and 50 wt % to 15 wt % of a second polyester are dried and mixed to form a mixture. The first polyester is polyethylene terephthalate (PET), polyethylene naphthalate (PEN), or combinations thereof. The second polyester is copolymerized of 1 part by mole of terephthalic acid, m parts by mole of 1,4-cyclohexanedimethanol (1,4-CHDM), n parts by mole of 1,3-cyclohexanedimethanol (1,3-CHDM), and o parts by mole of ethylene glycol (EG). m+n+o=1, 0o0.4, 0.6m+n1, and 0.06n/m1.31. The mixture is melted and blended to form a polyester composition, which is extruded to form a sheet. The sheet is then biaxially stretched to obtain a film. The biaxially stretched film is then treated with a thermal setting.