Patent classifications
C08G63/54
POLYOL COMPOSITION, ADHESIVE COATING MATERIAL, CURED OBJECT OBTAINED THEREFROM, ADHESIVE SHEET, AND SOLAR CELL MODULE
The invention provides an adhesive coating material which realizes excellent adhesive strength and moist-heat resistance at the time of bonding a solar cell sealing material and a base sheet, a polyol composition for the coating material, a cured object of the adhesive coating material, an adhesive sheet obtained by being coated with adhesive coating material, and a solar cell module using the sheet. As a polyol component of the adhesive coating material which forms an adhesive layer b in a back sheet E of the solar cell module illustrated in Figure, a hydroxyl group-containing (meth)acrylic resin (I) and unsaturated double bond-containing polyester polyol (II) are used as essential components.
Polyester resin for toner, method for producing same and toner
Disclosed is a toner which is excellent in low-temperature fixability, high-temperature offset resistance, storage stability and durability, while having a wide range of fixing temperature. Also disclosed is a polyester resin used for such a toner. The polyester resin is one of the following polyester resin (A)-(E) for toners. (A) A polyester resin for toners having an Mp as determined by GPC of not less than 12,000 and having an unsaturated double bond (B) A polyester resin for toners obtained by crosslinking the polyester resin (A) (C) A polyester resin for toners containing the polyester resin (A) and another polyester resin having an Mp as determined by GPC of less than 12,000 (D) A polyester resin for toners obtained by crosslinking the polyester resin (C) (E) A polyester resin for toners containing a THF soluble fraction and a THF insoluble fraction wherein the Mw/Mn of the THF soluble fraction is not less than 6 and the total of the acid value and the hydroxyl value of the THF insoluble fraction is not more than 40 mgKOH/g.
Non-random isobutylene copolymers
Non-random isobutylene copolymer includes repeat units derived from isobutylene and one or more comonomers selected from isoprene, butadiene, cyclopentadiene, dicyclopentadiene, limonene, substituted styrenes, and C4 to C10 dienes other than isoprene, butadiene, limonene, cyclopentadiene, or dicyclopentadiene, wherein the molar ratio of isobutylene derived repeat units to the comonomer derived repeat units is from 75:1 to 1.5:1. The non-random copolymers have a molecular weight, Mn, of from 200 to 20,000 Daltons and typically have a high double bond content and a high vinylidene double bond content when diene monomers are utilized.
A Polyester Polyol and Polyurethane Polymers Made Therefrom
Described herein is a polyester polyol, which is derived from a first reaction product of (a) a Component A, wherein the Component A is a phthalic acid, a phthalic anhydride or mixtures thereof, (b) a Component B, wherein the Component B is a dimer fatty acid, a dimer fatty acid diol or mixtures thereof, and (c) a Component C, wherein the Component C is an aliphatic diol, an aromatic diol, or mixtures thereof, wherein Component C comprises 2 to 10 carbon atoms and optionally catenated heteroatoms selected from O, S, and N. Also disclosed herein are polyurethane polymers and pressure sensitive adhesives made from the polyurethane polymers or the polyester polyols.
A Polyester Polyol and Polyurethane Polymers Made Therefrom
Described herein is a polyester polyol, which is derived from a first reaction product of (a) a Component A, wherein the Component A is a phthalic acid, a phthalic anhydride or mixtures thereof, (b) a Component B, wherein the Component B is a dimer fatty acid, a dimer fatty acid diol or mixtures thereof, and (c) a Component C, wherein the Component C is an aliphatic diol, an aromatic diol, or mixtures thereof, wherein Component C comprises 2 to 10 carbon atoms and optionally catenated heteroatoms selected from O, S, and N. Also disclosed herein are polyurethane polymers and pressure sensitive adhesives made from the polyurethane polymers or the polyester polyols.
REACTIVE POLYESTER RESIN BASED ON A HYDROXYLATED AND/OR EPOXIDIZED FATTY ACID TRIGLYCERIDE POLYOL FOR COATINGS WITH HIGH SOLIDS CONTENT
The invention relates to a hydroxylated and/or carboxylated polyester resin, which comprises, in its structure, ester units formed from a polyol component a) comprising at least one polyol al) chosen from hydroxylated and/or epoxidized fatty acid triglycerides of general formula (I): R-CO2-(H)C-(CH2-CO2-R)2 (I) with R being the residue radical without a carboxyl group of a hydroxylated and/or epoxidized fatty acid RCO2H with R comprising from 13 to 21 carbon atoms and at least one hydroxyl and/or epoxy group. The invention also relates to a crosslinkable coating composition in an organic solvent medium comprising said resin, just like the coating which results from this use.
REACTIVE POLYESTER RESIN BASED ON A HYDROXYLATED AND/OR EPOXIDIZED FATTY ACID TRIGLYCERIDE POLYOL FOR COATINGS WITH HIGH SOLIDS CONTENT
The invention relates to a hydroxylated and/or carboxylated polyester resin, which comprises, in its structure, ester units formed from a polyol component a) comprising at least one polyol al) chosen from hydroxylated and/or epoxidized fatty acid triglycerides of general formula (I): R-CO2-(H)C-(CH2-CO2-R)2 (I) with R being the residue radical without a carboxyl group of a hydroxylated and/or epoxidized fatty acid RCO2H with R comprising from 13 to 21 carbon atoms and at least one hydroxyl and/or epoxy group. The invention also relates to a crosslinkable coating composition in an organic solvent medium comprising said resin, just like the coating which results from this use.
Isobutylene copolymers, method for making isobutylene copolymers and isobutylene copolymer products
Isobutylene copolymer includes repeat units derived from isobutylene and one or more comonomers selected from isoprene, butadiene, cyclopentadiene, dicyclopentadiene, limonene, substituted styrenes, and C4 to C10 dienes other than isoprene, butadiene, limonene, cyclopentadiene, or dicyclopentadiene, wherein the molar ratio of isobutylene derived repeat units to the comonomer derived repeat units is from 75:1 to 1.5:1. The copolymers have a molecular weight, Mn, of from 200 to 20,000 Daltons and typically have a high double bond content and a high vinylidene double bond content when diene monomers are utilized.
Heat-curable powder coating composition and preparation method thereof
The invention relates to the field of powder coatings, and specifically discloses a heat-curable powder coating composition and a preparation method thereof. The powder coating composition comprises: i) component A comprising at least one amorphous solid polyester resin compound having a Michael donor reactive group; ii) component B comprising at least one amorphous ethylenically unsaturated solid polyester resin with a Michael acceptor reactive group; iii) component C comprising at least one (semi) crystalline solid reactive diluent; iv) component D comprising at least one epoxy group-containing solid substance; v) component E comprising at least one basic catalyst. The present invention also discloses a preparation method of the above heat-curable powder coating composition. By adopting the invention, ultra-low temperature curing can be realized. The curing temperature is as low as 90-110° C., and the curing time is short.
URETHANE RESIN
There is provided a urethane resin that is excellent in adhesive strength, and maintains high adhesive strength even after exposure to high temperature and humidity. A urethane resin obtained by reacting a glycol-modified aromatic hydrocarbon-formaldehyde resin (A) modified with a glycol with a polyisocyanate (B) having two or more free isocyanate groups in a molecule.