Patent classifications
C08G63/86
Method of Producing Copolyester Material with Peptide and Copolyester Material with Peptide Thereof
A method of producing copolyester material with peptide and is disclosed. The method includes: putting ethylene glycol, collagen peptide and Benzenedicarboxylic acid into a container, and mixing them to form a mixture; heating the mixture for executing an esterification reaction, to product esters and water; heating the esters to a first temperature, and stirring the esters via a mixer; in a specific period, decreasing the pressure in the container to a first pressure for executing a polycondensation reaction; decreasing the pressure in the container to a second pressure, and stirring the esters via the mixer, to produce a copolyester material with peptide.
POLYCYCLOHEXYLENEDIMETHYLENE TEREPHTHALATE RESIN HAVING ENHANCED CRYSTALLIZATION SPEED AND METHOD FOR PREPARING SAME
The present invention relates to a polycyclohexylenedimethylene terephthalate (PCT) resin having enhanced crystallization speed and a method for preparing same. A PCT resin, according to an embodiment of the present invention, comprises: a reactant of (A) a dicarboxylic acid compound or a dicarboxylic acid ester compound and (B) a diol compound total of which 90 mol % or more is cyclohexanedimethanol; and 10-1000 ppm of antimony (Sb) atoms on the basis of the total weight of the resin, wherein the differential between the melting point (Tm) and a reduced crystallization temperature (Tmc) is 45° C. or lower. A PCT resin, according to the present invention, has high crystallization speed and thus enables fast production of various molded products. In particular, the PCT resin has high crystallization temperature and high heat resistance and thus enables fast production of a high-quality heat-resistant molded product by means of injection molding.
Heat resistant polyethylene terephthalate and a process for the preparation of the same
The present disclosure relates to a process for preparing polyester. The process for preparing the polyester essentially involves the preparation of the isosorbide oligomer and the isosorbide polymer from the isosorbide oligomer. The isosorbide oligomer or isosorbide polymer is then co-polymerized with the polyester. The copolymerization isosorbide oligomer or isosorbide polymer may be carried out at any stage of the preparation of the polyester. The polyester obtained in accordance with the process of the present disclosure can be used in packaging applications such as preparing packaging materials or containers. The material or container obtained from the polyester of the present disclosure is capable of withstanding a temperature of 60 to 90° C. without undergoing any deformation and shrinkage. Further, the material or container obtained from the polyester of the present disclosure is transparent or has lower color b* value.
Catalyst Composition For A Polyester Manufacturing Process
A catalyst composition for a polyester manufacturing process, comprising a titanium catalyst and/or an antimony catalyst as main catalyst, and either
(i) at least one co-catalyst A, or
(ii) at least one co-catalyst B and at least one co-catalyst C, or
(iii) a combination thereof, and
wherein co-catalyst A is selected from the group consisting of a metal salt of an alkyl or an aryl phosphinic acid, or a metal salt of an alkyl or aryl diphosphinic acid, or a combination thereof, and co-catalyst B is selected from the group consisting of an alkyl or aryl phosphinic acid, an alkyl or aryl diphosphinic acid a combination thereof, and co-catalyst C selected from the group of a metal salt, a metal hydroxide or a metal organyl compound.
Polyester yarn for industrial sewing thread and preparing method thereof
A type of polyester yarn for an industrial sewing thread and preparing method thereof are provided. The preparing method is composed of a viscosity enhancing by a solid state polycondensation and a melt spinning for a modified polyester, and the modified polyester is a product of esterification and polycondensation of evenly mixed terephthalic acid, ethylene glycol, tert-butyl branched dicarboxylic acid, trimethylsilyl branched diol and a doped Sb.sub.2O.sub.3 powder, wherein the tert-butyl branched dicarboxylic acid is selected from the group consisting of 5-tert-butyl-1,3-benzoic acid, 2-tert-butyl-1,6-hexanedioic acid, 3-tert-butyl-1,6-hexanedioic acid and 2,5-di-tert-butyl-1,6-hexanedioic acid. Moreover, the modified polyester is dispersed with a doped ZrO.sub.2 powder. An obtained fiber has an intrinsic viscosity drop of 23-28% when stored at 25° C. and R.H. 65% for 60 months.
Oxygen scavenging compositions requiring no induction period
The present invention provides a composition comprising: a polyester base polymer; an oxidizable polyether-based additive; and a transition metal catalyst, wherein the polyester base polymer is substantially free of antimony. Containers made include a wall made of the composition. The polyester base polymer may preferably include polyethylene terephthalate and include less than about 100 ppm of antimony, less than about 50 ppm, less than about 10 ppm, or between about 0 and about 2 ppm. Containers made from the composition are substantially clear and exhibit excellent oxygen scavenging properties with little to no induction period.
PPREPARING POLYESTER COMPRISING 2,5-FURANDICARBOXYLATE UNITS WITH GERMANIUM CATALYST
A process for preparing a polyester having 2,5-furandicarboxylate units includes subjecting a starting composition including 2,5-furandicarboxylic acid and an aliphatic diol to esterification conditions to produce an ester composition and contacting the ester composition with a germanium containing solution at polycondensation conditions to produce a polyester including 2,5-furandicarboxylate units, and polyester including 2,5-furandicarboxylate units including of from 5 to 100 ppm of germanium and having a number average molecular weight of at least 30 kg/mol.
PROCESS OF MANUFACTURING BIODEGRADABLE PET CHIPS
The present invention describes a process of manufacturing biodegradable PET chips, comprising the steps of providing a purified terephthalic acid (PTA) in a predetermined quantity in a slurry tank; providing virgin monoethylene glycol (MEG) in a predetermined quantity in the slurry tank; transferring the combination of the slurry tank to an esterification reactor for esterification of the combination in the reactor at above 250° C. temperature which releases monomers; transferring the monomers from the esterification reactor to a polymerisation reactor; providing poly-catalysts such as, but not limited, to Ti-based catalyst, sb2O3 or any other suitable catalysts or combination thereof into the polymerisation reactor; and polymerization of the monomers in the polymerisation reactor at above 280° C. temperature, wherein an enzyme based composition is provided either at PTA/MEG stage or poly-catalyst stage or at other stages or combination thereof.
POLYESTER COPOLYMER FOR EXTRUSION
The polyester copolymer according to the present disclosure can be extrusion-molded, and thus, can be usefully applied for the preparation of various containers.
POLYESTER FILM FOR EMBOSSING AND METHOD FOR MANUFACTURING THE SAME
A polyester film for embossing and a method for manufacturing the same are provided. The polyester film for embossing is made from a recycled polyester material. The polyester film for embossing includes a base layer and a surface coating layer. The base layer is formed from a polyester composition.
The polyester composition includes regenerated polyethylene terephthalate as a main component. The surface coating layer is disposed on at least one surface of the base layer. A material of the surface coating layer includes a main resin, fillers, and melamine. Based on a total weight of the surface coating layer being 100 wt %, an existing amount of the main resin is 45 wt % to 95 wt %, an existing amount of the fillers is 0.1 wt % to 30 wt %, and an existing amount of the melamine is 0.01 wt % to 25 wt %.